基本信息
孟繁柯  男  博导  中国科学院上海有机化学研究所
电子邮件: mengf@sioc.ac.cn
通信地址: 上海市徐汇区零陵路345号
邮政编码: 200032

招生信息

   
招生专业
070303-有机化学
招生方向
不对称催化,有机硼化学,过渡金属催化,钴催化

教育背景

2010-09--2015-12   Boston College   博士
2006-09--2010-06   北京大学   学士

工作经历

   
工作简历
2016-01~2016-08,Boston College, 博士后

专利与奖励

   
奖励信息
(1) 2019 Thieme Chemistry Journals Award, 其他, 2019
(2) Bristol-Myers Squibb Fellowship in Synthetic Organic Chemistry, 其他, 2014
(3) 国家优秀自费留学生奖学金, 国家级, 2014
(4) John LaMattina Graduate Fellowship, 研究所(学校), 2013
(5) 曾宪梓奖学金, 研究所(学校), 2007

出版信息

   
发表论文
(1) Cobalt-Catalyzed Sequential Site- and Stereoselective Hydrosilylation of 1,3- and 1,4-Enynes, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 通讯作者
(2) Cobalt-Catalyzed Regio-, Diastereo- and Enantioselective Intermolecular Hydrosilylation of 1,3-Dienes with Prochiral Silanes, Angewandte Chemie International Edition, 2022, 通讯作者
(3) Cobalt-catalyzed diastereo- and enantioselective allyl addition to aldehydes and α-ketoesters through allylic C–H functionalization, Cell Reports Physical Science, 2021, 通讯作者
(4) Cobalt-Catalyzed Diastereo- and Enantioselective Reductive Allyl Additions to Aldehydes with Allylic Alcohol Derivatives via Allyl Radical Intermediates, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 通讯作者
(5) Cobalt-Catalyzed Diastereo- and Enantioselective Hydroalkylation of Cyclopropenes with Cobalt Homoenolates, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 通讯作者
(6) Cobalt-catalyzed atom-economical, diastereo- and enantioselective coupling of aldimines and cyclopropanols, SCIENCE CHINA-CHEMISTRY, 2021, 通讯作者
(7) How Solvents Control the Stereospecificity of Ni-Catalyzed Miyaura Borylation of Allylic Pivalates, ACS CATALYSIS, 2019, 通讯作者
(8) Cobalt-Catalyzed Diastereo- and Enantioselective Hydroalkenylation of Cyclopropenes with Alkenylboronic Acids, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 通讯作者
(9) Cu-Catalyzed Enantioselective Reductive Coupling of 1,3-Dienes and Aldimines, ORGANIC LETTERS, 2018, 通讯作者
(10) Cu-catalyzed regioselective borylcyanation of 1,3-dienes, CHEMICAL COMMUNICATIONS, 2018, 通讯作者
(11) Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and their in situ addition to carbonyl compounds, CHEMICAL SCIENCE, 2018, 通讯作者
(12) N-Heterocyclic Carbene-Cu-Catalyzed Enantioselective Allenyl Conjugate Addition, ORGANIC LETTERS, 2018, 通讯作者
(13) Copper-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Alkenes: Method Development, Applications and Mechanistic Studies, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 通讯作者
(14) Cu-Catalyzed Enantioselective Hydroboration of 1,1-Disubstittuted Alkenes: Method Development, Applications and Mechanistic Studies, Asian Journal of Organic Chemistry, 2018, 通讯作者
(15) N-Heterocyclic Carbene–Cu-Catalyzed Enantioselective Conjugate Addition with Alkenylboronic Esters as Nucleophiles, ACS Catalysis, 2017, 通讯作者
(16) N-heterocyclic Carbene-Cu-Catalyzed Enantioselective Conjugate Additions with Alkenylboronic Esters as Nucleophiles, ACS CATALYSIS, 2017, 通讯作者
(17) Cu-Catalyzed Enantioselective Boron Addition to N-Heteroaryl-Substituted Alkenes, ORGANIC LETTERS, 2017, 通讯作者
(18) Catalytic Enantioselective 1,6-Conjugate Additions of Propargyl and Allyl Group, Nature, 2016, 第 1 作者
(19) Multicomponent Catalytic Enantioselective Conjugate Addition Reactions Involving Allylcopper Intermediates Derived from Butadiene and Isoprene, Angewandte Chemie International Edition, 2016, 第 1 作者
(20) Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 第 2 作者
(21) Cu-catalyzed chemoselective synthesis of 2-boron-substituted allylcopper complexes and their in situ site-, diastereo- and enantioselective additions to carbonyls, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 第 1 作者
(22) Multifunctional organoboron compounds for scalable natural product synthesis, NATURE, 2014, 第 1 作者
(23) Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron,1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–CuComplex, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 第 1 作者
(24) Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their InSitu Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 第 1 作者
(25) NHC–Cu-Catalyzed Protoboration of Mono-Substituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism, ORGANIC LETTERS, 2013, 第 1 作者
(26) Exceptionally E- and β-Selective NHC–Cu- Catalyzed Proto-Silyl Addition to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes, Chemistry-A European Journal, 2013, 第 1 作者
(27) Diastereoselective Total Synthesis of (+/-)-Schindilactone A, Part 3: The Final Phase and Completion, CHEMISTRY-AN ASIAN JOURNAL, 2012, 第 8 作者
(28) Diastereoselective Total Synthesis of (+/-)-Schindilactone A, Part 2: Construction of the Fully Functionalized CDEFGH Ring System, CHEMISTRY-AN ASIAN JOURNAL, 2012, 第 6 作者
(29) Diastereoselective Total Synthesis of (+/-)-Schindilactone A, Part 1: Construction of the ABC and FGH Ring Systems and Initial Attempts to Construct the CDEF Ring System, CHEMISTRY-AN ASIAN JOURNAL, 2012, 第 7 作者
(30) Diastereoselective Total Synthesis of (+/-)-Schindilactone A, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 第 8 作者
(31) Direct Imidation to Construct 1H-Benzodimidazole through Pd-II-Catalyzed C-H Activation Promoted by Thiourea, CHEMISTRY-A EUROPEAN JOURNAL, 2009, 第 4 作者

科研活动

   
科研项目
( 1 ) 金属配合物结构设计与小分子活化, 参与, 中国科学院计划, 2017-02--2020-02
( 2 ) 中科院****C类, 负责人, 中国科学院计划, 2017-02--2019-02
( 3 ) 不对称自由基反应, 负责人, 研究所自选, 2016-08--2018-08
( 4 ) 不对称自由基反应, 负责人, 研究所自选, 2017-02--2019-02
( 5 ) 青年****, 负责人, 国家任务, 2017-05--2019-05
( 6 ) 铜催化利用原位生成手性金属中间体构建季碳中心的不对称多组分反应, 负责人, 国家任务, 2018-01--2020-12
( 7 ) 廉价金属催化的含氮杂环取代烯烃的不对称转化, 负责人, 地方任务, 2019-04--2022-03
( 8 ) 钴催化利用有机硼试剂对环丙烯的不对称官能团化反应, 负责人, 国家任务, 2020-01--2023-12
( 9 ) 钴催化烯丙基、炔丙基碳氢键不对称官能团化反应, 负责人, 国家任务, 2021-01--2023-12