固体催化材料活性中心结构/酸碱性与催化反应微观机制的多谱学实验与理论模拟研究

   

070304-物理化学
070302-分析化学

固体催化材料酸碱性与微观反应机制

2012-09--2017-06   中国科学院武汉物理与数学研究所   理学博士

2008-09 至 2012-07, 郑州大学, 材料科学与工程学院, 学士

2012-09 至 2017-07, 中国科学院精密测量科学与技术创新研究院（原中国科学院武汉物理与数学研究所）, 分析化学, 博士

   

2019-10~现在, 中国科学院精密测量科学与技术创新研究院, 副研究员
2017-06~2019-10,中国科学院武汉物理与数学研究所, 博士后

   

（1） 青年突击手, 研究所（学校）, 2020
（2） 优秀共青团员, , 省级, 2017
（3） 武汉分院院长奖学金特别奖, 院级, 2017
（4） 博士研究生国家奖学金, 部委级, 2016

   

[1] Wei Chen, Mengdi Huang, Xianfeng Yi, Yu Hui, Pan Gao, Guangjin Hou, Alexander G Stepanov, Yucai Qin, Lijuan Song, ShangBin Liu, Zhongfang Chen, Anmin Zheng. Protonated methylcyclopropane is an intermediate providing complete 13C-label scrambling at C4 olefin isomerization in zeolite. CHEM CATALYSIS[J]. 2023, 3(2): http://dx.doi.org/10.1016/j.checat.2022.100503.
[2] Xianfeng Yi, Anmin Zheng. Shine a light on the defect evolution over the TiO2 surface. CHEM CATALYSIS[J]. 2023, 3(5): http://dx.doi.org/10.1016/j.checat.2023.100630.
[3] Zhang, Peng, Yi, Xianfeng, Xia, Changjiu, Peng, Xinxin, Zhang, Shuai, Li, Chengxiang, Zheng, Anmin, Zhang, Xiaoxin, Luo, Yibin, Cui, Lifeng, Yu, Fuhong, Shu, Xingtian. Rational construction of multiple hollow silicalite-1 zeolite with enhanced quasi acidity for robust vapor-phase Beckmann rearrangement. NANO RESEARCH. 2023, [4] Peng, WenLi, Liu, Fengqing, Yi, Xianfeng, Sun, Shugang, Shi, Hui, Hui, Yu, Chen, Wei, Yu, Xin, Liu, Zhiqiang, Qin, Yucai, Song, Lijuan, Zheng, Anmin. Structural and Acidic Characteristics of Multiple Zr Defect Sites in UiO-66 Metal-Organic Frameworks. JOURNAL OF PHYSICAL CHEMISTRY LETTERS[J]. 2022, 13(40): 9295-9302, http://dx.doi.org/10.1021/acs.jpclett.2c02468.
[5] Wang, Tao, Jin, Fang, Yi, Xianfeng, Wu, Guiying, Zheng, Anmin. Atom-planting synthesis of MCM-36 catalyst to investigate the influence of pore structure and titanium coordination state on epoxidation activity. MICROPOROUS AND MESOPOROUS MATERIALS[J]. 2021, 310: http://dx.doi.org/10.1016/j.micromeso.2020.110645.
[6] Yao Xiao, Xianfeng Yi, Wenli Peng, Wei Chen, Zhiqiang Liu, Anmin Zheng. Precisely regulating the Brønsted acidity and catalytic reactivity of novel allylic C–H acidic catalysts. FUEL. 2021, 289: http://dx.doi.org/10.1016/j.fuel.2020.119845.
[7] Yi, Xianfeng, Peng, YungKang, Chen, Wei, Liu, Zhiqiang, Zheng, Anmin. Surface Fingerprinting of Faceted Metal Oxides and Porous Zeolite Catalysts by Probe-Assisted Solid-State NMR Approaches. ACCOUNTS OF CHEMICAL RESEARCHnull. 2021, 54(10): 2421-2433, http://dx.doi.org/10.1021/acs.accounts.1c00069.
[8] Xiao, Yao, Chen, Wei, Yi, Xianfeng, Peng, Wenli, Liu, Zhiqiang, Xia, Hongqiang, Zheng, Anmin. Confinement-Driven "Flexible" Acidity Properties of Porous Zeolite Catalysts with Varied Probe-Assisted Solid-State NMR Spectroscopy. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2021, 125(21): 11580-11590, http://dx.doi.org/10.1021/acs.jpcc.1c01209.
[9] Zhou, Hang, Yi, Xianfeng, Hui, Yu, Wang, Liang, Chen, Wei, Qin, Yucai, Wang, Ming, Ma, Jiabi, Chu, Xuefeng, Wang, Yeqing, Hong, Xin, Chen, Zifeng, Meng, Xiangju, Wang, Hai, Zhu, Qiuyan, Song, Lijuan, Zheng, Anmin, Xiao, FengShou. Isolated boron in zeolite for oxidative dehydrogenation of propane. SCIENCE[J]. 2021, 372(6537): 76-+, http://dx.doi.org/10.1126/science.abe7935.
[10] 肖瑶, 夏长久, 易先锋, 刘凤庆, 刘尚斌, 郑安民. 固体核磁共振技术在锡硅分子筛表征中的应用. 波谱学杂志[J]. 2021, 38(4): 571-584, http://lib.cqvip.com/Qikan/Article/Detail?id=7106152891.
[11] Peng, WenLi, Mi, Jinxing, Liu, Fujian, Xiao, Yao, Chen, Wei, Liu, Zhiqiang, Yi, Xianfeng, Liu, Wentao, Zheng, Anmin. Accelerating Biodiesel Catalytic Production by Confined Activation of Methanol over High-Concentration Ionic Liquid-Grafted UiO-66 Solid Superacids. ACS CATALYSIS[J]. 2020, 10(20): 11848-11856, https://www.webofscience.com/wos/woscc/full-record/WOS:000614389200016.
[12] Yi, Xianfeng, Xiao, Yao, Li, Guangchao, Liu, Zhiqiang, Chen, Wei, Liu, ShangBin, Zheng, Anmin. From One to Two: Acidic Proton Spatial Networks in Porous Zeolite Materials. CHEMISTRY OF MATERIALS[J]. 2020, 32(3): 1332-1342, https://www.webofscience.com/wos/woscc/full-record/WOS:000513299400039.
[13] Yi, Xianfeng, Ko, HuiHsin, Deng, Feng, Liu, ShangBin, Zheng, Anmin. Solid-state(31)P NMR mapping of active centers and relevant spatial correlations in solid acid catalysts. NATURE PROTOCOLS[J]. 2020, 15(10): 3527-3555, https://www.webofscience.com/wos/woscc/full-record/WOS:000572338400002.
[14] Yi Xianfeng, Zheng Anmin, Liu Shang-Bin. Acidity characterization of solid acid catalysts by solid-state 31P NMR of adsorbed phosphorus-containing probe molecules: An update. ANNUALREPORTSONNMRSPECTROSCOPY[J]. 2020, 101: 65-149, [15] Liu, Zhiqiang, Yi, Xianfeng, Wang, Guiru, Tang, Xiaomin, Li, Guangchao, Huang, Ling, Zheng, Anmin. Roles of 8-ring and 12-ring channels in mordenite for carbonylation reaction: From the perspective of molecular adsorption and diffusion. JOURNAL OF CATALYSIS[J]. 2019, 369: 335-344, http://dx.doi.org/10.1016/j.jcat.2018.11.024.
[16] Jin, Zhu, Yi, Xianfeng, Wang, Liang, Xu, Shaodan, Wang, Chengtao, Wu, Qinming, Wang, Lingxiang, Zheng, Anmin, Xiao, FengShou. Metal-acid interfaces enveloped in zeolite crystals for cascade biomass hydrodeoxygenation. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2019, 254: 560-568, http://dx.doi.org/10.1016/j.apcatb.2019.05.022.
[17] Sun Zhihua, Yi Xianfeng, Tao Kewen, Ji Chengmin, Liu Xitao, Li Lina, Han Shiguo, Zheng Anmin, Hong Maochun, Luo Junhua. A New Molecular Ferroelectric Showing Room-Temperature Record-Fast Switching of Spontaneous Polarization. Angewandte Chemie International Edition[J]. 2018, 57: 9833-9837, [18] Yi, Xianfeng, Liu, Kangyu, Chen, Wei, Li, Junjie, Xu, Shutao, Li, Chengbin, Xiao, Yao, Liu, Haichao, Guo, Xinwen, Liu, ShangBin, Zheng, Anmin. Origin and Structural Characteristics of Tri-coordinated Extra-framework Aluminum Species in Dealuminated Zeolites. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 140(34): 10764-10774, http://dx.doi.org/10.1021/jacs.8b04819.
[19] Yi, Xianfeng, Li, Guangchao, Huang, Ling, Chu, Yueying, Liu, Zhiqiang, Xia, Hongqiang, Zheng, Amain, Deng, Feng. An NMR Scale for Measuring the Base Strength of Solid Catalysts with Pyrrole Probe: A Combined Solid-State NMR Experiment and Theoretical Calculation Study. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2017, 121(7): 3887-3895, http://ir.wipm.ac.cn/handle/112942/10025.
[20] Li, Guangchao, Yi, Xianfeng, Huang, Ling, Jiang, Jizhou, Yu, Zhiwu, Liu, Zhiqiang, Zheng, Anmin. Solvent Effect Inside the Nanocage of Zeolite Catalysts: A Combined Solid-State NMR Approach and Multiscale Simulation. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2017, 121(31): 16921-16931, http://ir.hfcas.ac.cn:8080/handle/334002/30971.
[21] Huang, Mengdi, Wang, Qiang, Yi, Xianfeng, Chu, Yueying, Dai, Weili, Li, Landong, Zheng, Anmin, Deng, Feng. Insight into the formation of the tert-butyl cation confined inside H-ZSM-5 zeolite from NMR spectroscopy and DFT calculations. CHEMICAL COMMUNICATIONS[J]. 2016, 52(70): 10606-10608, http://ir.wipm.ac.cn/handle/112942/9575.
[22] Yi, Xianfeng, Ding, Lihong, Li, Guangchao, Liu, Zhiqiang, Xia, Hongqiang, Chu, Yueying, Zheng, Anmin, Deng, Feng. Insights into the reaction mechanism of propene H/D exchange over acidic zeolite catalysts from theoretical calculations. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2016, 6(16): 6328-6338, http://ir.wipm.ac.cn/handle/112942/9587.
[23] Yi, Xianfeng, Byun, Youngchul, Chu, Yueying, Zheng, Anmin, Hong, Suk Bong, Deng, Feng. Stability of the Reaction Intermediates of Ethylbenzene Disproportionation over Medium-Pore Zeolites with Different Framework Topologies: A Theoretical Investigation. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2013, 117(45): 23626-23637, http://dx.doi.org/10.1021/jp4089386.
[24] Xianfeng Yi, Yao Xiao, Changjiu Xia, Fengqing Liu, Yujia Liu, Yu Hui, Xin Yu, Yucai Qin, Wei Chen, Zhiqiang Liu, Lijuan Song, Anmin Zheng. Adsorbate-driven dynamic active sites in stannosilicate zeolites. FUNDAMENTAL RESEARCH. http://dx.doi.org/10.1016/j.fmre.2022.12.015.

   

（ 1 ） 分子筛催化剂酸碱中心相互作用的固体核磁共振研究, 主持, 国家级, 2019-01--2021-12
（ 2 ） 分子筛催化的原位动态表征及反应机理研究, 主持, 国家级, 2022-01--2026-12
（ 3 ） 分子筛催化剂酸特性的固体核磁共振研究, 主持, 国家级, 2017-12--2019-10
（ 4 ） 多功能分子筛催化剂酸碱特性的固体核磁共振研究, 主持, 国家级, 2019-06--2019-10

（1）脱铝分子筛活性中心物种演化机制研究   第二十一届全国分子筛学术大会   2021-09-27
（2）固体催化材料酸特性的NMR实验与理论计算研究   第一届分子科学博士后论坛   2021-05-16
（3）脱铝分子筛酸中心空间距离及非骨架铝物种演化机制研究   第二十届全国分子筛学术大会   易先锋，肖瑶，郑安民   2019-10-22
（4）丝光沸石分子筛酸性质子空间分布的固体NMR研究   第二十届全国波谱学学术年会   2018-10-11
（5）丝光沸石酸性质子空间相互作用机制的固体NMR研究   第十七届全国青年催化学术会议   2018-08-17