基本信息

龚昱  男  博导  中国科学院上海应用物理研究所
电子邮件: gongyu@sinap.ac.cn
通信地址: 上海市嘉定区嘉罗公路2019号
邮政编码: 201800

研究领域

锕系和镧系化合物在熔盐和溶液中的配位结构及其与分离效果和熔盐堆运行间的关系、熔盐体系中锕系和镧系元素的综合利用,为阐明钍铀循环过程中关键元素在堆运行、后处理和再利用过程中的化学行为和规律提供科学基础,具体包括:

1. 钍铀循环关键元素的新型分离方法与机制研究
2. 新型锕系和镧系化合物的合成、结构与性质
3. 基于光谱和质谱方法的锕系和镧系配位化学研究
4. 镧系和锕系元素化合物的综合利用研究

招生信息

   
招生专业
070301-无机化学
070304-物理化学
招生方向
镧系和锕系元素化学
乏燃料后处理
基于谱学的配位化学

教育背景

2005-09--2010-07   复旦大学化学系   博士
2001-09--2005-07   复旦大学化学系   学士
学历

研究生

学位

博士

工作经历

   
工作简历
2015-02~现在, 中国科学院上海应用物理研究所, 研究员
2014-09~2014-11,美国弗吉尼亚大学(University of Virginia), 博士后
2012-02~2014-08,美国劳伦斯伯克利国家实验室(Lawrence Berkeley National Laboratory), 博士后
2010-08~2012-01,美国弗吉尼亚大学(University of Virginia), 博士后
社会兼职
   

教授课程

锕系化学前沿

专利与奖励

   
奖励信息
(1) 瞬态新奇分子的光谱、成键和反应研究, 二等奖, 国家级, 2018
(2) 上海市研究生优秀成果(学位论文), 市地级, 2012
(3) 吴征铠奖学金, 研究所(学校), 2010
(4) 张存浩优秀研究生奖, 国家级, 2007
专利成果
   

出版信息

已在Chem. Rev, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Inorg. Chem.和J. Phys. Chem. A等期刊上发表第一和通讯作者论文50余篇。

发表论文
(1) Tetrapositive Hafnium-Diamide Complexes in the Gas Phase: Formation, Structure and Reaction, Journal of the American Society for Mass Spectrometry, 2019-10, 通讯作者
(2) End-on Oxygen Bound Sulfur Monoxide Complex of Titanium Oxyfluoride, Inorganic Chemistry, 2019-09, 通讯作者
(3) Efficient Removal of Azo-Dyes in Aqueous Solution by CeB6 Nanocrystals, ACS Applied Nano Materials, 2019-09, 通讯作者
(4) Formation of Cerium and Neodymium Isocyanides in the Reactions of Cyanogen with Ce and Nd Atoms in Argon Matrices, The Journal of Physical Chemistry A, 2019-09, 通讯作者
(5) Infrared Spectroscopic and Theoretical Studies of the 3d Transition Metal Oxyfluoride Molecules, Inorganic Chemistry, 2019-08, 通讯作者
(6) Side-On Sulfur Monoxide Complexes of Tantalum, Niobium, and Vanadium Oxyfluorides, Inorganic Chemistry, 2019, 通讯作者
(7) Coordination Structures of the Uranyl(VI)−Diamide Complexes: ACombined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study, Inorganic Chemistry, 2019, 通讯作者
(8) Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides, Inorganic Chemistry, 2019, 通讯作者
(9) Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl, Journal of The Electrochemical Society, 2019, 通讯作者
(10) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, The Journal of Physical Chemistry A, 2018, 通讯作者
(11) Infrared Spectra of the SO2F2 Anion in Solid Argon and Neon, The Journal of Physical Chemistry A, 2018, 通讯作者
(12) Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2018, 通讯作者
(13) Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)​33+ Complexes in the Gas Phase, Journal of the American Society for Mass Spectrometry, 2017, 通讯作者
(14) Formation and Characterization of Homoleptic Thorium Isocyanide Complexes, Inorganic Chemistry, 2017, 通讯作者
(15) Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt, Journal of Radioanalytical and Nuclear Chemistry, 2017, 通讯作者
(16) Infrared Spectroscopic and Theoretical Studies on the OMF2 and, The Journal of Physical Chemistry A, 2017, 通讯作者
(17) Matrix Infrared Spectra of Manganese and Iron Isocyanide, The Journal of Physical Chemistry A, 2017, 通讯作者
(18) Coordination Structure and Fragmentation Chemistry of the, The Journal of Physical Chemistry A, 2017, 通讯作者
(19) Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-​Ring (AnN)​2 Molecules Stabilized by Delocalized π-​Bonding, Journal of the American Chemical Society, 2016, 第 4 作者
(20) The evaporation behaviors of rare-​earth-​doped FLiNaK melts during low-​pressure distillation, Journal of Radioanalytical and Nuclear Chemistry, 2016, 通讯作者
(21) Synthesis and hydrolysis of uranyl, neptunyl, and plutonyl gas-​phase complexes exhibiting discrete actinide-​carbon bonds, Organometallics, 2016, 第 3 作者
(22) Electrospray production and collisional dissociation oflanthanide/methylsulfonyl anion complexes: Sulfur dioxide anionas a ligand., Int. J. Mass. Spectrom., 2015, 第 1 作者
(23) Reactions of Laser-Ablated U Atoms with HCN: Infrared Spectra in Solid Argon and Quantum Chemical Calculations for HUNC, Eur. J. Inorg. Chem., 2015, 第 1 作者
(24) Synthesis and Structures of Plutonyl Nitrate Complexes: Is Plutonium Heptavalent in PuO3(NO3)2- ?, Inorg. Chem., 2015, 第 3 作者
(25) Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide, J. Am. Chem. Soc., 2015, 第 1 作者
(26) Reactions of laser-ablated U atoms with (CN)2: infrared spectra and electronic structure calculations of UNC, U(NC)2, and U(NC)4 in solid argon, Chem. Commun., 2015, 第 1 作者
(27) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)​1-​5 and NU(NN)​1-​6 Complexes in Solid Argon, Inorganic Chemistry, 2014, 第 3 作者
(28) Reactions of Lanthanide Atoms with Oxygen Difluoride and the Role of the Ln Oxidation State, Inorganic Chemistry, 2014, 第 5 作者
(29) Tetrapositive Plutonium, Neptunium, Uranium and Thorium Coordination Complexes: Chemistry Revealed by Electron Transfer and Collision Induced Dissociation, J. Phys. Chem. A, 2014, 第 1 作者
(30) Activation of Gas-Phase Uranyl: From an Oxo to a Nitrido Complex, J. Phys. Chem. A, 2014, 第 1 作者
(31) Infrared Spectra and Electronic Structure Calculations for NN Complexes with U, UN, and NUN in Solid Argon, Neon, and Nitrogen, J. Phys. Chem. A, 2014, 第 3 作者
(32) Crown Ether Complexes of Uranyl, Neptunyl and Plutonyl: Hydration Differentiates Inclusion versus Outer-Coordination, Inorg. Chem., 2014, 第 1 作者
(33) Dissociation of Diglycolamide Complexes of Ln3+ (Ln = La-Lu) and An3+ (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior, Inorg. Chem., 2014, 第 1 作者
(34) A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands, Angew. Chem. Int. Ed., 2013, 第 1 作者
(35) Formation and Characterization of the Uranyl−SO2 Complex, UO2(CH3SO2)(SO2)−, J. Phys. Chem. A, 2013, 第 1 作者
(36) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl−,, J. Phys. Chem. A, 2013, 第 1 作者
(37) Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1-5 and, Inorg. Chem., 2013, 第 3 作者
(38) Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au), Inorganic Chemistry, 2012, 第 1 作者
(39) Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)​H Intermediate in Solid Argon, Inorganic Chemistry, 2012, 第 1 作者
(40) Reactions of Group 3 Metals with OF2: Infrared Spectroscopic and Theoretical Investigations of the Group 3 Oxydifluoride OMF2 and Oxyfluoride OMF Molecules, Journal of Physical Chemistry A, 2012, 第 1 作者
(41) Infrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands, Dalton Transactions, 2012, 第 1 作者
(42) Formation of Metal Oxyfluorides from Specific Metal Reactions with Oxygen Difluoride: Infrared Spectroscopic and Theoretical Investigations of the OScF2 Radical and OScF with Terminal Single and Triple Sc=​O Bonds, Chemistry - A European Journal, 2012, 第 1 作者
(43) Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-​Isolation and Quantum-​Chemical Investigation of Mercury Oxyfluorides, Angewandte Chemie, International Edition, 2012, 第 3 作者
(44) Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character, Inorganic Chemistry, 2012, 第 1 作者
(45) Infrared Spectra of Rh12C and Rh13C in Solid Neon and Solid Argon, Chemical Physics Letters, 2012, 第 1 作者
(46) Reactions of Late Lanthanide Metal Atoms and Methanol in Solid Argon: A Matrix Isolation Infrared Spectroscopic and Theoretical Study, Journal of Physical Chemistry A, 2011, 第 1 作者
(47) Matrix Infrared Spectra and Theoretical Studies of Thorium Oxide Species: ThOx and Th2Oy, Journal of Physical Chemistry A, 2011, 第 2 作者
(48) Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether, Dalton Transactions, 2011, 第 1 作者
(49) Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Scandium, Yttrium, and Lanthanide Metal Atoms with Dimethyl Ether, Journal of Physical Chemistry A, 2011, 第 1 作者
(50) Infrared Spectra and Quantum Chemical Calculations of the Bridge-​Bonded HC(F)​LnF2 (Ln = La-​Lu) Complexes, Organometallics, 2011, 第 1 作者
(51) Matrix Infrared Spectroscopic and Theoretical Investigations of Uranium Atom and Methanol Reaction Products, Inorganic Chemistry, 2011, 第 1 作者
(52) Is rhodium tetroxide in the formal oxidation state VIII stable? a quantum chemical and matrix isolation investigation of rhodium oxides, Theoretical Chemistry Accounts, 2011, 第 1 作者
(53) Infrared spectrum of the CH3OCH2 radical in solid argon, Journal of Physical Chemistry A, 2011, 第 1 作者
(54) Water Adsorption on Platinum Dioxide and Dioxygen Complex: matrix Isolation Infrared Spectroscopic and Theoretical Study of Three PtO2-​H2O Complexes, ChemPhysChem, 2010, 第 1 作者
(55) Chemistry on Single Atoms: Spontaneous Hydrogen Production from Reactions of Transition-​Metal Atoms with Methanol at Cryogenic Temperatures, Angewandte Chemie, International Edition, 2010, 第 3 作者
(56) Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon, Journal of Physical Chemistry A, 2010, 第 2 作者
(57) Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State +VIII, Angewandte Chemie, International Edition, 2009, 第 1 作者
(58) Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, Physical Chemistry Chemical Physics, 2009, 第 1 作者
(59) Infrared Spectra of Oxygen-​Rich Yttrium and Lanthanum Dioxygen​/Ozonide Complexes in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
(60) Spectroscopic Characterization of a Copper(III) Trisuperoxide Complex Bearing Both Side-​On and End-​On Ligands, Journal of Physical Chemistry A, 2009, 第 1 作者
(61) Infrared Spectra of Transition-​Metal Dioxide Anions: MO2- (M = Rh, Ir, Pt, Au) in Solid Argon, Journal of Physical Chemistry A, 2009, 第 1 作者
(62) Is the FeO2- Anion Bent or Linear?, Journal of Physical Chemistry A, 2009, 第 1 作者
(63) Spectroscopic and Theoretical Studies of Transition Metal Oxides and Dioxygen, Chem. Rev., 2009, 第 1 作者
(64) Formation and Characterization of Two FeO3 Isomers in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(65) Matrix Infrared Spectra and Density Functional Calculations of TiO3 and TiO5 in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(66) Noble-​Gas-​Induced Disproportionation Reactions: Facile Superoxo-​to-​Peroxo Conversion on Chromium Dioxide, Journal of Physical Chemistry A, 2008, 第 3 作者
(67) Matrix isolation infrared spectroscopic and theoretical study of the hydrolysis of boron dioxide in solid argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(68) Formation and Characterization of Mononuclear and Dinuclear Manganese Oxide-​Dioxygen Complexes in Solid Argon, Journal of Physical Chemistry A, 2008, 第 1 作者
(69) Formation and Characterization of the Photochemically Interconvertible Side-​On and End-​On Bonded Dioxygen-​Iron Dioxide Complexes in Solid Argon, Journal of Physical Chemistry A, 2007, 第 1 作者
(70) Formation and characterization of the oxygen-​rich scandium oxide​/dioxygen complexes ScOn (n = 4, 6, 8) in solid argon, Journal of Physical Chemistry A, 2007, 第 1 作者
(71) Matrix isolation infrared spectroscopic and theoretical study of noble gas coordinated dipalladium-​dioxygen complexes, Chemical Physics, 2007, 第 2 作者
(72) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Dinuclear Chromium Oxide Clusters: Cr2On (n = 2, 4, 6) in Solid Argon, Journal of Physical Chemistry A, 2007, 第 3 作者
(73) Formation and Characterization of the Oxygen-​Rich Hafnium Dioxygen Complexes: OHf(η2-​O2)​(η2-​O3)​, Hf(η2-​O2)​3, and Hf(η2-​O2)​4, Journal of Physical Chemistry A, 2007, 第 1 作者
(74) Formation and Characterization of the Tetranuclear Scandium Nitride: Sc4N4, Journal of Physical Chemistry A, 2007, 第 1 作者
(75) Interconvertible Side-​On- and End-​On-​Bonded Oxo-​Superoxo Titanium Ozonide Complexes, Journal of Physical Chemistry A, 2007, 第 1 作者
(76) Remarkable dinitrogen activation and cleavage by the Gd dimer: from dinitrogen complexes to ring and cage nitrides, Angewandte Chemie, International Edition, 2007, 第 3 作者
(77) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Group IV Metal Oxide Clusters: M2O2 and M2O4, Journal of Physical Chemistry A, 2007, 第 1 作者
(78) Infrared Spectra of Chlorinated Ethylene Cations: C2Cl4+, C2HCl3+, 1,​1-​C2H2Cl2+, and trans-​C2H2Cl2+ in Solid Argon, Journal of Physical Chemistry A, 2007, 第 2 作者
(79) Matrix Isolation Infrared Spectroscopic and Theoretical Study of Noble Gas Coordinated Rhodium-​Dioxygen Complexes, Journal of Physical Chemistry A, 2007, 第 2 作者
发表著作
   

科研活动

   
科研项目
( 1 ) “千人计划”青年人才项目, 主持, 国家级, 2016-10--2019-09
( 2 ) 燃料盐中锕系元素化合物的结构,性质与反应, 主持, 市地级, 2015-01--2020-03
( 3 ) 锕系金属氟化物红外光谱研究, 主持, 国家级, 2016-09--2018-08
( 4 ) 钍镤铀-中性二酰胺配合物的气相结构与反应研究, 主持, 国家级, 2018-01--2021-12
参与会议
(1)钍铀循环化学研究进展   第五届全国核化学与放射化学青年学术研讨会   2019-07-18
(2)锕系配位化合物的质谱和红外光谱研究   第三届锕系物理与化学学术交流会   2018-07-20
(3)金属氟氧化物的红外光谱研究   第4次环境放射化学战略研讨会   2017-10-26
(4)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2017-04-02
(5)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2016-07-19
(6)质谱和红外光谱方法在锕系化学   第三届全国核化学与放射化学青年学术研讨会   龚昱   2015-11-29
(7)质谱方法在锕系化学中的应用   第六届全国环境放射化学学术研讨会   龚昱   2015-09-02
(8)质谱方法在锕系化学中的应用   第十四届全国应用化学年会   龚昱   2015-07-23

合作情况

   
项目协作单位
   

指导学生

已指导学生

杨甜宏  硕士研究生  070301-无机化学  

陈秀婷  博士研究生  070301-无机化学  

现指导学生

魏睿  博士研究生  070301-无机化学  

王晨阳  博士研究生  070301-无机化学  

李杨娟  博士研究生  070301-无机化学  

熊志欣  硕士研究生  070301-无机化学  

刘西艳  博士研究生  070301-无机化学  

胡靖雯  硕士研究生  070301-无机化学