基本信息
吴波  女  硕导  中国科学院大连化学物理研究所
电子邮件: bowu@dicp.ac.cn
通信地址: 辽宁省大连市中山路457号
邮政编码: 116023

研究领域

不对称合成

招生信息

   
招生专业
070303-有机化学
招生方向
有机化学

教育背景

2011-09--2016-07   中国科学院大连化学物理研究所   博士学位
2007-09--2011-06   湖南大学   学士学位
学历

研究生

学位

博士

工作经历

   
工作简历
2018-12~现在, 中国科学院大连化学物理研究所, 副研究员
2018-06~2018-12,中国科学院大连化学物理研究所, 助理研究员
2016-11~2018-01,美国伊利诺伊大学芝加哥分校, 博士后

专利与奖励

   
专利成果
( 1 ) 一种合成手性3,4-二氢香豆素的方法, 发明, 2016, 第 2 作者, 专利号: 201610403147.4
( 2 ) 一种合成 1,2-二氢苯并呋喃并吡啶化合物的方法, 发明, 2019, 第 3 作者, 专利号: 201910935808.1
( 3 ) 一种钯催化不对称还原合成手性 β-羟基酮的方法, 发明, 2019, 第 1 作者, 专利号: 201910935822.1
( 4 ) 一种合成手性杂三芳基甲烷的方法, 发明, 2019, 第 3 作者, 专利号: 201910167900.8

出版信息

   
发表论文
[1] Huang, WenJun, Chen, ZhiPeng, Liu, LiXia, Zhou, YongGui, Wu, Bo, Jiang, GuoFang. A facile synthesis of pyrrolo2,3-jphenanthridines via the cascade reaction of indoleanilines and aldehydes. JOURNAL OF HETEROCYCLIC CHEMISTRY[J]. 2022, 59(6): 1116-1122, http://dx.doi.org/10.1002/jhet.4444.
[2] Wang, Xiaoqing, Bai, Yuqing, Zhai, Xiaoyong, Wu, Bo, Zhou, Yonggui. Synthesis of poly(silyl ether)s via copper-catalyzed dehydrocoupling polymerization. CHINESE CHEMICAL LETTERS[J]. 2022, 33(5): 2639-2642, http://dx.doi.org/10.1016/j.cclet.2021.09.054.
[3] XiaoQing Wang, YuQing Bai, Kun Wang, Bo Wu, YongGui Zhou. A metal-free and air-tolerable insertion polymerization using sulfoxonium ylides as monomers. EUROPEAN POLYMER JOURNAL. 2022, 179: http://dx.doi.org/10.1016/j.eurpolymj.2022.111578.
[4] XiaoQing Wang, Bo Wu PhD, YuQing Bai, XiaoYong Zhai, YongGui Zhou PhD. CuH-catalyzed consecutive hydrosilylation/dehydrocoupling polymerization of difunctional hydroxyketones with dihydrosilanes for syntheses of chiral poly(silyl ether)s. EUROPEAN POLYMER JOURNAL. 2022, 177: http://dx.doi.org/10.1016/j.eurpolymj.2022.111474.
[5] Zhai, XiaoYong, Wang, XiaoQing, Wu, Bo, Zhou, YongGui. Copper-Catalyzed Si-H Bond Insertion Polymerization for Synthesis of Optically Active Polyesters Containing Silicon. CHINESE JOURNAL OF CHEMISTRY[J]. 2022, 40(1): 21-27, http://dx.doi.org/10.1002/cjoc.202100569.
[6] Wang, XinWei, Chen, MuWang, Wu, Bo, Wang, Baomin, Wan, Boshun, Zhou, YongGui. Chiral phosphoric acid-catalyzed regioselective synthesis of spiro aminals with quaternary stereocenters. TETRAHEDRON LETTERS[J]. 2021, 65: http://dx.doi.org/10.1016/j.tetlet.2020.152793.
[7] Wang, XinWei, Li, Xiang, Chen, MuWang, Wu, Bo, Zhou, YongGui. Chiral Phosphoric Acid-Catalyzed Pictet-Spengler Reactions for Synthesis of 5 ',11 '-Dihydrospiroindoline-3,6 '-indolo3,2-cquinolin-2-ones Containing Quaternary Stereocenters. JOURNAL OF ORGANIC CHEMISTRY[J]. 2021, 86(9): 6897-6906, http://dx.doi.org/10.1021/acs.joc.1c00289.
[8] Huang, WenJun, Ma, YaYa, Liu, LiXia, Wu, Bo, Jiang, GuoFang, Zhou, YongGui. Chiral Phosphoric Acid-Catalyzed C6 Functionalization of 2,3-Disubstituted Indoles for Synthesis of Heterotriarylmethanes. ORGANIC LETTERS[J]. 2021, 23(7): 2393-2398, http://dx.doi.org/10.1021/acs.orglett.0c04002.
[9] Zhao, ZiBiao, Li, Xiang, Wu, Bo, Zhou, YongGui. Biomimetic Asymmetric Reduction of Quinazolinones with Chiral and Regenerable NAD(P)H Models. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(7): 714-718, http://lib.cqvip.com/Qikan/Article/Detail?id=7102778939.
[10] Zhao, ZiBiao, Li, Xiang, Chen, MuWang, Wu, Bo, Zhou, YongGui. Enantioselective Synthesis of Tetrahydroquinolines via One-Pot Cascade Biomimetic Reduction. CHINESE JOURNAL OF CHEMISTRY[J]. 2020, 38(12): 1691-1695, http://lib.cqvip.com/Qikan/Article/Detail?id=7103704700.
[11] Wang, XiaoQing, Zhai, XiaoYong, Wu, Bo, Bai, YuQing, Zhou, YongGui. Synthesis of Chiral Poly(silyl ether)s via CuH-Catalyzed Asymmetric Hydrosilylation Polymerization of Diketones with Silanes. ACS MACRO LETTERS[J]. 2020, 9(7): 969-973, https://www.webofscience.com/wos/woscc/full-record/WOS:000555009000009.
[12] 谢焕平, 吴波, 陈木旺, 余长斌, 黎红旺, 李翔, 周永贵. 方酰胺催化氮杂二烯和吡唑啉-5-酮的加成:含吡唑三芳基甲烷的不对称合成. 有机化学[J]. 2020, 40(10): 3452-3462, http://lib.cqvip.com/Qikan/Article/Detail?id=7103355116.
[13] Xie, Huanping, Wu, Bo, Chen, Muwang, Yu, Changbin, Li, Hongwang, Li, Xiang, Zhou, Yonggui. Enantioselective Synthesis of Triarylmethanes Bearing Pyrazole Moiety through Squaramide-Catalyzed Addition of Azadienes with Pyrazolin-5-ones. CHINESE JOURNAL OF ORGANIC CHEMISTRY[J]. 2020, 40(10): 3452-3462, http://dx.doi.org/10.6023/cjoc202003005.
[14] Li, Xiang, Zhao, ZiBiao, Chen, MuWang, Wu, Bo, Wang, Han, Yu, ChangBin, Zhou, YongGui. Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions. CHEMICAL COMMUNICATIONS[J]. 2020, 56(43): 5815-5818, https://www.webofscience.com/wos/woscc/full-record/WOS:000537959100019.
[15] Zhu, ZhouHao, Ding, YiXuan, Wu, Bo, Zhou, YongGui. Design and synthesis of chiral and regenerable 2.2paracyclophane-based NAD(P)H models and application in biomimetic reduction of flavonoids. CHEMICAL SCIENCE[J]. 2020, 11(37): 10220-10224, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162316/.
[16] Xie, HuanPing, Sun, Lei, Wu, Bo, Zhou, YongGui. Copper-Catalyzed Alkynylation/Cyclization/Isomerization Cascade for Synthesis of 1,2-Dihydrobenzofuro3,2-bpyridines and Benzofuro3,2-bpyridines. JOURNAL OF ORGANIC CHEMISTRY[J]. 2019, 84(23): 15498-15507, https://www.webofscience.com/wos/woscc/full-record/WOS:000502170600045.
[17] Wang, XinWei, Chen, MuWang, Wu, Bo, Wang, Baomin, Zhou, YongGui. Chiral Phosphoric Acid-Catalyzed Synthesis of Fluorinated 5,6-Dihydroindolo1,2-cquinazolines with Quaternary Stereocenters. JOURNAL OF ORGANIC CHEMISTRY[J]. 2019, 84(12): 8300-8308, [18] HuanPing Xie, Bo Wu, XinWei Wang, YongGui Zhou. Chiral Brønsted acid-catalyzed conjugate addition of indoles to azadienes: Enantioselective synthesis of hetero-triarylmethanes. CHINESE JOURNAL OF CATALYSIS. 2019, 1566-1575, http://dx.doi.org/10.1016/S1872-2067(19)63396-6.
[19] Shen, HongQiang, Wu, Bo, Xie, HuanPing, Zhou, YongGui. Preparation of Axially Chiral 2,2 '-Biimidazole Ligands through Remote Chirality Delivery and Their Application in Asymmetric Carbene Insertion into N-H of Carbazoles. ORGANIC LETTERS[J]. 2019, 21(8): 2712-2717, http://cas-ir.dicp.ac.cn/handle/321008/165496.
[20] Zhao, Yang, Wang, Han, Wu, Bo, Zhou, YongGui. Synthesis of paracyclophanes with planar and central chirality: kinetic resolution of 2.2paracyclophane aldimines via palladium-catalyzed addition of arylboronic acids. ORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(24): 3956-3960, [21] Bo Wu, Selwyn S Jayakar, Xiaojuan Zhou, Katherine Titterton, David C Chiara, Andrea L Szabo, Pavel Y Savechenkov, Daniel E Kent, Jonathan B Cohen, Stuart A Forman, Keith W Miller, Karol S Bruzik. Inhibitable photolabeling by neurosteroid diazirine analog in the β3-Subunit of human hetereopentameric type A GABA receptors. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY. 2019, 162: 810-824, http://dx.doi.org/10.1016/j.ejmech.2018.11.019.
[22] Gu, Zheng, Wu, Bo, Jiang, GuoFang, Zhou, YongGui. Synthesis of Benzofuran-fused 1,4-Dihydropyridines via Bifunctional Squaramide-catalyzed Formal 4+2 Cycloaddition of Azadienes with Malononitrile. CHINESE JOURNAL OF CHEMISTRY[J]. 2018, 36(12): 1130-1134, http://lib.cqvip.com/Qikan/Article/Detail?id=6100154713.
[23] HuanPing Xie, Zhong Yan, Bo Wu, ShuBo Hu, YongGui Zhou. Synthesis of electron-deficient (Sa,R,R)-(CF3)2-C3-TunePhos and its applications in asymmetric hydrogenation of α-iminophosphonates. TETRAHEDRON LETTERS. 2018, 59(31): 2960-2964, http://dx.doi.org/10.1016/j.tetlet.2018.06.037.
[24] 吴波. Regioselective a-Addition of Deconjugated Butenolides: Enantioselective Synthesis of Dihydrocoumarins. Angew. Chem. Int. Ed.. 2017, [25] Gao, Xiang, Wu, Bo, Yan, Zhong, Zhou, YongGui. Enantioselective palladium-catalyzed arylation of N-tosylarylimines with arylboronic acids using a chiral 2,2 '-bipyridine ligand. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2016, 14(1): 55-58, http://cas-ir.dicp.ac.cn/handle/321008/171560.
[26] Chen, MuWang, Wu, Bo, Chen, ZhangPei, Shi, Lei, Zhou, YongGui. Synthesis of Chiral Fluorinated Propargylamines via Chemoselective Biomimetic Hydrogenation. ORGANIC LETTERS[J]. 2016, 18(18): 4650-4653, http://cas-ir.dicp.ac.cn/handle/321008/170182.
[27] Yan, Zhong, Wu, Bo, Gao, Xiang, Zhou, YongGui. Enantioselective synthesis of quaternary alpha-aminophosphonates by Pd-catalyzed arylation of cyclic alpha-ketiminophosphonates with arylboronic acids. CHEMICAL COMMUNICATIONS[J]. 2016, 52(72): 10882-10885, http://cas-ir.dicp.ac.cn/handle/321008/170114.
[28] Huang, WenXue, Liu, LianJin, Wu, Bo, Feng, GuangShou, Wang, Baomin, Zhou, YongGui. Synthesis of Chiral Piperazines via Hydrogenation of Pyrazines Activated by Alkyl Halides. ORGANIC LETTERS[J]. 2016, 18(13): 3082-3085, http://cas-ir.dicp.ac.cn/handle/321008/170364.
[29] 高翔, 吴波, 黄文学, 陈木旺, 周永贵. Enantioselective Palladium-Catalyzed C¢H Functionalization of Indoles Using an Axially Chiral 2,2’-Bipyridine Ligand. ANGEWANDTE CHEMIE INTERNATIONAL EDITION[J]. 2016, 54: 11956-, http://cas-ir.dicp.ac.cn/handle/321008/148000.
[30] Yan, Zhong, Wu, Bo, Gao, Xiang, Chen, MuWang, Zhou, YongGui. Enantioselective Synthesis of alpha-Amino Phosphonates via Pd-Catalyzed Asymmetric Hydrogenation. ORGANIC LETTERS[J]. 2016, 18(4): 692-695, http://cas-ir.dicp.ac.cn/handle/321008/171278.
[31] Gao, Xiang, Wu, Bo, Yan, Zhong, Zhou, YongGui. Copper-catalyzed enantioselective C-H functionalization of indoles with an axially chiral bipyridine ligand. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2016, 14(35): 8237-8240, http://www.corc.org.cn/handle/1471x/2376159.
[32] 陈木旺, 叶智识, 陈章培, 吴波, 周永贵. Enantioselective Synthesis of Trifluoromethyl Substituted Piperidines with Multiple Stereogeni Centers via Hydrogenation of Pyridinium Hydrochlorides. ORGANIC CHEMISTRY FRONTIERS有机化学前沿[J]. 2015, 2: 586-, http://cas-ir.dicp.ac.cn/handle/321008/148058.
[33] Peng, Libo, Yang, Limin, Wu, Nan, Wu, Bo. Primary primitive neuroectodermal tumor arising in the mesentery and ileocecum: A report of three cases and review of the literature. EXPERIMENTAL AND THERAPEUTIC MEDICINE[J]. 2015, 9(4): 1299-1303, https://www.webofscience.com/wos/woscc/full-record/WOS:000351711600034.
[34] Chen, MuWang, Ye, ZhiShi, Chen, ZhangPei, Wu, Bo, Zhou, YongGui. Enantioselective synthesis of trifluoromethyl substituted piperidines with multiple stereogenic centers via hydrogenation of pyridinium hydrochlorides. ORGANIC CHEMISTRY FRONTIERS[J]. 2015, 2(5): 586-589, https://www.webofscience.com/wos/woscc/full-record/WOS:000364445300023.
[35] 吴波, 陈木旺, 周永贵. A streamlined Synthesis of 2,3-Dihydrobenzofurans via the o-Quinone Methides Intermediates. 24th international society of heterocyclic chemistry congressnull. 2013, 141-, http://159.226.238.44/handle/321008/120085.
[36] Zhang, Min, Lin, Guoqiang, Wu, Bo, Shao, Zhigang. Composition optimization of arc ion plated CrNx films on 316L stainless steel as bipolar plates for polymer electrolyte membrane fuel cells. JOURNAL OF POWER SOURCES[J]. 2012, 205(1): 318-323, http://dx.doi.org/10.1016/j.jpowsour.2012.01.056.

科研活动

   
科研项目
( 1 ) 中国科学院大连化学物理 研究所优秀青年博士人才, 主持, 市地级, 2019-06--2022-06
( 2 ) 醇质子作为氢源的不对称还原, 主持, 国家级, 2020-01--2022-12
( 3 ) 金属催化硅氢化聚合合成手性聚硅醚, 主持, 市地级, 2020-08--2022-07

指导学生

现指导学生

陈简  硕士研究生  070303-有机化学