戴文  男  研究员 博士生导师  中国科学院大连化学物理研究所
电子邮件: daiwen@dicp.ac.cn
通信地址: 辽宁省大连市中山路457号催化楼323房间
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研究领域


戴文,男,博士,研究员,博士生导师,中国科学院专项人才计划获得者 (择优支持),大连化物所“张大煜青年学者”。1986年出生,江西抚州人。现任中国科学院大连化学物理研究所有机硼化学与绿色氧化创新特区研究组组长。2011年7月于沈阳药科大学获得药物化学硕士学位;2015年1月于中国科学院大连化学物理研究所获得博士学位;同年获得“大连化物所优秀博士后奖励基金”资助,于2015年1月至2016年9月留所从事博士后研究;2016年10月至2019年10月在美国匹兹堡大学继续从事博士后研究;2020年1月加入中国科学院大连化学物理研究所开展独立研究工作。迄今已在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、ACS Catal等国际知名期刊发表论文20余篇。主要研究方向:(1)催化氧化;(2)自由基化学;(3) 生物质转化。


招生信息

招生要求:
1)有机化学、药物化学、多相催化等相关专业;
2)身心健康、工作勤奋踏实,具有良好的学术道德和团队协作精神


招生专业:有机化学(070303)
招生方向:催化氧化,自由基化学,生物质转化

出版信息

代表性论文


1. Luo, H. H.; Wang, L. Y.*; Shang, S. S.; Li, G. S.; Lv, Y.; Gao, S.*; Dai, W.*Cobalt Nanoparticles-Catalyzed Widely Applicable Successive C-C Bond Cleavage in Alcohols to Access Esters​, Angew. Chem. Int. Ed., 2020, 59, 19268.


2. Dai, W.; Geib, S. J.; Curran, D. P.*, 1,4-Hydroboration Reactions of Electron-Poor Aromatic Rings by N-Heterocyclic Carbene Boranes, J. Am. Chem. Soc. 2020, 142, 6261.


3. Dai, W.; Geib, S. J.; Curran, D. P.*, Ring-Opening Reactions of NHC-Boriranes with In Situ Generated HCl: Synthesis of a New Class of NHC-Boralactones, J. Am. Chem. Soc. 2019, 141, 3623.


4. Dai, W.; Geib, S. J.; Curran, D. P.*, Facile Synthesis of α-N-Heterocyclic Carbene-Boryl Ketones from N-Heterocyclic Carbene-Boranes and Alkenyl Triflates, J. Am. Chem. Soc. 2019, 141, 12355.


5. Dai, W.; McFadden, T. R.; Curran, D. P.*, 5-EndoCyclizations of NHC-Boraallyl Radicals Bearing Ester Substituents: Characterization of Derived 1,2-Oxaborole Radicals and Boralactones, J. Am. Chem. Soc. 2018, 140, 15868.


6. Dai, W.; Curran, D . P.*; Walton, J. C.*, EPR and Preparative Studies of 5-endo Cyclizations of Radicals Derived from Alkenyl NHC-Boranes Bearing tert-Butyl Ester Substituents, J. Org. Chem. 2019, 84, 2102.


7. Dai, W.; Geib, S . J.; Curran, D . P.*, Reactions of N-Heterocyclic Carbene Boranes with 5-Diazo-2,2-dimethyl-1,3

-dioxane-4,6-dione:Synthesis of Mono- and Bis-hydrazonyl NHC-Boranes, J. Org. Chem. 2018, 83, 8775.


8. Dai, W.*; Shang, S.; Lv, Y.; Li, G.; Li, C.*; Gao, S.*,Highly Chemoselective and Enantioselective Catalytic Oxidation of Heteroaromatic Sulfides via High-Valent Manganese(IV)-Oxo Cation Radical Oxidizing Intermediates, ACS Catal. 2017, 7, 4890.


9. Dai, W.; Mi, Y.; Lv, Y.; Chen, B.; Li, G.; Chen,G*; Gao,S*, Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst, Adv Synth Catal. 2016, 358, 667.


10. Dai, W.; Lv, Y.; Wang, L.; Shang, S.; Chen, B.; Li, G.; Gao, S.*, Highly Efficient Oxidation of Alcohols Catalyzed by a Porphyrin-inspired Manganese Complex, Chem. Commun. 2015, 51, 11268.


11. Dai, W.; Li, G.; Chen, B.; Wang, L.; Gao, S.*, A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-deficient Olefins, Org. Lett. 2015, 17, 904.


12. Dai, W.; Shang, S.; Chen, B.; Li, G; Wang, L.; Ren, L; Gao, S*, Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an In Situ Formed Manganese complex, J. Org. Chem. 2014, 79, 6688.


13. Dai, W.; Li, J.; Li, G.; Yang, H.; Wang, L.; Gao, S.*,Asymmetric Epoxidation of Alkenes Catalyzed by Porphyrin-inspired Manganese Complex, Org. Lett. 2013, 15, 4138.


14. Dai, W.; Li, J.; Chen, B.; Li, G.; Lv, Y.; Wang, L.; Gao, S.*, Asymmetric Oxidation Catalysis by a Porphyrin-Inspired Manganese Complex: Highly Enantioselective Sulfoxidation with a Wide Substrate Scope, Org. Lett. 2013, 15, 5658.


15. Dai, W.; Wang, L.; Lv, Y.; Gao, S.*,Metal-Free Catalysis of Nitrogen-doped Nanocarbons for the Ammoxidation of Alcohols to Nitriles, Chem. Commun. 2017, 53, 1048.


16. Shang, S.; Wang, L.;Dai, W.; Chen, B.; Lv, Y.; Gao, S.*, High Catalytic Activity of Mesoporous Co-N/C Catalysts for Aerobic Oxidative Synthesis of Nitriles, Catal. Sci. Technol., 2016, 6, 5746.


17. Chen, B.; Wang, L.; Dai, W.; Shang, S.; Lv, Y.; Gao, S.*, Metal-Free and Solvent-Free Oxidative Coupling of Amines to Imines with Mesoporous Carbon from Macrocyclic Compounds, ACS Catal., 2015, 5, 2788.