研究方向：

1.过渡金属配（簇）合物催化剂的合成与催化研究；

2.绿色化学CO₂气体的催化转化；

3.金属有机催化有机小分子的活化与转化。

　　本课题组主要开展过渡金属配位化学、金属有机催化化学和有机小分子活化与催化等方向的研究，开发以过渡金属配合物为主的新型配合物催化剂，用于活化气体小分子和有机小分子，生成有经济价值的化学品；并且此研究基础上，探索反应机理，开展设计合成金属配合物催化剂，催化合成药物化学品的研究。

070301-无机化学
070303-有机化学

过渡金属配（簇）合物催化剂的合成与催化研究；
绿色化学CO2气体的催化转化；
金属有机催化有机小分子的活化与转化

2004-09--2008-07   英国诺丁汉大学化学系   博士
2000-09--2003-07   中科院福建物质结构研究所   硕士
1995-09--1999-07   武汉大学化学系   学士

博士研究生

理学博士

   

2012-08~现在, 中国科学院福建物质结构研究所, 研究员
2008-03~2012-08,美国哈佛大学化学与生物化学系, 博士后
1999-10~2004-07,中国科学院福建物质结构研究所, 研究实习员

   

[1] 黄德光, 李影华. 一种三苯基膦烯丙基卤化钯化合物及其衍生物的制备和应用. CN: CN111116666B, 2020-12-29.
[2] 黄德光, 相仕群, 张晓峰. 一种1-(2-吡啶基)-吡唑-3-甲酸及其衍生物的合成方法. CN: CN109369617B, 2020-07-31.

[1] Fan, Weibin, Xiang, Shiqun, Li, Yinghua, Zhang, Wei, Guo, Shiwei, Huang, Deguang. Iodine-Mediated Pyridine Ring Expansion for the Construction of Azepines. ORGANIC LETTERS[J]. 2022, 24(11): 2075-2080, [2] Guo, Shiwei, Li, Yinghua, Fan Weibin, Liu, Zhiqi, Huang, Deguang. Copper(II)-Catalyzed Selective CAr-H Bond Formylation: Synthesis of Dialdehyde Aniline. Frontiers in Chemistry[J]. 2022, 10: 891858-, [3] Fan Weibin, ZHANG Yuan, Li, Yinghua, Zhang, Wei, Huang, Deguang. Solvent-Free Strategy for Direct Access to Versatile Quaternary Ammonium Salts with Complete Atom Economy. ChemSusChem[J]. 2022, DOI:10.1002/cssc.202200529-, [4] ZHANG Yuan, Liu Zhiqi, Zhu Tingyu, Huang, Ying, Fan Weibin, Huang Deguang. Synthesis of methylene-bridged α,β-unsaturated ketones: α-Csp3–H methylenation of aromatic ketones using Selectfluor as a mild oxidant. Org. Biomol. Chem[J]. 2022, 20: 415-419, https://pubs.rsc.org/en/content/articlelanding/2022/ob/d1ob02043a.
[5] Xiang, Shiqun, Li, Yinghua, Fan, Weibin, Jin, Jiang, Zhang, Wei, Huang, Deguang. Copper(II)-Dioxygen Facilitated Activation of Nitromethane: Nitrogen Donors for the Synthesis of Substituted 2-Hydroxyimino-2-phenylacetonitriles and Phthalimides. FRONTIERS IN CHEMISTRY[J]. 2021, 8: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7878530/.
[6] Jin, Jiang, Li, Yinghua, Xiang, Shiqun, Fan, Weibin, Guo, Shiwei, Huang, Deguang. Selectfluor facilitated bridging of indoles to bis(indolyl)methanes using methyl tert-butyl ether as a new methylene precursor. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2021, 19(18): 4076-4081, http://dx.doi.org/10.1039/d1ob00120e.
[7] Zhang, Wei, Xiang, Shiqun, Fan, Weibin, Jin, Jiang, Li, Yinghua, Huang, Deguang. A three-component iodine-catalyzed oxidative coupling reaction: a heterodifunctionalization of 3-methylindoles. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2021, 19(26): 5794-5799, http://dx.doi.org/10.1039/d1ob00730k.
[8] Xiang, Shiqun, Fan, Weibin, Zhang, Wei, Li, Yinghua, Guo, Shiwei, Huang, Deguang. Aqueous CO2 fixation: construction of pyridine skeletons in cooperation with ammonium cations. GREEN CHEMISTRY[J]. 2021, 23(20): 7950-7955, http://dx.doi.org/10.1039/d1gc02303a.
[9] Li, Yinghua, Fan, Weibin, Zhang, Zilong, Xie, Xingkun, Xiang, Shiqun, Huang, Deguang. Copper(II)-hydroxide facilitated C-C bond formation: the carboxamido pyridine system versus the methylimino pyridine system. DALTON TRANSACTIONS[J]. 2020, 49(35): 12189-12196, https://www.webofscience.com/wos/woscc/full-record/WOS:000569986300038.
[10] Li, Yinghua, Zhu, Yingzu, Xiang, Shiqun, Fan, Weibin, Jin, Jiang, Huang, Deguang. Temperature controlled condensation of nitriles: efficient and convenient synthesis of beta-enaminonitriles, 4-aminopyrimidines and 4-amidinopyrimidines in one system. RSC ADVANCES[J]. 2020, 10(11): 6576-6583, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000515393300051.
[11] Deguang Huang. Temperature controlled condensation of nitriles: efficient and convenient synthesis of benaminonitriles, 4-aminopyrimidines and 4- amidinopyrimidines in one system. RSC Advance. 2020, [12] Zhu, Yingzu, Li, Yinghua, Xiang, Shiqun, Fan, Weibin, Jin, Jiang, Huang, Deguang. Utilization of nitriles as the nitrogen source: practical and economical construction of 4-aminopyrimidine and beta-enaminonitrile skeletons. ORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(17): 3071-3077, [13] Xiang, Shiqun, Zhang, Xiaofeng, Chen, Hui, Li, Yinghua, Fan, Weibin, Huang, Deguang. Copper(II) facilitated decarboxylation for the construction of pyridyl-pyrazole skeletons. INORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(9): 2359-2364, [14] Tang, Changquan, Wang, Mingxue, Shang, Xiaoying, Chen, Xueyuan, Huang, Deguang, Zheng, Qingdong. Real-time monitoring of intracellular nitric oxide using a long-wavelength-emitting probe via one-photon or two-photon excitation. JOURNAL OF MATERIALS CHEMISTRY C[J]. 2019, 7(11): 3246-3252, http://dx.doi.org/10.1039/c8tc06238b.
[15] Zhang, Xiaofeng, Zhang, Zilong, Xiang, Shiqun, Zhu, Yingzu, Chen, Changneng, Huang, Deguang. Base induced C-CN bond cleavage at room temperature: a convenient method for the activation of acetonitrile. INORGANIC CHEMISTRY FRONTIERS[J]. 2019, 6(5): 1135-1140, https://www.webofscience.com/wos/woscc/full-record/WOS:000473066900024.
[16] Wang, Yang, Zhang, Xiaofeng, Liu, Haixiong, Chen, Hui, Huang, Deguang. Nickel-catalyzed direct formation of the C-S bonds of aryl sulfides from arylsulfonyl chlorides and aryl iodides using Mn as a reducing agent. ORGANIC CHEMISTRY FRONTIERS[J]. 2017, 4(1): 31-36, https://www.webofscience.com/wos/woscc/full-record/WOS:000397104100006.
[17] Wang, Yang, Liu, Haixiong, Zhang, Xiaofeng, Zhang, Zilong, Huang, Deguang. Experimental and mechanistic insights into copper(II)-dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivatives. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2017, 15(43): 9164-9168, https://www.webofscience.com/wos/woscc/full-record/WOS:000414805900016.
[18] Deguang Huang. Experimental and mechanistic insights into copper(II)–dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivativesinsights into copper(II)–dioxygen catalyzed oxidative. Org. Biomol. Chem.. 2017, [19] WANG Qing, MA Cheng-Bing, CHEN Hui, SUN Lei, HUANG De-Guang, CHEN Chang-Neng. Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2＇-pyridyl)-2,5-dithiahexane. 结构化学. 2016, 35(9): 1451-1460, http://lib.cqvip.com/Qikan/Article/Detail?id=670318589.
[20] Wang Qing, Ma ChengBing, Chen Hui, Huang DeGuang, Chen ChangNeng. Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis, Characterization and Properties. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2016, 35(12): 1972-1979, http://lib.cqvip.com/Qikan/Article/Detail?id=671015407.
[21] 王清, 马成丙, 陈惠, 孙磊, 黄德光, 陈昌能. Syntheses and Crystal Structures of the First Row Transition Metals with 1，6-Bis（2’-pyridyl）-2，5-dithiahexane简. 结构化学. 2016, 1451-1460, http://lib.cqvip.com/Qikan/Article/Detail?id=74717288504849544857484957.
[22] Liu, HaiXiong, Zhang, Xiaofeng, Gao, XianJing, Chen, Changneng, Huang, Deguang. Synthesis and mechanism study of a dimeric tetranuclear carbonate-bridged copper(II) complex resulting from CO2 fixation by controlling O-2 concentration. INORGANIC CHEMISTRY COMMUNICATIONS[J]. 2016, 68: 63-67, http://dx.doi.org/10.1016/j.inoche.2016.03.026.
[23] Wang Qing, Ma ChengBing, Chen Hui, Sun Lei, Huang DeGuang, Chen ChangNeng. Syntheses and Crystal Structures of the First Row Transition Metals with 1,6-Bis(2 '-pyridyl)-2,5-dithiahexane. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2016, 35(9): 1451-1460, http://lib.cqvip.com/Qikan/Article/Detail?id=670318589.
[24] 王清, 马成丙, 陈惠, 黄德光, 陈昌能. Five-heterocyclic-biphosphine-substituted Fe-only Hydrogenase Mimic: Synthesis,Characterization and Properties. 结构化学. 2016, 35(12): 1972-1979, http://lib.cqvip.com/Qikan/Article/Detail?id=671015407.
[25] Xie XingKun, Zhang XiaoFeng, Liu HaiXiong, Wang Yang, Chen ChangNeng, Huang DeGuang. Synthesis of a Hexagonal Molecular Nickel-wheel. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2015, 34(11): 1689-1696, http://lib.cqvip.com/Qikan/Article/Detail?id=666772459.
[26] XIE Xing-Kun, ZHANG Xiao-Feng, LIU Hai-Xiong, WANG Yang, CHEN Chang-Neng, HUANG De-Guang. Synthesis of a Hexagonal Molecular Nickel-wheel. 结构化学. 2015, 34(11): 1689-1696, http://lib.cqvip.com/Qikan/Article/Detail?id=666772459.
[27] Troeppner, O, Huang, D, Holm, R H, IvanovicBurmazovic, I. Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo) nickel(II) complex. DALTON TRANSACTIONS[J]. 2014, 43(14): 5274-5279, https://www.webofscience.com/wos/woscc/full-record/WOS:000332929200007.
[28] WU Nan-Nan, CHEN Chang-Neng, HUANG De-Guang. Activation of Nitromethane to Cyanide by a Mononuclear Cu(Ⅱ) Complex. 结构化学. 2014, 33(11): 1643-1648, http://lib.cqvip.com/Qikan/Article/Detail?id=664291640.
[29] Wu NanNan, Chen ChangNeng, Huang DeGuang. Activation of Nitromethane to Cyanide by a Mononuclear Cu(II) Complex. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY[J]. 2014, 33(11): 1643-1648, https://www.webofscience.com/wos/woscc/full-record/WOS:000346233900012.
[30] Zhang, Xiaofeng, Huang, Deguang, Chen, YuSheng, Holm, R H. Synthesis of Binucleating Macrocycles and Their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features. INORGANIC CHEMISTRY[J]. 2012, 51(20): 11017-11029, https://www.webofscience.com/wos/woscc/full-record/WOS:000309739100057.
[31] Huang, Deguang, Makhlynets, Olga V, Tan, Lay Ling, Lee, Sonny C, RybakAkimova, Elena V, Holm, R H. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA[J]. 2011, 108(4): 1222-1227, https://www.webofscience.com/wos/woscc/full-record/WOS:000286594800008.
[32] Huang, Deguang, Makhlynets, Olga V, Tan, Lay Ling, Lee, Sonny C, RybakAkimova, Elena V, Holm, R H. Fast Carbon Dioxide Fixation by 2,6-Pyridinedicarboxamidato-nickel(II)-hydroxide Complexes: Influence of Changes in Reactive Site Environment on Reaction Rates. INORGANIC CHEMISTRY[J]. 2011, 50(20): 10070-10081, https://www.webofscience.com/wos/woscc/full-record/WOS:000295602500040.
[33] Stephen, Emma, Huang, Deguang, Shaw, Jennifer L, Blake, Alexander J, Collison, David, Davies, E Stephen, Edge, Ruth, Howard, Judith A K, McInnes, Eric J L, Wilson, Claire, Wolowska, Joanna, McMaster, Jonathan, Schroeder, Martin. Redox Non-Innocence of Thioether Crowns: Spectroelectrochemistry and Electronic Structure of Formal Nickel(III) Complexes of Aza-Thioether Macrocycles. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2011, 17(37): 10246-10258, http://dx.doi.org/10.1002/chem.201100812.
[34] Deguang Huang, R H Holm. Reactions of the Terminal Ni II –OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular Ni II …Fe II Bridged Site. Journal of the American Chemical Society. 2010, 132(13): 4693-4701, [35] Deguang Huang. Cleavage of Ni-S-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions. Inorg. Chem.. 2009, [36] Huang, Deguang, Zhang, Xiaofeng, McInnes, Eric J L, McMaster, Jonathan, Blake, Alexander J, Davies, E Stephen, Wolowska, Joanna, Wilson, Claire, Schroder, Martin. Crystallographic, Electrochemical, and Electronic Structure Studies of the Mononuclear Complexes of Au(I)/(II)/(III) with 9aneS(2)O (9aneS(2)O=1-oxa-4,7-dithiacyclononane). INORGANIC CHEMISTRY[J]. 2008, 47(21): 9919-9929, https://www.webofscience.com/wos/woscc/full-record/WOS:000260426700030.
[37] Huang, Deguang, Blake, Alexander J, McInnes, Eric J L, McMaster, Jonathan, Davies, E Stephen, Wilson, Claire, Wolowska, Joanna, Schroder, Martin. Electronic structure of the mononuclear Ag(II) complex Ag(18aneS(4)O(2))(2+) (18aneS(4)O(2)=1,10-dioxa-4,7,13,16-tetrathiacyclooctadecane). CHEMICAL COMMUNICATIONS[J]. 2008, 1305-1307, https://www.webofscience.com/wos/woscc/full-record/WOS:000254352900011.
[38] CHEN Hui, ZHANG XiaoFeng, HUANG DeGuang, CHEN ChangNeng, LIU QiuTian. Synthesis and Structure of a New Dimanganese Complex Mn2(μ-OAc)2(phen)4(ClO4)2. 结构化学[J]. 2006, 25(1): 103-107, http://lib.cqvip.com/Qikan/Article/Detail?id=20974343.
[39] ZHANGXiaoFeng, Chen Feng, Huang Deguang, Chen Changneng, Liu Qiutian. Synthesis and Strutural Characterization of {Mn(phen)2(OAc)(H2O)ClO4}2.H2O. 结构化学[J]. 2003, 22(2): 151-154, http://lib.cqvip.com/Qikan/Article/Detail?id=7516455.
[40] Zhang Xiaofeng, Huang Deguang, Chen Feng, Chen Changneng, Liu Qiutian. Synthesis and Structural Characterization of Mn(phen)2(H2O)2(OAc)2.6H2O. 结构化学[J]. 2003, 22(5): 525-528, http://lib.cqvip.com/Qikan/Article/Detail?id=8376958.
[41] 黄德光. 模拟Mn酶活性中心的簇（配）合物的合成、结构及性质研究. 2003, 150-, http://ir.fjirsm.ac.cn/handle/350002/7092.
[42] Liu Qiutian, Huang Deguang, Zhu Hongping, Chen Changneng. Synthesis and Structural Characterization of Mononuclear Mn~(II) Picolilato Complex Mn(2-C_5H_4NCOO)_2(H_2O)_2·1/2CH_3CN. Chinese Journal of Structural Chemistry[J]. 2002, 21(2): 161-164, 

（1） 专章： Cluster Compounds, 书名： Modern Inorganic Synthetic Chemistr, Elsevier, 2017-07, 第 2 作者

   

（ 1 ） ****, 主持, 市地级, 2012-09--2015-09
（ 2 ） 国家基金面上项目, 主持, 国家级, 2014-01--2017-12

已指导学生

刘海雄  硕士研究生  085216-化学工程  

陈帅  硕士研究生  070301-无机化学  

汤昌泉  博士研究生  070303-有机化学  

现指导学生

相仕群  博士研究生  070301-无机化学  

范伟斌  博士研究生  070301-无机化学  

郭世维  硕士研究生  085204-材料工程