基本信息

陈祥雨  男  博导  化学科学学院
电子邮件: chenxiangyu20@ucas.ac.cn
通信地址: 北京怀柔区怀北镇怀北庄中国科学院雁栖湖校区
邮政编码: 101408

研究领域

不对称催化,小分子催化,金属有机,自由基化学

因课题组发展需要,目前计划招聘研究助理(本科、硕士学历以上),博士后,联合培养学生多人,此招聘信息长期有效。热忱欢迎具有催化、合成化学背景的青年才俊加盟!

教育背景

​中国科学院化学研究所   博士 (导师:叶松研究员)
湘潭大学  学士


主要工作经历

​德国亚琛工业大学, 博士后


奖励

   
奖励信息
(1) Springer 优秀博士论文, 其他, 2016
(2) 中国科学院优秀博士学位论文, 院级, 2015

出版信息

   
近5年代表性论文
(1) Insight into the Selective Methylene Oxidation Catalyzed by Mn(CF3-PDP)(SbF6)2/H2O2/CH2ClCO2H) System: A DFT Mechanistic Study, Org. Lett., 2021, 通讯作者
(2) Photoinduced α-Alkenylation of Katritzky Salts: Synthesis of β,γ-Unsaturated Esters, Org. Lett., 2021, 通讯作者
(3) N-heterocyclic carbene-catalyzed radical reactions, Sci. China: Chem., 2021, 通讯作者
(4) Donor-Acceptor Complex Enables Synthesis of E-Olefins from Alcohols, Amines and Carboxylic Acids, Chem. Sci., 2021, 通讯作者
(5) Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N-Heterocyclic Carbenes, Org. Lett., 2020, 通讯作者
(6) Site-Selective Pyridyl Alkyl Ketone Synthesis from N-Alkenoxypyridiniums through Boekelheide-Type Rearrangements, Org. Lett., 2020, 通讯作者
(7) Photochemical Decarboxylative C(sp3)–X Coupling Facilitated by Weak Interaction of N-Heterocyclic Carbene, Org. Lett., 2020, 通讯作者
(8) Dual N-heterocyclic carbene/photocatalysis: a new strategy for radical processes, Org. Chem. Front., 2020, 通讯作者
(9) Highly enantioselective 1,6-addition of dienolates to coumarins and chromones through N-heterocyclic carbene catalysis, Org. Chem. Front., 2020, 通讯作者
(10) How does the nickel catalyst control the doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles? The rebound mechanism, Org. Chem. Front., 2020, 通讯作者
(11) Bifunctional N-Heterocyclic Carbenes Derived from l-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis, Acc. Chem. Res., 2020, 第 1 作者
(12) Light-Induced Excited-State Palladium Catalysis for Challenging Couplings, Chem, 2020, 通讯作者
(13) N-Heterocyclic Carbene-Catalyzed 1,6-Addition of Homoenolate Equivalent Intermediates: Asymmetric Synthesis of Nonspirocyclic Quaternary Oxindoles, CCS Chem., 2019, 第 1 作者
(14) Intramolecular α-Oxygenation of Amines via N-Heterocyclic Carbene-Catalyzed Domino Reaction of Aryl Aldehyde: Experiment and DFT Calculation, CCS Chem., 2019, 第 1 作者
(15) Arylatin of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis, Angew. Chem. Int. Ed., 2019, 第 1 作者
(16) Radical Umpolung: Efficient Options for the Synthesis of 1,4-Dicarbonyl Compounds, Angew. Chem. Int. Ed., 2019, 第 1 作者
(17) N-Heterocyclic Carbene Catalyzed Quadruple Domino Reactions: Asymmetric Synthesis of Cyclopenta[c]chromenones, Angew. Chem. Int. Ed., 2018, 通讯作者
(18) N‐Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations, Angew. Chem. Int. Ed., 2018, 第 1 作者
(19) Asymmetric Synthesis of Spiro-oxindole-ε-lactones through N-Heterocyclic Carbene Catalysis, Org. Lett., 2018, 通讯作者
(20) Control of N-Heterocyclic Carbene Catalyzed Reactions of Enals: Asymmetric Synthesis of Oxindole-γ-Amino Acid Derivatives, Angew. Chem. Int. Ed., 2017, 第 1 作者
(21) N-Heterocyclic Carbene Catalyzed [4+2] Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5-Diaryl Cyclohexenones, Angew. Chem. Int. Ed., 2017, 第 1 作者
(22) N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate, Chem. Sci., 2016, 第 1 作者
(23) Metal-Free meta-Selective Alkyne Oxyarylation with Pyridine N-Oxides: Rapid Assembly of Metyrapone Analogues, Angew. Chem. Int. Ed., 2016, 第 1 作者
发表著作
(1) New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations, Springer, 2016-01, 第 1 作者