基本信息
龚昱  男  博导  中国科学院上海应用物理研究所
电子邮件: gongyu@sinap.ac.cn
通信地址: 上海市嘉定区嘉罗公路2019号
邮政编码:

研究领域

   

招生信息

   
招生专业
070301-无机化学
070304-物理化学
招生方向
锕系元素化学,乏燃料后处理
光谱与动力学
理论配位化学

教育背景

2005-09--2010-07   复旦大学化学系   博士
2001-09--2005-07   复旦大学化学系   学士
学历
   
学位
   

工作经历

   
工作简历
2015-02~现在, 中国科学院上海应用物理研究所, 研究员
2014-09~2014-11,美国弗吉尼亚大学(University of Virginia), 博士后
2012-02~2014-08,美国劳伦斯伯克利国家实验室(Lawrence Berkeley National Laboratory), 博士后
2010-08~2012-01,美国弗吉尼亚大学(University of Virginia), 博士后
2005-09~2010-07,复旦大学化学系, 博士
2001-09~2005-07,复旦大学化学系, 学士
社会兼职
   

教授课程

锕系化学前沿

专利与奖励

   
奖励信息
(1) 瞬态新奇分子的光谱、成键和反应研究, 二等奖, 国家级, 2018
(2) 上海市研究生优秀成果(学位论文), 市地级, 2012
(3) 吴征铠奖学金, 研究所(学校), 2010
(4) 张存浩优秀研究生奖, 国家级, 2007
专利成果
   

出版信息

   
发表论文
(1) Side-On Sulfur Monoxide Complexes of Tantalum, Niobium, and Vanadium Oxyfluorides, Inorganic Chemistry, 2019, 第 11 作者
(2) Coordination Structures of the Uranyl(VI)−Diamide Complexes: ACombined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study, Inorganic Chemistry, 2019, 第 11 作者
(3) Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides, Inorganic Chemistry, 2019, 第 11 作者
(4) Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl, Journal of The Electrochemical Society, 2019, 第 11 作者
(5) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, The Journal of Physical Chemistry A, 2018, 第 11 作者
(6) Infrared Spectra of the SO2F2 Anion in Solid Argon and Neon, The Journal of Physical Chemistry A, 2018, 第 11 作者
(7) Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2018, 第 11 作者
(8) Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)​33+ Complexes in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2017, 第 11 作者
(9) Formation and Characterization of Homoleptic Thorium Isocyanide Complexes, Inorganic Chemistry, 2017, 第 11 作者
(10) Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt, Journal of Radioanalytical and Nuclear Chemistry, 2017, 第 11 作者
(11) Infrared Spectroscopic and Theoretical Studies on the OMF2 and, The Journal of Physical Chemistry A, 2017, 第 11 作者
(12) Matrix Infrared Spectra of Manganese and Iron Isocyanide, The Journal of Physical Chemistry A, 2017, 第 11 作者
(13) Coordination Structure and Fragmentation Chemistry of the, The Journal of Physical Chemistry A, 2017, 第 11 作者
(14) Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-​Ring (AnN)​2 Molecules Stabilized by Delocalized π-​Bonding, Journal of the American Chemical Society, 2016, 第 4 作者
(15) The evaporation behaviors of rare-​earth-​doped FLiNaK melts during low-​pressure distillation, Journal of Radioanalytical and Nuclear Chemistry, 2016, 第 11 作者
(16) Synthesis and hydrolysis of uranyl, neptunyl, and plutonyl gas-​phase complexes exhibiting discrete actinide-​carbon bonds, Organometallics, 2016, 第 3 作者
(17) Electrospray production and collisional dissociation oflanthanide/methylsulfonyl anion complexes: Sulfur dioxide anionas a ligand., Int. J. Mass. Spectrom., 2015, 第 1 作者
(18) Reactions of Laser-Ablated U Atoms with HCN: Infrared Spectra in Solid Argon and Quantum Chemical Calculations for HUNC, Eur. J. Inorg. Chem., 2015, 第 1 作者
(19) Synthesis and Structures of Plutonyl Nitrate Complexes: Is Plutonium Heptavalent in PuO3(NO3)2- ?, Inorg. Chem., 2015, 第 3 作者
(20) Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide, J. Am. Chem. Soc., 2015, 第 1 作者
(21) Reactions of laser-ablated U atoms with (CN)2: infrared spectra and electronic structure calculations of UNC, U(NC)2, and U(NC)4 in solid argon, Chem. Commun., 2015, 第 1 作者
(22) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)​1-​5 and NU(NN)​1-​6 Complexes in Solid Argon, Inorganic Chemistry, 2014, 第 3 作者
(23) Reactions of Lanthanide Atoms with Oxygen Difluoride and the Role of the Ln Oxidation State, Inorganic Chemistry, 2014, 第 5 作者
(24) Tetrapositive Plutonium, Neptunium, Uranium and Thorium Coordination Complexes: Chemistry Revealed by Electron Transfer and Collision Induced Dissociation, J. Phys. Chem. A, 2014, 第 1 作者
(25) Activation of Gas-Phase Uranyl: From an Oxo to a Nitrido Complex, J. Phys. Chem. A, 2014, 第 1 作者
(26) Infrared Spectra and Electronic Structure Calculations for NN Complexes with U, UN, and NUN in Solid Argon, Neon, and Nitrogen, J. Phys. Chem. A, 2014, 第 3 作者
(27) Crown Ether Complexes of Uranyl, Neptunyl and Plutonyl: Hydration Differentiates Inclusion versus Outer-Coordination, Inorg. Chem., 2014, 第 1 作者
(28) Dissociation of Diglycolamide Complexes of Ln3+ (Ln = La-Lu) and An3+ (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior, Inorg. Chem., 2014, 第 1 作者
(29) A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands, Angew. Chem. Int. Ed., 2013, 第 1 作者
(30) Formation and Characterization of the Uranyl−SO2 Complex, UO2(CH3SO2)(SO2)−, J. Phys. Chem. A, 2013, 第 1 作者
(31) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl−,, J. Phys. Chem. A, 2013, 第 1 作者
(32) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1-5 and, Inorg. Chem., 2013, 第 3 作者
(33) Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au), Inorganic Chemistry, 2012, 第 1 作者
(34) Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)​H Intermediate in Solid Argon, Inorganic Chemistry, 2012, 第 1 作者
(35) Reactions of Group 3 Metals with OF2: Infrared Spectroscopic and Theoretical Investigations of the Group 3 Oxydifluoride OMF2 and Oxyfluoride OMF Molecules, Journal of Physical Chemistry A, 2012, 第 1 作者
(36) Infrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands, Dalton Transactions, 2012, 第 1 作者
(37) Formation of Metal Oxyfluorides from Specific Metal Reactions with Oxygen Difluoride: Infrared Spectroscopic and Theoretical Investigations of the OScF2 Radical and OScF with Terminal Single and Triple Sc=​O Bonds, Chemistry - A European Journal, 2012, 第 1 作者
(38) Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-​Isolation and Quantum-​Chemical Investigation of Mercury Oxyfluorides, Angewandte Chemie, International Edition, 2012, 第 3 作者
(39) Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character, Inorganic Chemistry, 2012, 第 1 作者
(40) Infrared Spectra of Rh12C and Rh13C in Solid Neon and Solid Argon, Chemical Physics Letters, 2012, 第 1 作者
(41) Reactions of Late Lanthanide Metal Atoms and Methanol in Solid Argon: A Matrix Isolation Infrared Spectroscopic and Theoretical Study, Journal of Physical Chemistry A, 2011, 第 1 作者
(42) Matrix Infrared Spectra and Theoretical Studies of Thorium Oxide Species: ThOx and Th2Oy, Journal of Physical Chemistry A, 2011, 第 2 作者
(43) Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether, Dalton Transactions, 2011, 第 1 作者
(44) Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Scandium, Yttrium, and Lanthanide Metal Atoms with Dimethyl Ether, Journal of Physical Chemistry A, 2011, 第 1 作者
(45) Infrared Spectra and Quantum Chemical Calculations of the Bridge-​Bonded HC(F)​LnF2 (Ln = La-​Lu) Complexes, Organometallics, 2011, 第 1 作者
(46) Matrix Infrared Spectroscopic and Theoretical Investigations of Uranium Atom and Methanol Reaction Products, Inorganic Chemistry, 2011, 第 1 作者
(47) Is rhodium tetroxide in the formal oxidation state VIII stable? a quantum chemical and matrix isolation investigation of rhodium oxides, Theoretical Chemistry Accounts, 2011, 第 1 作者
(48) Infrared spectrum of the CH3OCH2 radical in solid argon, Journal of Physical Chemistry A, 2011, 第 1 作者
(49) Water Adsorption on Platinum Dioxide and Dioxygen Complex: matrix Isolation Infrared Spectroscopic and Theoretical Study of Three PtO2-​H2O Complexes, ChemPhysChem, 2010, 第 1 作者
(50) Chemistry on Single Atoms: Spontaneous Hydrogen Production from Reactions of Transition-​Metal Atoms with Methanol at Cryogenic Temperatures, Angewandte Chemie, International Edition, 2010, 第 3 作者
(51) Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon, Journal of Physical Chemistry A, 2010, 第 2 作者
(52) Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State +VIII, Angewandte Chemie, International Edition, 2009, 第 1 作者
(53) Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, Physical Chemistry Chemical Physics, 2009, 第 1 作者
(54) Infrared Spectra of Oxygen-​Rich Yttrium and Lanthanum Dioxygen​/Ozonide Complexes in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
(55) Spectroscopic Characterization of a Copper(III) Trisuperoxide Complex Bearing Both Side-​On and End-​On Ligands, Journal of Physical Chemistry A, 2009, 第 1 作者
(56) Infrared Spectra of Transition-​Metal Dioxide Anions: MO2- (M = Rh, Ir, Pt, Au) in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
(57) Is the FeO2- Anion Bent or Linear?, Journal of Physical Chemistry A, 2009, 第 1 作者
(58) Spectroscopic and Theoretical Studies of Transition Metal Oxides and Dioxygen, Chem. Rev., 2009, 第 1 作者
(59) Formation and Characterization of Two FeO3 Isomers in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(60) Matrix Infrared Spectra and Density Functional Calculations of TiO3 and TiO5 in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(61) Noble-​Gas-​Induced Disproportionation Reactions: Facile Superoxo-​to-​Peroxo Conversion on Chromium Dioxide, Journal of Physical Chemistry A, 2008, 第 3 作者
(62) Matrix isolation infrared spectroscopic and theoretical study of the hydrolysis of boron dioxide in solid argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(63) Formation and Characterization of Mononuclear and Dinuclear Manganese Oxide-​Dioxygen Complexes in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(64) Formation and Characterization of the Photochemically Interconvertible Side-​On and End-​On Bonded Dioxygen-​Iron Dioxide Complexes in Solid Argon, Journal of Physical Chemistry A, 2007, 第 1 作者
(65) Formation and characterization of the oxygen-​rich scandium oxide​/dioxygen complexes ScOn (n = 4, 6, 8) in solid argon, Journal of Physical Chemistry A, 2007, 第 1 作者
(66) Matrix isolation infrared spectroscopic and theoretical study of noble gas coordinated dipalladium-​dioxygen complexes, Chemical Physics, 2007, 第 2 作者
(67) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Dinuclear Chromium Oxide Clusters: Cr2On (n = 2, 4, 6) in Solid Argon, Journal of Physical Chemistry A, 2007, 第 3 作者
(68) Formation and Characterization of the Oxygen-​Rich Hafnium Dioxygen Complexes: OHf(η2-​O2)​(η2-​O3)​, Hf(η2-​O2)​3, and Hf(η2-​O2)​4, Journal of Physical Chemistry A, 2007, 第 1 作者
(69) Formation and Characterization of the Tetranuclear Scandium Nitride: Sc4N4, Journal of Physical Chemistry A, 2007, 第 1 作者
(70) Interconvertible Side-​On- and End-​On-​Bonded Oxo-​Superoxo Titanium Ozonide Complexes, Journal of Physical Chemistry A, 2007, 第 1 作者
(71) Remarkable dinitrogen activation and cleavage by the Gd dimer: from dinitrogen complexes to ring and cage nitrides, Angewandte Chemie, International Edition, 2007, 第 3 作者
(72) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Group IV Metal Oxide Clusters: M2O2 and M2O4, Journal of Physical Chemistry A, 2007, 第 1 作者
(73) Infrared Spectra of Chlorinated Ethylene Cations: C2Cl4+, C2HCl3+, 1,​1-​C2H2Cl2+, and trans-​C2H2Cl2+ in Solid Argon, Journal of Physical Chemistry A, 2007, 第 2 作者
(74) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Noble Gas Coordinated Rhodium-​Dioxygen Complexes, Journal of Physical Chemistry A, 2007, 第 2 作者
发表著作
   

科研活动

   
科研项目
( 1 ) “千人计划”青年人才项目, 主持, 国家级, 2016-10--2019-09
( 2 ) 燃料盐中锕系元素化合物的结构,性质与反应, 主持, 市地级, 2015-01--2020-03
( 3 ) 锕系金属氟化物红外光谱研究, 主持, 国家级, 2016-09--2018-08
( 4 ) 钍镤铀-中性二酰胺配合物的气相结构与反应研究, 主持, 国家级, 2018-01--2021-12
参与会议
(1)锕系配位化合物的质谱和红外光谱研究   第三届锕系物理与化学学术交流会   2018-07-20
(2)金属氟氧化物的红外光谱研究   第4次环境放射化学战略研讨会   2017-10-26
(3)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2017-04-02
(4)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2016-07-19
(5)质谱和红外光谱方法在锕系化学   第三届全国核化学与放射化学青年学术研讨会   龚昱   2015-11-29
(6)质谱方法在锕系化学中的应用   第六届全国环境放射化学学术研讨会   龚昱   2015-09-02
(7)质谱方法在锕系化学中的应用   第十四届全国应用化学年会   龚昱   2015-07-23

合作情况

   
项目协作单位
   

指导学生