基本信息
蒋高喜  男  博导  中国科学院兰州化学物理研究所
电子邮件: gxjiang@licp.cas.cn
通信地址: 江苏省苏州市工业园区金鸡湖大道99号苏州纳米城NW-8栋
邮政编码:

招生信息

   
招生专业
070303-有机化学
070304-物理化学
招生方向
金属有机化学
催化化学,均相催化
均相催化

教育背景

2003-09--2008-07   中科院上海有机化学研究所   博士
1999-09--2003-07   北京大学医学部药学院   学士学位

工作经历

   
工作简历
2012-01~现在, 中科院兰州化学物理研究所, 研究员
2009-01~2011-12,德国马普煤炭研究所, 博士后
2008-08~2008-12,香港大学化学系, 研究员助理
2003-09~2008-07,中科院上海有机化学研究所, 博士
1999-09~2003-07,北京大学医学部药学院, 学士学位

专利与奖励

   
专利成果
( 1 ) 一种苯甲醛及其衍生物的制备方法, 2016, 第 1 作者, 专利号: 201611075647.6
( 2 ) 一种喹啉衍生物的制备方法, 2016, 第 1 作者, 专利号: 201610578354.3
( 3 ) 苯并吡喃化合物及其制备方法, 2018, 第 1 作者, 专利号: 201810121584.6
( 4 ) 一种喹啉衍生物的制备方法, 2019, 第 1 作者, 专利号: CN106543078B
( 5 ) 一种单氟烯烃衍生物的制备方法, 2020, 第 1 作者, 专利号: 2020100025201

出版信息

   
发表论文
(1) Enantioselective Construction of Quinoxaline-Based Heterobiaryls and P,N-Ligands via Chirality Transfer Strategy, Org. Lett., 2021, 通讯作者
(2) High Chemo-/Stereoselectivity for Synthesis of Polysubstituted Monofluorinated Pyrimidyl Enol Ether Derivatives, Org. Lett., 2021, 通讯作者
(3) Enantioselective Construction of C−C Axially Chiral Quinazolinones via Chirality Exchange and Phase-Transfer Catalysis, Org. Lett., 2021, 通讯作者
(4) Enantioselective Construction of C−C Axially Chiral Quinazolinones via Chirality Exchange and Phase-Transfer Catalysis, Synlett, 2021, 通讯作者
(5) Synthesis of gem-Difluoroalkenes via a Sequence of Hydroboration and 1,2-Elimination of α,β-Unsaturated Carbonyls, Synlett, 2021, 通讯作者
(6) Fluorine Effects for Tunable C–C and C–S Bond Cleavage in Fluoro-Julia– Kocienski Intermediates, CCS Chemistry, 2020, 通讯作者
(7) Grignard-Reagent-Promoted Desulfonylation/Intramolecular Coupling for the Synthesis of 2‑(1-Fluorovinyl)pyridines, Org. Lett., 2020, 通讯作者
(8) Chiral Brønsted acid-catalyzed dynamic kinetic resolution of atropisomeric ortho-formyl naphthamides, Chem. Commun.,, 2020, 通讯作者
(9) Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger p-conjugated naphthopyrans with aggregation-induced emission characters, Chem. Sci., 2019, 通讯作者
(10) Catalytic Asymmetric Cascade Cyclization for Constructing Three Contiguous Stereocenters in Pyrrolobenzodiazepine-Based Cyclopentanones, Org. Lett., 2019, 通讯作者
(11) Brønsted Acid-Catalyzed Asymmetric Ring-Closing Alkylation of Inert N-substituted Pyrroles with α, β-Unsaturated Ketones, Adv. Synth. Catal, 2019, 通讯作者
(12) Controlled chemoselective defluorination and non-defluorination for [5 + 1] aromatic annulation via Meisenheimer-type nitrogen anion and radical intermediates, Chem. Sci.,, 2019, 通讯作者
(13) Direct Construction of Axially Chiral Arylquinoline via Acid Promoted Dehydrative Cyclization/Oxidation of Diarylmethanols, J. Mol. Cat (China), 2019, 通讯作者
(14) Rh(III)-Catalyzed regioselective mono- and di-iodination of azobenzenes using alkyl iodide, Org. Biomol. Chem., 2018, 通讯作者
(15) Synthesis of Non-Natural Amino Acid Derivatives Bearing Triphenylamine Core Skeleton via Pd-Catalyzed Direct Asymmetric Allylic Alkylation, ACTA CHIMICA SINICA, 2018, 通讯作者
(16) Hydroarylation and Hydroalkenylation of Vinylarenes by Bronsted Acidic Ionic Liquid, Journal of Molecular Catalysis, 2018, 通讯作者
(17) From Palladium to Brønsted Acid Catalysis: Highly Enantioselective Regiodivergent Addition of Alkoxyallenes to Pyrazolones, Angew. Chem. Int. Ed., 2017, 通讯作者
(18) A Green Aerobic Oxidative Synthesis of Pyrrolo[1,2‑a]quinoxalines from Simple Alcohols without Metals and Additives, J. Org. Chem., 2017, 通讯作者
(19) Assembly of Diversely Substituted Quinolines via Aerobic Oxidative Aromatization from Simple Alcohols and Anilines, J. Org. Chem., 2017, 通讯作者
(20) Tunable Aerobic Oxidative Hydroxylation/Dehydrogenative Homocoupling of Pyrazol-5-ones under Transition-Metal-Free Conditions, Org. Lett., 2017, 通讯作者
(21) Recent Advances in Pd-Catalyzed Tsuji-Trost-Type Allylic Alkylation with Allylic Alcohols, Current Catalysis, 2017, 通讯作者
(22) AgNO3 as nitrogen source for rhodium(III)-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes, Chem. Commun.,, 2016, 通讯作者
(23) Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o‑alkyloxyphenyl)phosphine to Aryl Acids, Organometallics, 2016, 通讯作者
(24) Efficient hydroarylation and hydroalkenylation of vinylarenes by Brønsted acid catalysis, RSC Adv, 2016, 通讯作者
(25) Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes, Org. Biomol. Chem.,, 2016, 通讯作者
(26) Triarylphosphines as Aryl Donors for Pd(II)-Catalyzed Aromatic Coupling of Oxabenzonorbornadienes, Org. Lett., 2015, 通讯作者
(27) Palladium catalyzed direct allylation of azlactones with simple allylic alcohols in the absence of any activators, RSC Advances, 2014, 通讯作者
(28) Br?nsted Acid Accelerated Pd-Catalyzed Direct Asymmetric Allylic Alkylation of Azlactones with Simple Allylic Alcohols: A Practical Access to Quaternary Allylic Amino Acid Derivatives, Org. Lett., 2014, 通讯作者
(29) Metal-Free Synthesis of ortho-CHO Diaryl Ethers by a Three-Component Sequential Coupling, Org. Lett., 2014, 通讯作者
(30) Highly Efficient Direct Allylation of Oxindoles with Simple Allylic Alcohols Enabled by Palladium-Br?nsted Acid Catalysis, synlett, 2014, 通讯作者
(31) Direct Asymmetric a-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts, Angew. Chem. Int. Ed., 2011, 第 1 作者
(32) A Highly Enantioselective Overman Rearrangement through Asymmetric Counteranion-Directed Palladium Catalysis, Angew. Chem. Int. Ed., 2011, 第 1 作者
(33) Palladium/Br?nsted Acid-Catalyzed a-Allylation of Aldehydes with Allylic Alcohols, Adv. Synth. Catal., 2011, 第 1 作者
(34) Enantioselective Hydrovinylation via Asymmetric counteranion-directed Ruthenium Catalysis, Chem. Commun., 2011, 第 1 作者
(35) Highly Efficient Oxidation of Amines to Imines by Singlet Oxygen and Its Application in Ugi-Type Reactions, Organic Letters, 2009, 第 1 作者
(36) Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation–Isomerization Pathway, Angew. Chem. Int. Ed., 2008, 第 1 作者
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科研活动

   
科研项目
( 1 ) 不对称催化与合成, 主持, 部委级, 2013-01--2017-02
( 2 ) 新颖有机小分子催化剂的设计、合成和应用, 主持, 市地级, 2012-01--2014-01
( 3 ) 基于手性肽链的抗衡阴离子的设计和在钯催化不对称烯丙基化反应中的应用, 主持, 国家级, 2013-01--2015-12
( 4 ) 有关膦化合物新用途的研究, 主持, 省级, 2015-07--2017-06
( 5 ) 基于原子经济性概念的不对称烯丙基化反应研究, 主持, 国家级, 2017-01--2019-12
( 6 ) 高原子经济性构建手性季碳中心化合物反应的研究, 主持, 省级, 2016-07--2019-06
( 7 ) 联烯醚在有机合成中的应用, 主持, 省级, 2019-07--2021-07
( 8 ) XXX产业化研究, 主持, 院级, 2020-01--2020-12
( 9 ) 不对称合成与催化, 主持, 部委级, 2019-01--2020-12
参与会议
(1)从手性钯催化到手性膦酸催化:烯丙基化构建手性化合物   第17届全国青年催化会议   2018-08-17
(2)从手性钯催化到手性膦酸催化: 烯丙基化构建手性季碳中心   中国化学第31届年会   2018-05-07
(3)Oxidative Synthesis and Asymmetric Allylic Alkylation of N/O-Containing Heterocyclic Compounds   第一届光电材料合成与应用论坛   2017-12-02
(4)Oxidative Synthesis and Asymmetric Allylic Alkylation of N-Containing Heterocyclic Compounds   新化学新材料高峰论坛   2017-11-27