General

Kaijun Yuan  PhD supervisor Dalian Institute of chemical Physics, CAS,China

address: 457 Zhongshan Road, dalian,China

Tel: 13840826033/0411-84379657

email:kjyuan@dicp.ac.cn

 

Research Areas

Photochemistry of small molecules in gas phase by using VUV FEL laser,focus on H2O, CO2, H2, H2S ,CO photochemistry

Ultrafast two-dimensional infrared spectroscopy to study ultrafast dynamics in the condensed phases, like hydrogen-bonding dynamics, isomerization, energy transfer, and photon-to-heat transfer

UV/vis transient spectroscopy at extremely high pressure (1000-100000 atm), focus on nano-materials, energy related materials, and 2D materials


Education

09/2003-01/2009, Dalian Institute of Chemical Physics, PhD, supervisor: Xueming Yang

09/1999-07/2003, University of Science and Technology of China (USTC), Bachelor

Experience

   
Work Experience

Dalian Institute of Chemical Physics, CAS 

07/2017-Now,    Professor in State Key Laboratory of Molecular Reaction Dynamics

09/2011-06/2017, Associate Professor in State Key Laboratory of Molecular Reaction Dynamics

05/2009-08/2011, Assistant Professor in State Key Laboratory of Molecular Reaction Dynamics


Publications

1.       Zhou, J. M.; Zhao, Y. R.; Hansen, C. S.; Yang, J. Y.; Chang, Y.; Yu, Y.; Cheng, G. K.; Chen, Z. C.; He, Z. G.; Yu, S. R.; Ding, H. B.; Zhang, W. Q.; Wu, G. R.; Dai, D. X.; Western, C. M.; Ashfold, M. N. R.; Yuan, K. J.; Yang, X. M. Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium. Nat Commun 2020, 11,1547.

2.    Zhou, J. M.; Luo, Z. J.; Yang, J. Y.; Chang, Y.; Zhang, Z. G.; Yu, Y.; Li, Q. M.; Cheng, G. K.; Chen, Z. C.; He, Z. G.; Che, L.; Yu, S. R.; Wu, G. R.; Yuan, K. J.; Yang, X. M. State-to-state photodissociation dynamics of CO2 around 108 nm: the O(S-1) atom channel. Phys Chem Chem Phys 2020, 22, 6260-6265.

3.   Zhan, Q.; Yan, L.; Yang, M. S.; Wu, G. R.; Hu, M. J.; Li, J. B.; Yuan, K. J.; Yan, X. M. Ultrafast Transient Spectra and Dynamics of MXene (Ti3C2Tx) in Response to Light Excitations of Various Wavelengths. J Phys Chem C 2020, 124, 6441-6447.

4.   Chang, Y.; Zhou, J. M.; Luo, Z. J.; Chen, Z. C.; He, Z. G.; Yu, S. R.; Che, L.; Wu, G. R.; Wang, X. G.; Yuan, K. J.; Yang, X. M. Photodissociation dynamics of H2O and D2O via the (D)over-tilde((1)A(1)) electronic state. Phys Chem Chem Phys 2020, 22, 4379-4386.

5.   Liu, K. K.; Song, S. Y.; Sui, L. Z.; Wu, S. X.; Jing, P. T.; Wang, R. Q.; Li, Q. Y.; Wu, G. R.; Zhang, Z. Z.; Yuan, K. J.; Shan, C. X. Efficient Red/Near-Infrared-Emissive Carbon Nanodots with Multiphoton Excited Upconversion Fluorescence. Adv Sci 2019, 6.

6.   Li, J. B.; Zhang, Q.; Yan, L.; Wu, G. R.; Hu, M. J.; Lin, X. B.; Yuan, K. J.; Yang, X. M. Ultrafast Flash Energy Conductance at MXene-Surfactant Interface and Its Molecular Origins. Adv Mater Interfaces 2019, 6.

7.   Jiang, H. T.; Zhang, Q.; Zhang, Y. T.; Sui, L. Z.; Wu, G. R.; Yuan, K. J.; Yang, X. M. Li-Ion solvation in propylene carbonate electrolytes determined by molecular rotational measurements. Phys Chem Chem Phys 2019, 21, 10417-10422.

8.   Deng, G. H.; Shen, Y. N.; Chen, H. L.; Chen, Y. J.; Jiang, B.; Wu, G. R.; Yang, X. M.; Yuan, K. J.; Zheng, J. R. Ordered-to-Disordered Transformation of Enhanced Water Structure on Hydrophobic Surfaces in Concentrated Alcohol-Water Solutions. J Phys Chem Lett 2019, 10, 7922-7928.

9.   Chen, W. T.; Zhang, L.; Yuan, D. F.; Chang, Y.; Yu, S. R.; Wang, S. W.; Wang, T.; Jiang, B.; Yuan, K. J.; Yang, X. M.; Wang, X. A. Observation of the Carbon Elimination Channel in Vacuum Ultraviolet Photodissociation of OCS. J Phys Chem Lett 2019, 10, 4783-4787.

10.   Chang, Y.; Chen, Z. C.; Zhou, J. M.; Luo, Z. J.; He, Z. G.; Wu, G. R.; Ashfold, M. N. R.; Yuan, K. J.; Yang, X. M. Striking Isotopologue-Dependent Photodissociation Dynamics of Water Molecules: The Signature of an Accidental Resonance. J Phys Chem Lett 2019, 10, 4209-4214.

11.   Y. Chang#, Y. Yu#, H. L. Wang#, X. Hu*, Q. M. Li, J. Y. Yang, S. Su, Z. G. He, Z. C. Chen, L. Che, X. A. Wang, W. Q. Zhang, G. R. Wu, D. Q. Xie, M. N. R. Ashfold, K. J. Yuan*, X. M. Yang*, Hydroxyl super rotors from vacuum ultraviolet photodissociation of water. Nat. Comm. 2019, 10, 1250.

12.   B. Jiang#, V. Ponnuchamy#*, Y. N. Shen#, X. M. Yang, K. J. Yuan*, V. Vetere, S. Mossa, I. Skarmoutsos*, Y. F. Zhang, J. R. Zheng*, The Anion Effect on Li+ Ion Coordination Structure in Ethylene Carbonate Solutions. J. Phys. Chem. Lett. 2016, 7, 3554-3559.

13.   S. R. Yu, S. Su, K. J. Yuan*, D. X. Dai, X. M. Yang*, Observation of Extremely High Vibrational Excitation in O2 from Inelastic Scattering of Rydberg H Atom with O2. J. Phys. Chem. Lett. 2012, 3, 2420-2424.

14.   K. J. Yuan, Y. Cheng, L. Cheng, Q. Guo, D. X. Dai, X. Y. Wang, X. M. Yang*, R. N. Dixon*, Nonadiabatic dissociation dynamics in H2O: Competition between rotationally and nonrotationally mediated pathways. P. Natl. Acad. Sci .U.S.A. 2008, 105, 19148-19153.

15.  K. J. Yuan, Y. Cheng, X. H. Liu, S. Harich, X. M. Yang*, D. H. Zhang*, Experimental and quantum dynamical study on an asymmetric insertion reaction: State-to-state dynamics of O(1D)+HD(1Σg+), v'=0, j'=0)-> OH(2П, v'', N'')+D(2S). Phys. Rev. Lett. 2006, 96, 103202.

16.   H. L. Wang#, Y. Yu#, Y. Chang, S. Su, S. R. Yu, Q. M. Li, K. Tao, H. L. Ding, J. Y. Yang, G. L. Wang, L. Che*, Z. G. He, Z. C. Chen, X. A. Wang*, W. Q. Zhang, D. X. Dai, G. R. Wu, K. J. Yuan*, X. M. Yang*, Photodissociation dynamics of H2O at 111.5 nm by a vacuum ultraviolet free electron laser. J. Chem. Phys. 2018, 148, 124301. (Editor’s Pick).

17.   S. R. Yu, K. J. Yuan*, H. Song, X. Xu, D. X. Dai, D. H. Zhang, X. M. Yang*, State-to-state differential cross-sections for the reactive scattering of H*(n) with o-D2. Chem. Sci. 2012, 3, 2839-2842 .

18.   K. J. Yuan, R. N. Dixon, X. M. Yang*, Photochemistry of the Water Molecule: Adiabatic versus Nonadiabatic Dynamics. Acc. Chem. Res. 2011, 44, 369-378. (cover paper)

19.   Y. A. Cheng, K. J. Yuan*, L. N. Cheng, Q. Guo, D. X. Dai, X. M. Yang*, Photodissociation dynamics of H2O: Effect of unstable resonances on the B1A1 electronic state. J. Chem. Phys. 2011, 134, 064301. (Editor’s Choice).

      20.   Y. W. Zhang, K. J. Yuan*, S. R. Yu, X. M. Yang*, Highly Rotationally Excited CH3 from Methane Photodissociation          through  Conical Intersection Pathway. J. Phys. Chem. Lett. 2010, 1, 475-479.


Research Interests

The primary interests in our group are to investigate the structure and chemical behavior of free radicals, and to provide microscopic details of primary photodissociation and bimolecular reaction processes. These objectives are achieved with a range of versatile experimental approaches using H atom Rydberg “tagging” TOF, molecular beam, etc. We try to explore new phenomena and to seek the fundamental understanding of chemical reactivity at the molecular level.


Honors & Distinctions

2013 Lu Jiaxi Young Scientist Award of Chinese Academy of Sciences

2010 Outstanding Thesis Awards of Chinese Academy of Sciences

2009 Zhuli Yuehua (朱李月华) Award for Chinese Excellent Graduate Student

2008 Excellent Graduate Student & Graduate Students’ Leader of CAS