基本信息
耿延候 男 汉族 博导 长春应用化学研究所
电子邮件:yhgeng@ciac.jl.cn
联系电话:0431-85262918
通信地址:长春市人民大街5625号
邮政编码:130022

研究领域

1、纳米尺度共轭齐聚物/聚合物的合成方法及其超分子化学;

2、共轭高分子合成方法学;

3、新型芳香单元及其共轭聚合物;

4、高迁移率有机/高分子半导体材料。

教育背景

   
学历

1991.09.05-1996.11.26  中国科学院长春应化所 博士研究生毕业

1987.09.01-1991.07.01  上海交通大学高分子科学专业 本科毕业

 

学位

1991.09.05-1996.11.26  中国科学院长春应化所 博士

1987.09.01-1991.07.01  上海交通大学高分子科学专业 学士


出国学习工作

2000.04-2003.08   美国 Rochester大学,访问学者

1998.10-2000.03   德国马普高分子研究所,洪堡学者
1998.04-1998.08  香港科技大学化学系,访问学者

工作经历

   
工作简历

1996.12-1998.10 中国科学院长春应用化学研究所,助理研究员
2003.09-至今      中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,研究员

教授课程

有机光电材料与器件

专利与奖励

一种有机半导体材料及使用该材料的有机薄膜晶体管  耿延候,田洪坤 中国 发明  2012-7-11 
一种可溶性酞菁化合物、其制备方法及一种有机薄膜晶体管 耿延候,董少强,田洪坤 国际专利 发明 2012-9-19 
化合物、聚合物、聚合物半导体材料及有机薄膜晶体管 耿延候,陈亚刚,田洪坤 中国 发明 2012-5-18
奖励信息

中科院百人计划结题评估优秀(2007年)

第九届吉林省青年科技奖(2007年)

国家杰出青年科学基金(2005年)

吉林省杰出青年科学基金(2004年)

中科院百人计划2003年)

德国洪堡奖学金(1998年)

专利成果
(1) 以菲为构造基元的一系列齐聚物和其制备方法,发明,2007,专利号:ZL 200510016895.9
(2) 稠环单元封端的齐聚噻吩类高迁移率有机半导体材料及用途,发明,2008,专利号:ZL 200510119064.4
(3) 一种聚(9,9-二烷基芴)的制备方法,发明,2009,专利号:ZL 200710055796.0
(4) 菲/噻吩杂化高迁移率有机半导体及其应用,发明,2007,专利号:ZL 200510119001.9
(5) 以9,10–二炔蒽为构造单元系列可溶性齐聚物及制备方法,发明,2008,专利号:ZL 200610016677.X
(6) 酞菁化合物及有机薄膜晶体管,发明,2010,第1作者,专利号:201010520550.8
(7) 一种有机半导体材料及使用该材料的有机薄膜晶体管,发明,2010,第1作者,专利号:201010118172.0
(8) 聚合物半导体材料和有机薄膜晶体管,发明,2011,第1作者,专利号:201110088350.4

出版信息

   
发表论文
(1) The First Soluble Conjugated Poly(2,6-anthrylene): Synthesis and Properties,Chemical Communication,
(2) Macromonomer Approach toward Fluorene-Based Monodisperse Conjugated Polymers,Macromolecules,
(3) Novel Highly Stable Semiconductors Based on Phenanthrene for Organic Field-Effect Transistors,Chemical Communication,
(4) Naphthyl End-Capped Quarterthiophene: A Simple Organic Semiconductor with High Mobility and Air Stability,Advanced Materials,
(5) Synthesis and Chain-Length Dependent Properties of Monodisperse Oligo(9,9-Di-n-Octylfluorene-2,7-Vinylene)s,Macromolecules,
(6) Synthesis and Characterization of Monodisperse Oligo(fluorene-cobithiophene)s,Chemistry-A European Journal,
(7) Naphthyl and Thionaphthyl End-Capped Oligothiophenes as Organic Semiconductors: Effect of Chain Length and End-Capping Groups,Advanced Functional Materials,
(8) Synthesis and Characterization of Coil-Rod-Coil Triblock Copolymers Comprising Fluorene-Based Mesogenic Monondisperse Conjugated Rod and Poly(ethylene oxide) Coil,Macromolecules,
(9) An Easily Made Thienoacene Comprising Seven Fused Rings for Ambient-Stable Organic Thin Film Transistors,Org. Electronics,2012,通讯作者
(10) An asymmetric conjugated oligomer based on thienoacene for solution processed single crystal organic thin-film transistors,Chem. Commun,2012,通讯作者
(11) Effect of End Groups on Optoelectronic Properties of Poly(9,9-dioctylfluorene): A Study with Hexadecylfluorenes as Model Polymers,J. Phys. Chem. C,2012,通讯作者
(12) Novel Conjugated Polymers Based on Dithieno[3,2-b:6,7-b]carbazole for Solution Processed Thin-Film Transistors,Macromol. Rapid Commun,2012,通讯作者
(13) Controlled Synthesis of Polyfluorenes via Kumada Catalyst Transfer Polycondensation with Ni(acac)2/dppp as the Catalyst,Macromolecules,2012,通讯作者
(14) Donor-Acceptor Conjugated Polymers with Dithienocarbazoles as Donor Units: Effect of Structure on Semiconducting Properties,Macromolecules,2012,通讯作者
(15) 基于含硫芳杂稠环化合物的可溶性共轭齐聚物的合成、表征及其在有机薄膜晶体管中的应用,分子科学学报,2012,通讯作者
(16) Non-Peripheral Tetrahexyl-Substituted Vanadyl Phthalocyanines with Intermolecular Cofacial π – π Stacking for Solution-Processed Organic Field-Effect Transistors,Advanced Materials,2011,通讯作者
(17) Conjugated Polymers Based on a S- and N-Containing Heteroarene:Synthesis, Characterization, and Semiconducting Properties,Macromolecules,2011,通讯作者
(18) Iterative Binomial Synthesis of Monodisperse Polyfluorenes up to 64-mers and Their Chain-Length-Dependent Properties,Macromolecules,2011,通讯作者
(19) 二噻吩并吡咯一苯并噻二唑D-A型共轭齐聚物的合成、表征及其在体相异质结太阳能电池中的应用,分子科学学报,2011,通讯作者
(20) Novel Liquid Crystalline Conjugated Oligomers Based on Phenanthrene for Organic Thin Film Transistors,Journal of Material Chemistry,2011,通讯作者
(21) Micellar Nanoparticles of Coil_Rod_Coil Triblock Copolymers for Highly Sensitive and Ratiometric Fluorescent Detection of Fluoride Ions,Macromolecules,2011,通讯作者
(22) LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the “Reversed” Thiophene Monomer,Macromolecules,2011,通讯作者
(23) Improve on/off ratio of organic heterojunction transistors by adopting single-sandwich configuration,SOLID-STATE ELECTRONICS,2011,第5作者
(24) Bulk Heterojunction Photovoltaic Cells with Low Donor Concentration,Advanced Materials,2011,第4作者
(25) Phthalocyanine derivatives for solution-processed organic thin-film transistors,Proceedings of SPIE,2011,通讯作者
(26) Donor-Acceptor Liquid Crystalline Conjugated Cooligomers for the Preparation of Films with the Ideal Morphology for Bulk Heterojunction Solar Cells,Polymer,2011,通讯作者
(27) X- and H-shape two dimensional conjugated oligomers with anthracene as the node,Chemistry-An Asian J.,2010,通讯作者
(28) A feasibly synthesized ladder-type conjugated molecule as the novel high mobility n-type organic semiconductor ,J. Mater. Chem.,2010,通讯作者
(29) Kumada chain-growth polycondensation as a universal method for synthesis of welL-defined conjugated polymers,Sci. China Chem.,2010,第1作者
(30) Grignard metathesis chain-growth polymerization for poly(bithienylmethylene)s: Ni catalyst can transfer across the nonconjugated monomer,Macromolecules,2010,通讯作者
(31) Alkyl substituted [6,6]-thienyl-C-61-butyric acid methyl esters: easily accessible acceptor materials for bulk-heterojunction polymer solar cells ,J. Mater. Chem.,2010,通讯作者
(32) Novel NIR-absorbing conjugated polymers for efficient polymer solar cells: effect of alkyl chain length on device performance,Journal of Materials Chemistry,2009,通讯作者
(33) The first liquid crystalline phthalocyanine derivative capable of edge-on alignment for solution processed organic thin-film transistors,Chemical Communications,2009,通讯作者
(34) Poly(oligothiophene-alt-benzothiadiazole)s Tuning the Structures of Oligothlophene Units toward High-Mobility Black Conjugated Polymers,Macromolecules ,2009,通讯作者
(35) Synthesis and Characterization of Soluble Oligo(9,10-Bisalkynylanthrylene)s,Organic Letter,2009,通讯作者
(36) Novel spiro-fluorenes from tandem radical addition for liquid crystalline monodisperse conjugated oligomers,Journal of Materials Chemistry,2009,通讯作者
(37) Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor-Acceptor Lamellae,Journal of the American Chemical Society,2009,通讯作者
(38) Synthesis and characterization of phenylene-thiophene all-conjugated diblock copolymers,POLYMER,2009,通讯作者
(39) Synthesis and Characterizations of Poly(9,10-bisarylethynyl-2,6-anthrylene)s and Poly(9,10-bisalkynyl-2,6-anthrylene),Macromolecules ,2009,通讯作者
(40) Grignard Metathesis Chain-Growth Polymerization for Polyfluorenes,Macromolecules ,2008,通讯作者
(41) Crystal packing motifs of oligothiophenes end-capped with N-containing aryls,Crystal Growth Design,2008,通讯作者
(42) Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s,Organic Letter,2008,通讯作者
(43) Grignard Metathesis Chain-Growth Polymerization for Polyfluorenes,Macromolecules,2008,通讯作者
(44) Synthesis and characterization of monodisperse oligo(fluorene-co-bithiophene)s,Chemistry-A European Journal ,2007,通讯作者
(45) Novel highly stable semiconductors based on phenanthrene for organic field-effect transistors,Chemical Communications,2006,通讯作者
(46) Synthesis and characterization of soluble oligo (9,10-bisalkynylanthrylene)s,Organic Letters,2006,通讯作者
(47) Synthesis of fluorene-based oligomeric organoboron reagents via Kumada, Heck, and stille cross-coupling reactions,Journal of Organic Chemistry ,2006,通讯作者
(48) Novel thiophene-aryl co-oligomers for organic thin film transistors,Journal of Materials Chemistry,2005,通讯作者

科研活动

   
科研项目

        国家自然科学基金委员会杰出青年基金、重点基金、面上基金、创新研究群体基金 (20521415, 20674083, 2062140150833004); 科技部973 项目(2009CB6236032009CB930603)。

参与会议
(1) Construction of “Ideal” Bulk-Heterojunction Nanostructured Films from Liquid Crystalline Donor-Acceptor Monodisperse Conjugated Oligomers,2010-12,耿延候
(2) Chain Growth Polymerization for Conjugated and Nonconjugated Polymers,2010-10,耿延候
(3) Donor-Acceptor (D-A) 型单分散共轭液晶齐聚物及其组装结构,2010年两岸三地高分子液晶态与超分子有序结构学术研讨会,2010-08,耿延候
(4) GRIM Chain-Growth Polymerization for Conjugated Polymers,2010-07,耿延候
(5) Kumada Chain-Growth Polycondensation for Conjugated and Unconjugated Polymers,2010-06,耿延候
(6) Conjugated oligomers capable of forming well-defined nanostructured films for high performance single-molecular organic solar cells,2010-03,耿延候

合作情况

   
项目协作单位
   

指导学生

已指导学生

田洪坤   博士研究生  070305-高分子化学与物理  

刘勤  博士研究生  070305-高分子化学与物理  

岳威  博士研究生  070305-高分子化学与物理  

崔维斌  博士研究生  070305-高分子化学与物理  

杨宝麟  硕士研究生  070305-高分子化学与物理  

卜腊菊  博士研究生  070305-高分子化学与物理  

何博  博士研究生  070305-高分子化学与物理  

黄鹂  博士研究生  070305-高分子化学与物理  

赵慧宇  博士研究生  070305-高分子化学与物理  

韩洋  硕士研究生  070305-高分子化学与物理  

现指导学生

吴书鹏  博士研究生  070305-高分子化学与物理  

邓云峰  硕士研究生  070305-高分子化学与物理  

隋爱国  硕士研究生  070305-高分子化学与物理  

王麒麟  博士研究生  070305-高分子化学与物理  

陈亚刚  博士研究生  070305-高分子化学与物理  

邵静  硕士研究生  070305-高分子化学与物理  

王磊  硕士研究生  070305-高分子化学与物理  

董少强  博士研究生  070305-高分子化学与物理  

曲建飞  博士研究生  070305-高分子化学与物理