基本信息
林华  男  博导  中国科学院福建物质结构研究所
电子邮件: linhua@fjirsm.ac.cn
通信地址: 福建省福州市鼓楼区杨桥西路155号化学楼515室
邮政编码:

研究领域

无机硫属功能材料,包括中远红外非线性光学晶体以及热电材料等


招生信息

   
招生专业
070304-物理化学
070301-无机化学
招生方向
非线性光学晶体材料
热电材料

教育背景

2007-09--2012-07   中国科学院福建物质结构研究所物理化学专业(硕博连读)   博士学位
2002-09--2006-07   福州大学化学化工学院国家理科化学基地班专业   理学学士
学历
研究生

学位
博士

工作经历

   
工作简历
2020-01~现在, 中国科学院福建物质结构研究所, 研究员
2015-01~2019-12,中国科学院福建物质结构研究所, 副研究员
2012-07~2015-01,中国科学院福建物质结构研究所, 助理研究员

专利与奖励

   
专利成果
( 1 ) 红外非线性光学晶体AB4C5Se12, 发明, 2015, 第 2 作者, 专利号: ZL 201210535628.2
( 2 ) TmCuTe2化合物及其制备和用途, 发明, 2017, 第 2 作者, 专利号: ZL 201310174698.4
( 3 ) 一种制备CsBi4Te6热电材料的方法, 发明, 2017, 第 2 作者, 专利号: ZL 201510887234.7
( 4 ) 晶体材料、制备方法以及含有该晶体材料的热电材料、其制备方法及热电转换器和应用, 发明, 2018, 第 2 作者, 专利号: ZL 201510894693.8
( 5 ) 红外非线性光学晶体、其制备方法与用途, 发明, 2018, 第 1 作者, 专利号: 201810367156.1
( 6 ) 红外非线性光学晶体材料AZn4In5Se12及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: 201611073007.1
( 7 ) 一类中温热电晶体材料及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: 201710046540.7
( 8 ) 一类红外非线性光学晶体材料及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: 201710035153.3
( 9 ) 光学晶体AZn4Ga5S12 用作红外非线性光学材料的用途, 发明, 2017, 第 2 作者, 专利号: 201610704761.4
( 10 ) 红外非线性光学晶体CsZn4Ga5S12及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: 201610705013.8
( 11 ) 三元稀土铜碲晶体材料用作热电材料的用途, 发明, 2019, 第 2 作者, 专利号: ZL 201710035154.8
( 12 ) 一类红外非线性光学晶体材料及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: 201510915491.7
( 13 ) 一类红外非线性光学晶体材料及其制备方法和用途, 发明, 2017, 第 2 作者, 专利号: PCT/CN2016/082990
( 14 ) 一种热电材料、其制备方法及应用, 发明, 2018, 第 2 作者, 专利号: ZL 201410837415.4
( 15 ) 一种热电材料、其制备方法及应用, 发明, 2017, 第 2 作者, 专利号: PCT/CN2014/095376
( 16 ) 一种四元非心硫化物的晶体材料及其制备方法与应用, 发明, 2019, 第 1 作者, 专利号: 201910070129.2
( 17 ) 一种三元非心硫化物的晶体材料及其制备方法与应用, 发明, 2019, 第 1 作者, 专利号: 201910637822.3
( 18 ) 一种二维铋烯纳米片的制备方法及其应用, 发明, 2021, 第 3 作者, 专利号: ZL201911347043.6
( 19 ) 一种析氧电催化材料及其制备方法和应用, 发明, 2020, 第 4 作者, 专利号: 201910878053.6
( 20 ) 一种热电材料、其制备方法及应用, 发明, 2018, 第 2 作者, 专利号: JP 6457657
( 21 ) 一种热电材料、其制备方法及应用, 发明, 2019, 第 2 作者, 专利号: US 10,439,120
( 22 ) 一种叠氮基金属酞菁-碳基复合材料及其制备方法和应用, 发明, 2021, 第 3 作者, 专利号: ZL 202010507162.X
( 23 ) 一种过渡金属单原子材料及其制备方法和应用, 发明, 2020, 第 3 作者, 专利号: 202010409398.X
( 24 ) 一种非心混阴离子晶体材料及其制备方法与应用, 发明, 2020, 第 1 作者, 专利号: 202010450475.6
( 25 ) 一种析氢电催化材料及其制备方法和应用, 发明, 2020, 第 4 作者, 专利号: 202010834105.2

出版信息

   
发表论文
(1) Ultralow thermal conductivity in the quaternary semiconducting chalcogenide Cs4[Ho26Cd7Se48] with an unprecedented closed cavity architecture., Inorg. Chem. Front., 2021, 通讯作者
(2) Quaternary Chalcohalides CdSnSX2 (X = Cl or Br) with Neutral Layers: Syntheses, Structures, and Photocatalytic Properties., Inorg. Chem., 2021, 通讯作者
(3) Structural Modulation from Cu3PS4 to Cu5Zn0.5P2S8: Single-Site Aliovalent-Substitution-Driven Second-Harmonic-Generation Enhancement., Inorg. Chem., 2021, 通讯作者
(4) Recent progress in oxychalcogenides as IR nonlinear optical materials., Dalton Trans., 2021, 通讯作者
(5) A3Mn2Sb3S8 (A = K and Rb): A new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks., Inorg. Chem. Front., 2021, 通讯作者
(6) AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds., Inorg. Chem., 2021, 通讯作者
(7) Rb2CuSb7S12: Quaternary Antimony-Rich Semiconductor Featuring a Three-Dimensional Open Framework and Exhibiting an Intriguing Photocurrent Response., Inorg. Chem., 2021, 通讯作者
(8) M2As2Q5 (M = Ba, Pb; Q = S, Se): A source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions., J. Mater. Chem. C, 2021, 通讯作者
(9) Quaternary Selenophosphate Cs2ZnP2Se6 Featuring Unique One-dimensional Chains and Exhibiting Remarkable Photo-electrochemical Response., Chinese J. Struct. Chem., 2021, 通讯作者
(10) Rational design of infrared nonlinear optical chalcogenides by chemical substitution, Coord. Chem. Rev., 2020, 第 1 作者
(11) One-Dimensional Chains in Pentanary Chalcogenides A2Ba3Cu2Sb2S10 (A = K, Rb, Cs) Displaying a Photocurrent Response, Inorg. Chem., 2020, 通讯作者
(12) Two new members in the quaternary Cs-Ag-As-S family with different arrangements of Ag–S and As–S asymmetric building units: syntheses, structures, and theoretical studies., Dalton Trans., 2020, 通讯作者
(13) Salt-inclusion chalcogenides: an emerging class of IR nonlinear optical materials., Dalton Trans., 2020, 通讯作者
(14) A new type of novel salt-inclusion chalcogenides with ultralow thermal conductivity., Chem. Commun., 2020, 通讯作者
(15) Salt-Inclusion Chalcogenide [Ba4Cl2][ZnGa4S10]: Rational Design of an IR Nonlinear Optical Material with Superior Comprehensive Performance Derived from AgGaS2., Chem. Mater., 2020, 通讯作者
(16) Partial Isovalent Anion Substitution to Access Remarkable Second-Harmonic Generation Response: A Generic and Effective Strategy for Design of Infrared Nonlinear Optical Materials., Chem. Mater., 2020, 通讯作者
(17) HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure., Chem. Mater., 2020, 通讯作者
(18) Dimensionality Reducing from Three-dimensional RbLu5Te8 to Two-dimensional CsMnGdTe3: Syntheses, Crystal and Electronic Structures., Chinese J. Struct. Chem., 2020, 通讯作者
(19) Combined experimental and theoretical investigations of Ba3GaS4I: interesting structural transformation originated from halogen substitution, Dalton Trans., 2019, 通讯作者
(20) Sn2Ga2S5: A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs, Chem. Mater., 2019, 通讯作者
(21) Quaternary semiconductor Ba8Zn4Ga2S15 featuring unique one-dimensional chains and exhibiting desirable yellow emission, Chem. Commun., 2019, 通讯作者
(22) Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials, Cryst. Growth Des., 2019, 通讯作者
(23) Impressive second harmonic generation response in a novel phase-matchable NLO-active MOF derived from achiral precursors, J. Mater. Chem. C, 2019, 通讯作者
(24) [(Ba19Cl4)(Ga6Si12O42S8)]: a Two-Dimensional Wide-Band-Gap Layered Oxysulfide with Mixed-Anion Chemical Bonding and Photocurrent Response, Inorg. Chem., 2019, 通讯作者
(25) Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials, J. Mater. Chem. C, 2019, 第 1 作者
(26) Solid-State Preparation, Structural Characterization, Physical Properties, and Theoretical Studies of a Series of Novel Rare-Earth Metal Chalcogenides with Unprecedented Closed-Cavities, Cryst. Growth Des., 2019, 通讯作者
(27) An unprecedented pentanary chalcohalide with Mn atoms in two chemical environments: unique bonding characteristics and magnetic properties, Chem. Commun., 2019, 通讯作者
(28) Modifying Disordered Sites with Rational Cations to Regulate Band- Gaps and Second Harmonic Generation Responses Markedly: Ba6Li2ZnSn4S16 vs Ba6Ag2ZnSn4S16 vs Ba6Li2.67Sn4.33S16, Cryst. Growth Des., 2018, 通讯作者
(29) Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework, Inorg. Chem., 2018, 通讯作者
(30) Evidence for Itinerant Carriers in Anisotropic Narrow-gap Semiconductor by Angle-Resolved Photoemission Spectroscopy, Adv. Mater., 2018, 第 4 作者
(31) Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg2GeS4 and BaAg2SnS4, Dalton Trans., 2018, 通讯作者
(32) Quaternary Layered Semiconductor Ba2Cr4GeSe10: Synthesis, Crystal Structure and Thermoelectric Property, Inorg. Chem., 2018, 通讯作者
(33) Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance, Inorg. Chem. Front., 2018, 第 1 作者
(34) Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matcha-bility Controlled by Dipole Moment of the Asymmetric Building Unit, Chem. Mater., 2017, 第 1 作者
(35) Ba5Cu8In2S12: a quaternary semiconductor with unique 3D copper-rich framework and ultralow thermal conductivity, Chem. Commun., 2017, 第 1 作者
(36) Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A = K, Rb, Cs) with 3D Diamond-like Frameworks, Chem.-Eur. J., 2017, 第 1 作者
(37) Non-centrosymmetric Selenides AZn4In5Se12 (A = Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties, Chem. Asian J., 2017, 第 1 作者
(38) Syntheses, Structures, and Thermoelectric Properties of Ternary Tellurides: RECuTe2 (RE = Tb–Er), Inorg. Chem. Front., 2017, 第 1 作者
(39) Two excellent phase-matchable infrared nonlinear-optical materials based on the 3D diamond-like frameworks: RbGaSn2Se6 and RbInSn2Se6, Dalton Trans., 2017, 第 1 作者
(40) Two new phases in the ternary RE–Ga–S systems with unique interlinkage of GaS4 building units: synthesis, structure, and properties, Dalton Trans., 2017, 第 1 作者
(41) Enhanced thermoelectric performance in ternary spinel Cu4Mn2Te4 via synergistic effect of tellurium-deficiency and chlorine-doping, Dalton Trans., 2017, 通讯作者
(42) Syntheses and characterization of three new sulfides with large band gaps: acentric Ba4Ga4SnS12, centric Ba12Sn4S23 and Ba7Sn3S13, Dalton Trans., 2017, 通讯作者
(43) KBa2(PO3)5: Properties and Comparison With Isostructural Polyphosphate Compounds., Chinese J. Struct. Chem., 2017, 通讯作者
(44) Synthesis, Crystal Structure, Physical Properties and Theoretical Studies of New Ternary Sulfide with Closed Cavities: CsYb7S11, Chinese J. Struct. Chem., 2017, 通讯作者
(45) Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance, Angew. Chem. Int. Ed., 2016, 第 1 作者
(46) Cs6Cl)6Cs3[Ga53Se96]: A Unique Long Period-Stacking Structure of Layers Made from Ga2Se6 Dimers via Cis or Trans Intralayer Linking, Inorg. Chem., 2016, 第 1 作者
(47) Strong Infrared NLO Tellurides with Multifunction: CsXII4In5Te12 (XII = Mn, Zn, Cd), Inorg. Chem., 2016, 第 1 作者
(48) Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE9Cd4Se18] (RE = Tb–Tm), Dalton Trans., 2016, 第 1 作者
(49) CsBi4Te6: a new facile synthetic method and mid-temperature thermoelectric performance, Dalton Trans., 2016, 第 1 作者
(50) AXII4XIII5Te12 (A = Rb, Cs; XII = Mn, Zn, Cd; XIII = Ga, In): quaternary semiconducting tellurides with very low thermal conductivities, Dalton Trans., 2016, 第 1 作者
(51) Chemical Modification and Energetically Favorable Atomic Disorder of a Layered Thermoelectric Material TmCuTe2 Leading to High Performance, Chem.-Eur. J., 2014, 第 1 作者
(52) Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12, J. Am. Chem. Soc., 2013, 第 1 作者
(53) Quaternary Supertetrahedra-Layered Telluride CsMnInTe3: Why Does This Type of Chalcogenide Tilt?, Inorg. Chem., 2013, 第 1 作者
(54) Synthesis, Structure, and Property of a Three-dimensional Channel Quaternary Compound: Cs0.75(6)Er4.43(5)In3.32(6)S12, Chinese J. Struct. Chem., 2013, 通讯作者
(55) Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A = K, Rb, Cs), Chem. Mater., 2012, 第 1 作者
(56) Diverse Closed Cavities in Condensed Rare Earth Metal–Chalcogenide Matrixes: Cs[Lu7Q11] and (ClCs6)[RE21Q34] (RE = Dy, Ho; Q = S, Se, Te), Inorg. Chem., 2012, 第 1 作者
(57) Quaternary Rare-Earth Selenides with Closed Cavities: Cs[RE9Mn4Se18] (RE = Ho–Lu), Inorg. Chem., 2012, 第 1 作者
(58) Syntheses, Structure, Physical Properties, and Electronic Structures of DyCuxAl12-x (4.0 ≤ x ≤ 6.0), Eur. J. Inorg. Chem., 2011, 第 1 作者
(59) 
发表著作
(1) Inorganic Chalcogenides: From Zero-Dimensional Clusters to Three-Dimensional Frameworks in Advanced Structural Chemistry: Tailor Made, Properties and Applications of Inorganic Materials, Volume 2, Chapter 9, 465–530, Wiley, 2021-04, 第 1 作者

科研活动

   
科研项目
( 1 ) 三维类金刚石网格硫属化合物的探索合成,晶体生长及非线性光学性能研究, 主持, 国家级, 2018-01--2021-12
( 2 ) 三元 RE/Cu/Te化合物的探索合成和热电性质研究, 主持, 国家级, 2014-01--2016-12
( 3 ) 窄带隙硫属半导体化合物的设计合成及热电性能研究, 主持, 省级, 2015-04--2018-04
( 4 ) 新颖混金属红外非线性光学材料的结构设计,固相合成及性能研究, 主持, 省级, 2019-07--2022-12
( 5 ) 类金刚石构型中远红外非线性光学晶体的结构设计与晶体生长, 主持, 省级, 2021-03--2023-02