研究方向：面向光、电催化的有机小分子纳米材料制备

研究领域：

   1）石墨烯（片、带、点）的制备、修饰及应用；

   2）前沿纳米材料的制备及光、电催化研究；

   3）有机小分子前沿纳米材料（超微、超细、超薄、自组装及复合）制备、表征及性能研究；

   4）基于量子点的生物荧光检测。

我们秉承“结构决定性能”的研究理念，更注重纳米结构的制备及调控对材料性能的影响。

   

070304-物理化学（含：化学物理）

基于石墨烯的纳米材料制备及应用
纳米半导体的光电催化研究
基于石墨烯量子点的生物传感器

2004-09--2008-07   中国科学院化学研究所   博士
1999-09--2002-03   北京科技大学   硕士
1995-09--1999-07   北京科技大学   学士

博士

博士

2012年09月 至 今  中国科学院福建物质结构研究所（海西创新研究院） 课题组长  研究员

2012-09~现在, 中国科学院福建物质结构研究所, 研究员
2010-09~2012-09,荷兰格罗宁根大学, 博士后
2002-05~2004-09,福建工业总公司, 研究实习员

   

[1] 康龙田, 徐晓. 一种自支撑Cu3P基异质结电催化剂及其制备方法. ZL 2021 1 1484343.6, 2021-12-07.
[2] 康龙田, 唐多思, 刘晶晶. 一种高品质氮掺杂石墨烯量子点的制备方法. CN: CN108529601B, 2021-03-05.

   

[1] 何瑛, 康龙田. 1. Ying He, Zhuoyue Wang, Aihui Cao, Xiao Xu, Junqiang Li, Bo Zhang, and Longtian Kang*,Construction of graphene oxide–coated zinc tetraphenyporphyrin nanostructures for photocatalytic CO2 reduction to highly selective CH4 product. JOURNAL OF COLLOID AND INTERFACE SCIENCE[J]. 2023, 638: 123-134, https://doi.org/10.1016/j.jcis.2023.01.100.
[2] He, Ying, Li, Renfu, Cao, Aihui, Xu, Xiao, Huang, Weifeng, Sun, Miao, Li, Junqiang, Chen, Xueyuan, Kang, Longtian. Morphology-dependent Photoelectric Properties and Photocatalytic CO2 Reduction of Zinc Porphyrin Nanocrystals. CRYSTAL GROWTH & DESIGN[J]. 2022, 22(4): 2620-2627, http://dx.doi.org/10.1021/acs.cgd.2c00071.
[3] 康龙田. Synthesis of Axially Coordinated Cobalt Porphyrin/graphene Oxide Nanocomposite for Enhanced Electrocatalytic CO2 Reduction to CO. Chin. J. Struct. Chem.[J]. 2022, [4] Cao, Aihui, Li, Renfu, Xu, Xiao, Huang, Weifeng, He, Ying, Li, Junqiang, Sun, Miao, Chen, Xueyuan, Kang, Longtian. Cobalt-intercalated one-dimensional nanocrystals of urea perylene imide polymer for enhanced visible-light photocatalytic water oxidation. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2022, 309: http://dx.doi.org/10.1016/j.apcatb.2022.121293.
[5] Huang, Weifeng, Li, Junqiang, Xu, Xiao, Cao, Aihui, He, Ying, SUn, Miao, Kang, Longtian. Controllable dispersion of cobalt phthalocyanine molecules on graphene oxide for enhanced electrocatalytic reduction of CO2 to CO. NEW JOURNAL OF CHEMISTRY[J]. 2022, 46(15): 7153-7160, http://dx.doi.org/10.1039/d1nj06182h.
[6] 康龙田. Heterostructure of Semiconductors on Self-Supported Cuprous Phosphide Nanowires for Enhanced Overall Water Splitting. Acs Applied Materials & Interfaces[J]. 2022, 14(15): 17520-17530, [7] Zhong, Zhou, Xu, Xiao, Cao, Aihui, You, Weifeng, Tao, Zhijie, Kang, Longtian. Synthesis of one-dimensional nickel perylene diimide/iron hydroxide nanohybrid as catalyst and precursor for efficient photocatalytic and electrocatalytic water oxidation. JOURNAL OF POWER SOURCES[J]. 2021, 489: http://dx.doi.org/10.1016/j.jpowsour.2021.229493.
[8] Xu, Xiao, Cao, Aihui, You, Weifeng, Tao, Zhijie, Kang, Longtian, Liu, Jingjing. Assembly of Cobalt Layered Double Hydroxide on Cuprous Phosphide Nanowire with Strong Built-In Potential for Accelerated Overall Water Splitting. SMALL[J]. 2021, 17(39): http://dx.doi.org/10.1002/smll.202101725.
[9] Zhong, Zhou, Liu, Jingjing, Xu, Xiao, Cao, Aihui, Tao, Zhijie, You, Weifeng, Kang, Longtian. Synthesis of Z-scheme cobalt porphyrin/nitrogen-doped graphene quantum dot heterojunctions for efficient molecule-based photocatalytic oxygen evolution. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2021, 9(4): 2404-2413, http://dx.doi.org/10.1039/d0ta10196f.
[10] Tao, Zhijie, Li, Renfu, Xu, Xiao, Cao, Aihui, You, Weifeng, He, Ying, Huang, Weifeng, Kang, Longtian, Chen, Xueyuan. Controllable Synthesis and Effects of Porphyrin Copper Nanostructures on Photoelectric Properties. CRYSTAL GROWTH & DESIGN[J]. 2021, 21(6): 3582-3591, http://dx.doi.org/10.1021/acs.cgd.1c00357.
[11] Zhong, Zhou, Li, Renfu, Lin, Wenlie, Xu, Xiao, Tian, Xuemin, Li, Xiaoxin, Chen, Xueyuan, Kang, Longtian. One-dimensional nanocrystals of cobalt perylene diimide polymer with in-situ generated FeOOH for efficient photocatalytic water oxidation. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2020, 260: http://dx.doi.org/10.1016/j.apcatb.2019.118135.
[12] Li, Xiaoxin, Chai, Guoliang, Xu, Xiao, Liu, Jingjing, Zhong, Zhou, Cao, Aihui, Tao, Zhijie, You, Weifeng, Kang, Longtian. Electrocatalytic reduction of CO2 to CO over iron phthalocyanine-modified graphene nanocomposites. CARBON[J]. 2020, 167: 658-667, http://dx.doi.org/10.1016/j.carbon.2020.06.036.
[13] Xu, Xiao, Yan, Xiaomei, Zhong, Zhou, Kang, Longtian, Yao, Jiannian. The construction of porous graphene tri-doped with B, N and Co for enhanced oxygen reduction reaction. CARBON[J]. 2019, 145: 311-320, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000466073000034.
[14] Liu, Jingjing, Xu, Xiao, Chen, Zhitao, Li, Renfu, Kang, Longtian, Yao, Jiannian. A fluorometric displacement assay for adenosine triphosphate using layered cobalt(II) double hydroxide nanosheets. MICROCHIMICA ACTA[J]. 2019, 186(4): https://www.webofscience.com/wos/woscc/full-record/WOS:000462938600002.
[15] Xu, Xiao, Tian, Xuemin, Zhong, Zhou, Kang, Longtian, Yao, Jiannian. In-situ growth of iron/nickel phosphides hybrid on nickel foam as bifunctional electrocatalyst for overall water splitting. JOURNAL OF POWER SOURCES[J]. 2019, 424: 42-51, http://dx.doi.org/10.1016/j.jpowsour.2019.03.084.
[16] Tian, Xuemin, Lin, Chensheng, Zhong, Zhou, Li, Xiaoxin, Xu, Xiao, Liu, Jingjing, Kang, Longtian, Chai, Guoliang, Yao, Jiannian. Effect of Axial Coordination of Iron Porphyrin on Their Nanostructures and Photocatalytic Performance. CRYSTAL GROWTH & DESIGN[J]. 2019, 19(6): 3279-3287, http://dx.doi.org/10.1021/acs.cgd.9b00125.
[17] Yan, Xiaomei, Xu, Xiao, Liu, Qin, Guo, Jia, Kang, Longtian, Yao, Jiannian. Functionalization of multi-walled carbon nanotubes with iron phthalocyanine via a liquid chemical reaction for oxygen reduction in alkaline media. JOURNAL OF POWER SOURCES[J]. 2018, 389: 260-266, http://dx.doi.org/10.1016/j.jpowsour.2018.03.042.
[18] JingJing Liu, ZhiTao Chen, Zhou Zhong, XiaoMei Yan, LongTian Kang, JianNian Yao. Fluorescence-tunable probe for antioxidant capacity assay based on dopamine self-polymerization on graphitic carbon nitride. SENSORS & ACTUATORS: B. CHEMICAL. 2018, 262: 570-576, http://dx.doi.org/10.1016/j.snb.2018.02.062.
[19] Xu, Xiao, Zhong, Zhou, Yan, Xiaomei, Kang, Longtian, Yao, Jiannian. Cobalt layered double hydroxide nanosheets synthesized in water-methanol solution as oxygen evolution electrocatalysts. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2018, 6(14): 5999-6006, https://www.webofscience.com/wos/woscc/full-record/WOS:000431506600060.
[20] Yan, Xiaomei, Xu, Xiao, Zhong, Zhou, Liu, Jingjing, Tian, Xuemin, Kang, Longtian, Yao, Jiannian. The effect of oxygen content of carbon nanotubes on the catalytic activity of carbon-based iron phthalocyanine for oxygen reduction reaction. ELECTROCHIMICA ACTA[J]. 2018, 281: 562-570, http://dx.doi.org/10.1016/j.electacta.2018.05.183.
[21] Guo, Jia, Yan, Xiaomei, Liu, Qin, Li, Qiang, Xu, Xiao, Kang, Longtian, Cao, Zhanmin, Chai, Guoliang, Chen, Jun, Wang, Yaobing, Yao, Jiannian. The synthesis and synergistic catalysis of iron phthalocyanine and its graphene-based axial complex for enhanced oxygen reduction. NANO ENERGY[J]. 2018, 46: 347-355, http://dx.doi.org/10.1016/j.nanoen.2018.02.026.
[22] Liu, L J, Lai, Y D, Li, H H, Kang, L T, Liu, J J, Cao, Z M, Yao, J N. The role of dissolution in the synthesis of high-activity organic nanocatalysts in a wet chemical reaction. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2017, 5(17): 8029-8036, https://www.webofscience.com/wos/woscc/full-record/WOS:000400553700044.
[23] Liu JingJing, Tang Duosi, Chen Zhitao, Yan Xiaomei, Zhong Zhou, Kang Longtian, Yao Jiannian. Chemical redox modulated fluorescence of nitrogen-doped graphene quantum dots for probing the activity of alkaline phosphatase. BIOSENSORS AND BIOELECTRONICS[J]. 2017, 94: 271-277, http://dx.doi.org/10.1016/j.bios.2017.03.017.
[24] Pan, Jiannan, Kang, Longtian, Huang, Ping, Jia, Ziyan, Liu, Jingjing, Yao, Jiannian. The controllable synthesis of ultrafine one-dimensional small-molecule semiconducting nanocrystals in surfactant-assisted wet chemical reactions and their confinement effect. JOURNAL OF MATERIALS CHEMISTRY C[J]. 2017, 5(25): 6377-6385, https://www.webofscience.com/wos/woscc/full-record/WOS:000404722500032.
[25] 康龙田. A pure organic heterostructure of m-oxo dimeric iron(III) porphyrin and graphitic-C3N4 for solar H2 roduction from water. Journal of Materials Chemistry A. 2016, [26] Li, Huihui, Jie, Liulun, Pan, Jiannan, Kang, Longtian, Yao, Jiannian. Direct photocatalytic hydrogen evolution from water splitting using nanostructures of hydrate organic small molecule as photocatalysts. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2016, 4(17): 6577-6584, https://www.webofscience.com/wos/woscc/full-record/WOS:000374862600040.
[27] Tang, Duosi, Liu, Jingjing, Yan, Xiaomei, Kang, Longtian. Graphene oxide derived graphene quantum dots with different photoluminescence properties and peroxidase-like catalytic activity. RSC ADVANCES[J]. 2016, 6(56): 50609-50617, https://www.webofscience.com/wos/woscc/full-record/WOS:000377515200028.
[28] Lai, Yiding, Li, Huihui, Pan, Jiannan, Guo, Jia, Kang, Longtian, Cao, Zhanmin. Synthesis of Ultrathin Nanosheets of Perylene. CRYSTAL GROWTH & DESIGN[J]. 2015, 15(3): 1011-1016, https://www.webofscience.com/wos/woscc/full-record/WOS:000350614400001.
[29] Jing-Jing Liu, Zhi-Tao Chen, Duo-Si Tang, Yao-Bing Wang, Long-Tian Kang, Jian-Nian Yao. Graphene quantum dots-based fluorescent probe for turn-on sensing of ascorbic acid. SENSORS & ACTUATORS: B. CHEMICAL. 2015, 212: 214-219, http://dx.doi.org/10.1016/j.snb.2015.02.019.
[30] Han, Mingkai, Rong, Yangchun, Li, Qiang, Xing, Xianran, Kang, Longtian. Thermal expansion of nano-sized BaTiO3. CRYSTENGCOMM[J]. 2015, 17(9): 1944-1951, https://www.webofscience.com/wos/woscc/full-record/WOS:000350447700008.
[31] Spyrou, Konstantinos, Kang, Longtian, Diamanti, Eumorfia K, Gengler Regis, Y N, Gournis, Dimitrios, Prato, Maurizio, Rudolf, Petra. A novel route towards high quality fullerene-pillared graphene. CARBON[J]. 2013, 61: 313-320, http://dx.doi.org/10.1016/j.carbon.2013.05.010.
[32] 姚建年. Controlled Morphogenesis of Organic Polyhedral Nanocrystals from Cubes, Cubooctahedrons, to Octahedrons by Manipulating the Growth Kinetics. J AM CHEM SOC[J]. 2011, 133(6): 1895-1901, http://ir.iccas.ac.cn/handle/121111/28741.
[33] Kang, Longtian, Fu, Hongbing, Cao, Xinqiang, Shi, Qiang, Yao, Jiannian. Controlled Morphogenesis of Organic Polyhedral Nanocrystals from Cubes, Cubooctahedrons, to Octahedrons by Manipulating the Growth Kinetics. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2011, 133(6): 1895-1901, https://www.webofscience.com/wos/woscc/full-record/WOS:000287831800062.
[34] 姚建年. Superhydrophobic pure silver surface with flower-like structures by a facile galvanic exchange reaction with Ag(NH3)2OH. CHEM COMMUN. 2008, , 2692–2694.-, [35] 姚建年. Rapid room-temperature synthesis of silver nanoplates with tunable in-plane surface plasmon resonance from visible to near-IR. J MATER CHEM. 2008, 18(24): , 2673–2678.-, [36] Luo, Zhixun, Liu, Yuanyuan, Kang, Longtian, Wang, Yaobing, Fu, Hongbing, Ma, Ying, Yao, Jiannian, Loo, Boon H. Controllable Nanonet Assembly Utilizing a Pressure-Difference Method Based on Anodic Aluminum Oxide Templates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2008, 47(46): 8905-8908, https://www.webofscience.com/wos/woscc/full-record/WOS:000260878700025.
[37] Kang, Longtian, Chen, Yu, Xiao, Debao, Peng, Aidong, Shen, Fugang, Kuang, Xun, Fu, Hongbing, Yao, Jiannian. Organic core/diffuse-shell nanorods: fabrication, characterization and energy transfer. CHEMICAL COMMUNICATIONS[J]. 2007, 2695-2697, http://www.corc.org.cn/handle/1471x/2380871.
[38] 姚建年. A Colloid Chemical Reaction Route to the Preparation of Nearly Monodispersed Perylene Nanoparticles: Size-Tunable Synthesis and Three Dimensional Self-Organization,. J AM CHEM SOC. 2007, 129(23): , 7305-7312., [39] Kang, LT, Qiao, ZY, Yuan, BY, Cao, ZM. Calculation of interfacial tension based on sub-lattice model and thermodynamic data. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY[J]. 2003, 27(1): 57-64, http://dx.doi.org/10.1016/S0364-5916(03)00030-0.
[40] Junqiang Li, Weifeng Huang, Zhuoyue Wang, Xiao Xu, Miao Sun, Longtian Kang. Controllable Dispersion of Cobalt Phthalocyanine Molecules on Graphene Oxide for Enhanced Photocatalytic CO2 Reduction. MOLECULAR CATALYSIS. http://dx.doi.org/10.1016/j.mcat.2023.113253.

   

（ 1 ） 有机小分子纳米材料自组装、二次生长以及石墨烯的应用, 主持, 国家级, 2013-01--2013-12
（ 2 ） 纳米光子学测试仪的研制与推广，任务四“纳米光子学测试仪在非线性光学晶态材料中的应用研究”, 参与, 国家级, 2012-10--2015-09
（ 3 ） 所拨经费, 主持, 市地级, 2012-09--2015-09
（ 4 ） 石墨烯辅助的有机小分子前沿纳米晶体构筑及应用, 主持, 国家级, 2015-01--2018-12

已指导学生

李慧慧  硕士研究生  085204-材料工程  

刘伦杰  硕士研究生  085216-化学工程  

潘剑南  博士研究生  070304-物理化学  

现指导学生

田学敏  硕士研究生  070304-物理化学  

钟洲  博士研究生  070304-物理化学  

李小鑫  硕士研究生  070304-物理化学