课题组成立于2016年，研究工作聚焦于超分子/氢键有机框架化合物（SOFs/HOFs）及金属有机框架化合物（MOFs）的设计、合成与性能研究。从结构化学的角度出发，实验室的研究工作关注于开发新型稳定多孔框架材料，获得对MOFs/SOFs/HOFs化学更多的理解，并拓展它们的潜在应用范围。研究工作涉及异相光/热催化、液体/气体分离与存储、生物医用等交叉领域。

课题组长期招收国内以及国际研究生、博士后。

2016.08 – 至今 中国科学院福建物质结构研究所，课题组长，研究员

2015. 04 – 2016.04  美国西北大学，博士后助理研究员

2011. 10 – 2015. 04  美国德州农工大学，博士后助理研究员

2006.09 – 2011.07 中国科学院福建物质结构研究所，博士学位

1.曹荣，刘天赋，尹琦；基于稠环配体构筑的氢键有机框架材料、其制备方法及应用；申请号：201810220893.9；公布号：108727605 A；公布日期：2018年11月2日。

2. 刘天赋，黄阁；基于杂芳基官能团配体的金属有机框架材料及其制备方法和应用；申请号：202010023346．9；公布日期：2021年1月9日。

3. Hong-Cai Zhou, Tian-Fu Liu, Dawei Feng, Chromium metal organic frameworks and syntheses of metal organic frameworks, 发明, 2015, 美国发明专利: PCT/GB2015/05182

2022

39.Rui Wang, Bai-Tong Liu, Shuo Zhang, Xin-Song Huang, Lei Xie, Tian-Fu Liu*, Rong Cao*, Design of a Metal-Organic Framework with Preset Binding Sites for Crystallographic Visualized Metalation, Small Struct. 2022, doi: 10.1002/sstr.202200148

38.Qian-Qian Huang, Zhi-Bin Fang, Kuan Pang, Wei-Kang Qin, Tian-Fu Liu^*, Rong Cao^*, The Impact of Secondary Building Units in Metal–Organic Frameworks on Plasmonic Gold-Sensitized Photocatalysis, Adv. Funct. Mater. 2022, doi:10.1002/adfm.202205147

37.Zhao Xuan†, Yin Qi†, Mao Xinnan†, Cheng Chen, Zhang Liang, Wang Lu*, Liu Tian-Fu*, Li Youyong, Li Yanguang*. “Theory-Guided Design of Hydrogen-Bonded Cobaltoporphyrin Frameworks for Highly Selective Electrochemical H2O2 Production  in Acids. Nature Commun. 2022, 13, 2721 doi: 10.1038/s41467-022-30523-0

36. Wei-Kang Qin, Duan-Hui Si, Qi Yin, Xiang-Yu Gao, Qian-Qian Huang, Ya-Nan Feng, Lei Xie, Shuo Zhang, Xin-Song Huang, Tian-Fu Liu,* and Rong Cao,* Reticular Synthesis of Hydrogen-Bonded Organic Frameworks and Their Derivative via Mechanochemistry, Angew. Chem. Int. Ed. 2022, 61 (27) , e202202089.

35. An-An Zhang, Duanhui Si, Haibo Huang, Lei Xie, Zhi-Bin Fang, Tian-Fu Liu*, Rong Cao*, Partial Metalation of Porphyrin Moieties in Hydrogen-Bonded Organic Frameworks Provides Enhanced CO2 Photoreduction Activity, Angew. Chem. Int. Ed. 2022, 61, e202203955.

34. An-An Zhang; Yu-Lin Li, Zhi-Bin Fang, Lei Xie, Rong Cao, Yangyang Liu,* Tian-Fu Liu,* Facile Preparation of Hydrogen-Bonded Organic Framework/Cu2O Heterostructure Films via Electrophoretic Deposition for Efficient CO2 Photoreduction, ACS Appl. Mater. Interfaces. 2022, doi:10.1021/acsami.2c02917.

33. Hai–Bo Huang, Zhi–Bin Fang, Rui Wang, Lan Li, Mojtaba Khanpour, Tian-Fu Liu*, Rong Cao*, Engineering Hierarchical Architecture of Metal-Organic Frameworks for Highly Efficient Overall CO2 Photoreduction, Small, 2022, doi: 10.1002 smll.202200407

32. Qi Yin, Eugeny V. Alexandrov, Duan-Hui Si, Qian-Qian Huang, Zhi-Bin Fang, Yuan Zhang, An-An Zhang, Wei-Kang Qin, Yu-Lin Li, Tian-Fu Liu*, and Davide M. Proserpio, Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction, Angew. Chem. Int. Ed. 2022, 134  (6) , e202115854.

31. Yantong Lu, Kuangli Yu, Qi Yin, Jingwen Liu, Xue Han, Dian Zhao, Tian-Fu Liu, Chunxia Li*, Embedding red-emitting dyes in robust hydrogen-bonded organic framework for application in warm white light-emitting diodes. Micropor. Mesopor. Mat. 2022, 331, 111673.

2021

30. An-An Zhang, Xiyue Cheng, Xu He, Wei Liu, Shuiquan Deng, Rong Cao* and Tian-Fu Liu*, Harnessing Electrostatic Interactions for Enhanced Conductivity in Metal-Organic Frameworks, Research, 2021, 2021, 9874273.  

29. Bai-Tong Liu, Xiao-Hong Pan, Ding-Yang Zhang, Rui Wang, Jun-Yu Chen, Han-Ru Fang, Tian-Fu Liu*，Construction of Function-Orientated Core-Shell Nanostructure in Hydrogen-Bonded Organic Framework for Near-infrared Responsive Bacterial Inhibition, Angew. Chem. Int. Ed. 2021, 60 (49) , 25701-25707.  

28. Lan Li†, Zhi-Bin Fang† (equal contribution), Wenzhuo Deng, Jun-Dong Yi, Rui Wang, and Tian-Fu Liu,* Precise Construction of Stable Bimetallic Metal-Organic Frameworks with Single-Site Ti(IV) Incorporation in Nodes for Efficient Photocatalytic Oxygen Evolution, CCS. Chem. 2021, 3, 2839-2849.   

27. Mojtaba Khanpour, Wen-Zhou Deng, Zhi-Bin Fang, Yu-Lin Li, Qi Yin, An-An Zhang, Farzaneh Rouhani, Ali Morsali,* Tian-Fu Liu,* Radiochromic Hydrogen-Bonded Organic Frameworks for X-ray Detection, Chem. - Eur. J.  2021, 27 (42) , 10957-10965.

26. Nan Zhang, Qi Yin, Song Guo,* Kai-Kai Chen, Tian-Fu Liu,* Ping Wang, Zhi-Ming Zhang,* Tong-Bu Lu, Hot-electron leading-out strategy for constructing photostable HOF catalysts with outstanding H2 evolution activity, Applied Catalysis B: Environmental, 2021, 296, 120337.

25. Jing Sun, Xuan Zhang, Dong Zhang, Ying-Pin Chen, Fei Wang, Lan Li, Tian-Fu Liu, Huanghao Yang, Jibin Song,* and Rong Cao* Building Block Symmetry Relegation Brings Mesopore and Abundant Open Metal Sites in Metal-Organic Frameworks for Cancer Therapy, CCS. Chem. 2021, 3, 1048-1058.

24. Tao Li, Bai-Tong Liu, Zhi-Bin Fang, Qi Yin, Rui Wang, and Tian-Fu Liu*, Integrating Active C3N4 Moieties in Hydrogen-bonded Organic Frameworks for Efficient Photocatalysis, J. Mater. Chem. A, 2021, 9, 4687-4691.

2020

23. Jun-Dong Yi, Ruikuan Xie, Zai-Lai Xie, Guo-Liang Chai,* Tian-Fu Liu, Rui-Ping Chen, Yuan-Biao Huang,* Rong Cao,* Highly Selective CO2 Electroreduction to CH4 by in situ Generated Cu2O Single-Type Sites on Conductive MOF: Stabilizing Key Intermediates with Hydrogen Bond, Angew. Chem. Int. Ed. 2020, 59 (52) , 23641.

22. Lan Li, Xu‐Sheng Wang, Tian‐Fu Liu*, and Jinhua Ye*, Titanium‐Based MOF Materials: From Crystal Engineering to Photocatalysis, Small Methods, 2020, 4 (12), 2000486.

21. Bai-Tong Liu, Xiao-Hong Pan, Dan-Yue Nie, Xiao-Jing Hu, En-Ping Liu, and Tian-Fu Liu* Ionic Hydrogen-Bonded Organic Frameworks for Ion-Responsive Antimicrobial Membrane, Adv. Mater. 2020, 32 (48) , 2005912.

20. Ji-Fei Feng, Tian-Fu Liu* and Rong Cao*, An Electrochromic Hydrogen-Bonded Organic Framework Film, Angew. Chem. Int. Ed. 2020, 59 (50) , 22392.

19. Zhi-Bin Fang, Ting-Ting Liu, Junxue Liu, Shengye Jin, Xin-Ping Wu, Xue-Qing Gong, Kecheng Wang, Qi Yin, Tian-Fu Liu, Rong Cao*, and Hong-Cai Zhou, Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal−Organic Frameworks. J. Am. Chem. Soc. 2020, 142 (28), 12515-12523.

18. Hai-Xiong Liu, Ting-Ting Liu, Tao Huang, Zhi-Bin Fang, Lan Li, Qi Yin, Rong Cao, Xue-Qing Gong*, Tian-Fu Liu*, Drastic Change of Electronic Band Structure with Preserved Topology and Porosity, J. Mater. Chem. A, 2020, 8, 12370-12377

17. Bai-tong Liu, En-ping Liu, Rong-Jian Sa,* Tian-fu Liu*, Crystalline Hydrogen-Bonded Organic Chains Achieving Ultralong Phosphorescence via Triplet–Triplet Energy Transfer, Adv. Optical Mater. 2020, 8 (12) , 2000281.

16. Ge Huang, Li Yang, Qi Yin, Zhi-Bin Fang, Xiao-Jing Hu, An-An Zhang, Jun Jiang, Tian-Fu Liu*, and Rong Cao*. “A Comparison of Two Isoreticular Metal-Organic Frameworks with Cationic and Neutral Skeletons: Stability, Mechanism, and Functionality”. Angew. Chem. Int. Ed. 2020, 59 (11) , 4385.

15. Li Yu-Lin, Eugeny V. Alexandrov, Yin Qi, Li Lan, Fang Zhi-Bin, Yuan Wenbing*, Davide M. Proserpio* and Liu Tian-Fu*, “Record Complexity in the Polycatenation of Three Porous Hydrogen-bonded Organic Frameworks with Stepwise Adsorption Behaviors". J. Am. Chem. Soc. 2020, 142 (15), 7218.

2019

14. Xiao-Jing Hu, Zi-Xuan Li, Huan Xue, Xinsong Huang, Rong Cao, Tian-Fu Liu*, Designing a bifunctional Brønsted acid-base heterogeneous catalyst through precise installation of ligands on metal-organic frameworks,  CCS Chem. 2019, 1 (2), 616–622.

13. Qi Yin, Yu-Lin Li, Lan Li, Jian Lü, Tian-Fu Liu*, Rong Cao*, “Novel Hierarchical Meso-Microporous Hydrogen-bonded Organic Framework for Selective Separation of Acetylene and Ethylene versus Methane,” ACS Appl. Mater. Interfaces, 2019, 11 (19) , 17823–17827.

12. Yue Xie, Zhibin Fang, Lan Li, Hongxun Yang*, and Tian-Fu Liu*, “Creating Chemisorption Sites for Enhanced CO2 Photoreduction Activity through Alkylamine Modification of MIL-101-Cr,” ACS Appl. Mater. Interfaces, 2019, 11 (30) , 27017−27023.

11. Qi Yin, Jian Lü, Hong-Fang Li, Tian-Fu Liu*, Rong Cao*, “A Robust Microporous Porphyrin-based Hydrogen-bonded Organic Framework for Highly Selective Separation of C2 Hydrocarbons versus Methane,” Cryst. Growth Des. 2019, 19 (7) , 4157-4161.

10. Lan Li, Jun-Dong Yi, Zhi-Bin Fang, Xu-Sheng Wang, Nan Liu, Ya-Nan Chen, Tian-Fu Liu* and Rong Cao, “Creating Giant Secondary Building Layers via Alkali-Etching Exfoliation for Precise Synthesis of Metal-Organic Frameworks Chemistry of Materials,” Chem. Mater. 2019, 31 (18) , 7584−7589.

2018

9. Qi Yin, Peng Zhao, Rong-Jian Sa, Guang-Cun Chen, Jian Lü, Tian-Fu Liu*, Rong Cao*, “An Ultra-Robust and Crystalline Redeemable Hydrogen-Bonded Organic Framework for Synergistic Chemo-Photodynamic Therapy,” Angew. Chem. Int. Ed. 2018, 57 (26) , 7691-7696.

8. Lan Li, Qi Yin, Hong-Fang Li, Tian-Fu Liu* and Rong Cao*, “Rational design of phosphonocarboxylate metal–organic frameworks for light hydrocarbon separations,” Mater. Chem. Front. 2018, 2, 1436-1440.

Before 2017

7. Tian-Fu Liu, Nicolaas A. Vermeulen, Ashlee J. Howarth, Peng Li, Amy A. Sarjeant, Joseph T. Hupp, Omar K. Farha*, “Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation,” Eur. J. Inorg. Chem. 2016, 27, 4349-4352.

6. Shuai Yuan†, Tian-Fu Liu† (equal contribution), Dawei Feng, Jian Tian, Kecheng Wang, Junsheng Qin, Qiang Zhang, Yingpin Chen, Mathieu Bosch, Lanfang Zou, Scott J. Dalgarno, Hong-Cai Zhou*, “A Single Crystalline Porphyrinic Titanium Metal−Organic Framework,” Chem. Sci. 2015, 6 (7), 3926-3930.

5. Dahuan Liu†, Tian-Fu Liu† (equal contribution), Ying-Pin Chen, Lanfang Zou, Dawei Feng, Kecheng Wang, Qiang Zhang, Shuai Yuan, Chongli Zhong, and Hong-Cai Zhou*, “A Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications,” J. Am. Chem. Soc. 2015, 137 (24), 7740-7746.

4. Tian-Fu Liu†, Dawei Feng† (equal contribution), Ying-Pin Chen, Lanfang Zou, Mathieu Bosch, Shuai Yuan, Zhangwen Wei, Stephen Fordham, Kecheng Wang, and Hong-Cai Zhou*, “Topology Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium MOFs with High Surface Area,” J. Am. Chem. Soc. 2015, 137 (1), 413-419.

3. Tian-Fu Liu, Lanfang Zou, Dawei Feng, Ying-Pin Chen, Stephen Fordham, Xuan Wang, Yangyang Liu, Hong-Cai Zhou*, “Stepwise Synthesis of Robust Metal-Organic Frameworks via Post-Synthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation,” J Am. Chem. Soc. 2014, 136 (22), 7813–7816.

2. Dawei Feng†, Tian-Fu Liu† (equal contribution), Jie Su, Mathieu Bosch, Zhangwen Wei, Wei Wan, Ying-Pin Chen, Xuan Wang, Kecheng Wang, Xizhen Lian, Zhi-Yuan Gu, Jihye Park, Daqiang Yuan, Xiaodong Zou, Hong-Cai Zhou*, “Stable Metal-Organic Frameworks Containing Single-Molecule Traps for Enzyme Encapsulation,” Nature Comm. 2014. 6, 5979.

1. Tian-Fu Liu, Ying-Pin Chen, Andrey A Yakovenko, Hongcai Zhou*, “An Interconversion between Discrete and a Chain of Nanocages: Self-Assembly via a Solvent-Driven, Dimension-Augmentation Strategy,” J. Am. Chem. Soc. 2012, 134 (42), 17358- 17361.