1.芳环化合物的氢化和氢官能团化
设计合成新的催化体系实现对碳芳环化合物的不对称氢化及氢硼化、氢硅化、氢酯化等氢官能团化反应，为手性环状化合物的合成提供新策略。
2. 手性硼酸催化剂的设计合成及应用

设计合成手性硼酸催化剂并将其应用于有机合成反应中，探索其催化反应历程，为新型高效硼酸催化剂的设计提供基础。

3. 多齿含氮手性配体的设计及合成

以四氢咪唑啉和四氢嘧啶环为基本结构单元，设计合成新型手性多齿含氮配体并将其应用于催化反应中，为多齿含氮类配体提供一种新的配体骨架。

2002-09--2006-01   中科院大连化学物理研究所   博士研究生
1999-09--2002-06   华中师范大学   硕士研究生
1995-09--1999-06   华中师范大学   学士

2006.11-2008.12，获得德国洪堡奖学金资助在亚琛工业大学Carsten Bolm教授研究组进行博士后研究

2006.1-2006.9，大连化物所201组临时工作人员

2009.2-2009.9，华中师范大学化学学院任教

2009.10-至今，中科院大连化物所工作，副研究员

   

2006年获得中国科学院院长优秀奖

（1） Regioselective hydroesterification of alkenes and alkenylphenols utilizing CO 2 and hydrosilane †, CHEMICAL SCIENCE, 2023, 第 2 作者
（2） Hydrogenation of Alkyl Carboxylic Acids with Tetrahydropyrimidine-Derived Iridium Complexes under Mild Conditions, ACS CATALYSIS, 2022, 第 1 作者
（3） Carbo-Carboxylation of Alkenes via Intramolecular Heck Carbonylation Utilizing CO2 and Hydrosilane, ACS CATALYSIS, 2022, 第 2 作者
（4） Controllable stereoinversion in DNA-catalyzed olefin cyclopropanation via cofactor modification, CHEMICAL SCIENCE, 2021, 第 3 作者
（5） Water-initiated hydrocarboxylation of terminal alkynes with CO2 and hydrosilane, CHEMICAL COMMUNICATIONS, 2021, 第 2 作者
（6） Enantioselective Olefin Cyclopropanation with G-Quadruplex DNA-Based Biocatalysts, ACS CATALYSIS, 2020, 第 4 作者
（7） Tandem one-pot co2 reduction by pmhs and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids, CHEMICAL COMMUNICATIONS, 2018, 第 2 作者
（8） Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand, GREEN CHEMISTRY, 2018, 第 1 作者
（9） Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6, CHINESE JOURNAL OF CATALYSIS, 2017, 第 4 作者
（10） Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi2WO6, CHINESE JOURNAL OF CATALYSIS, 2017, 第 4 作者
（11） 钨酸铋担载钯纳米粒子光催化甲苯及其衍生物到醛的氧化反应（英文）, Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi_2WO_6, 催化学报, 2017, 第 4 作者
（12） Base-free hydrogenation of co2 to formic acid in water with an iridium complex bearing a n, n '-diimine ligand, GREEN CHEMISTRY, 2016, 第 1 作者
（13） A highly enantioselective thiolation of sulfonyl indoles to access 3-sec-sulfur-substituted indoles in water, CHEMICAL COMMUNICATIONS, 2016, 第 2 作者
（14） Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-1-(arylsulfonyl)alkylpyrroles in an Oil/Water Biphasic System, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 第 3 作者
（15） Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme, CHEMICAL COMMUNICATIONS, 2016, 第 5 作者
（16） Iodide-promoted dehydrogenation of formic acid on a rhodium complex, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 第 2 作者
（17） In situ electrodeposited indium nanocrystals for efficient co2 reduction to co with low overpotential, ACS CATALYSIS, 2016, 第 3 作者
（18） Rh—PPh3—polymer@mesosilica composite catalyst for the hydroformylation of 1—octene, CHINESE JOURNAL OF CATALYSIS催化学报, 2015, 第 2 作者
（19） Rh-PPh3-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene, CHINESE JOURNAL OF CATALYSIS, 2015, 第 2 作者
（20） 铑-三苯基膦配合物功能化的聚合物@介孔氧化硅复合材料在1-辛烯氢甲酰化反应中的应用, Rh-PPh3-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene, 催化学报, 2015, 第 2 作者
（21） 铑-三苯基膦配合物功能化的聚合物@介孔氧化硅复合材料在1-辛烯氢甲酰化反应中的应用, Rh-PPh3-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene, 催化学报, 2015, 第 2 作者
（22） Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation, CATALYSIS SCIENCE & TECHNOLOGY, 2015, 第 2 作者
（23） 含有手性BINAP基团的共轭微孔聚合材料应用于喹啉高效不对称氢化反应, Efficient enantioselective hydrogenation of quinolines catalyzed by conjugated microporous polymers with embedded chiral BINAP ligand, 催化学报, 2015, 第 3 作者
（24） A remarkable difference in CO2 hydrogenation to methanol on Pd nanoparticles supported inside and outside of carbon nanotubes, CHEMICAL COMMUNICATIONS, 2015, 第 2 作者
（25） 稳定于碳纳米管的Pt高价态物种在不对称氢化反应中的作用, Highly oxidized Pt species stabilized inside carbon nanotubes for asymmetric hydrogenation, 催化学报, 2015, 第 2 作者
（26） Selective oxidation of sulfides on Pt/BiVO4 photocatalyst under visible light irradiation using water as the oxygen source and dioxygen as the electron acceptor, JOURNAL OF CATALYSIS, 2015, 第 7 作者
（27） Unprecedentedly High Formic Acid Dehydrogenation Activity on an Iridium Complex with an N,N′-Diimine Ligand in Water, CHEMISTRY-A EUROPEAN JOURNAL, 2015, 第 2 作者
（28） 稳定于碳纳米管的Pt高价态物种在不对称氢化反应中的作用, Highly oxidized Pt species stabilized inside carbon nanotubes for asymmetric hydrogenation, 催化学报, 2015, 第 2 作者
（29） Highly oxidized Pt species stabilized inside carbon nanotubes for asymmetric hydrogenation, CHINESE JOURNAL OF CATALYSIS, 2015, 第 2 作者
（30） 含有手性BINAP基团的共轭微孔聚合材料应用于喹啉高效不对称氢化反应, Efficient enantioselective hydrogenation of quinolines catalyzed by conjugated microporous polymers with embedded chiral BINAP ligand, 催化学报, 2015, 第 3 作者
（31） Efficient enantioselective hydrogenation of quinolines catalyzed by conjugated microporous polymers with embedded chiral BINAP ligand, CHINESE JOURNAL OF CATALYSIS, 2015, 第 3 作者
（32） Enantioselective hydrogenation of α,β-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes, JOURNAL OF CATALYSIS, 2014, 第 2 作者
（33） Enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes, JOURNAL OF CATALYSIS, 2014, 第 2 作者
（34） Synthesis and Photovoltaic Properties of Polythiophene Incorporating with 3,4-Difluorothiophene Units, CHINESE JOURNAL OF CHEMISTRY, 2013, 第 5 作者
（35） Enantioselective Michael addition reactions in water using a DNA-based catalysts, the 6th asia-pacific congress on catalysis, 2013, 第 4 作者
（36） DNA Catalyzed Dithioacetalization in Water, ACTA CHIMICA SINICA, 2013, 第 4 作者
（37） DNA Catalyzed Dithioacetalization in Water, ACTA CHIMICA SINICA, 2013, 第 4 作者
（38） Enantioselective Michael addition reactions in water using a DNA-based catalyst, TETRAHEDRON, 2013, 第 4 作者
（39） CNTs Supported Rh Nanoparticles-Catalyzed Hydroformylation Reactions, the 6th asia-pacific congress on catalysis, 2013, 第 1 作者
（40） A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of a,b-unsaturated ketones to allylic alcohol, TETRAHEDRON LETTERS, 2013, 第 1 作者
（41） Synthesis and Photovoltaic Properties of Polythiophene Incorporating with 3,4-Difluorothiophene Units, Synthesis and Photovoltaic Properties of Polythiophene Incorporating with 3,4-Difluorothiophene Units, 中国化学：英文版, 2013, 第 5 作者
（42） An unexpected effect of water on the asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in carbon nanotubes, JOURNAL OF CATALYSIS, 2013, 第 2 作者
（43） An unexpected effect of water on the asymmetric hydrogenation of α-ketoesters on platinum nanoparticles confined in carbon nanotubes, JOURNAL OF CATALYSIS, 2013, 第 2 作者
（44） Nano Si preparation by constant cell voltage electrolysis of FFC-Cambridge Process in molten CaCl 2, Nano Si preparation by constant cell voltage electrolysis of FFC-Cambridge Process in molten CaCl 2, 能源化学：英文版, 2013, 第 2 作者
（45） A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol, TETRAHEDRON LETTERS, 2013, 通讯作者
（46） Nano Si preparation by constant cell voltage electrolysis of FFC-Cambridge Process in molten CaCl2, JOURNAL OF ENERGY CHEMISTRY, 2013, 第 2 作者
（47） Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme, CHEMICAL COMMUNICATIONS, 2012, 第 5 作者
（48） Enantioselective Diels-Alder Reaction Catalyzed by G-Quadruplex DNA and Its Metalloenzyme, 15TH INTERNATIONAL CONGRESS ON CATALYSIS, 2012, 第 6 作者
（49） The Synthesis of Chiral Isotetronic Acids with Amphiphilic Imidazole/Pyrrolidine Catalysts Assembled in Oil-in-Water Emulsion Droplets, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 第 4 作者
（50） Chiral Sulfur Compounds Studied by Raman Optical Activity: tert-Butanesulfinamide and its Precursor tert-Butyl tert-Butanethiosulfinate, CHIRALITY, 2012, 第 3 作者
（51） The Confinement Effect of Carbon Nanotubes on the Asymmetric Hydrogenation of α-ketoester, 15TH INTERNATIONAL CONGRESS ON CATALYSIS, 2012, 第 3 作者
（52） Asymmetric Hydrogenation of Heteroarenes and Arenes, CHEMICAL REVIEWS, 2012, 第 3 作者
（53） Enantioselective Diels-Alder Reactions with G-Quadruplex DNA-Based Catalysts, ANGEWANDTECHEMIEINTERNATIONALEDITION, 2012, 第 6 作者
（54） Chiral Primary Amine Organocatalysts for Syn-selective Asymmetric Cross-Aldol Reactions, CHINESE JOURNAL OF CATALYSIS, 2011, 第 3 作者
（55） Recyclable enamine catalysts for asymmetric direct cross-aldol reaction of aldehydes in emulsion media, GREEN CHEMISTRY, 2011, 第 3 作者
（56） Recyclable chiral diamine-polyoxometalate (POM) acids catalyzed asymmetric direct aldol reaction of aromatic aldehydes with long-chain aliphatic ketones, TETRAHEDRON LETTERS, 2011, 第 2 作者
（57） 手性伯胺催化剂用于顺式选择性的不对称Cross-Aldol反应, Chiral Primary Amine Organocatalysts for Syn-selective Asymmetric Cross-Aldol Reactions, 催化学报, 2011, 第 3 作者
（58） 芳香杂环化合物喹啉和异喹啉的不对称氢化研究, Studies on the Asymmetric Hydrogenation of Heteroaromatic Compounds, Quinolines and Isoquinolines, 2010, 第 1 作者
（59） 芳香杂环化合物喹啉和异喹啉的不对称氢化研究, Studies on the Asymmetric Hydrogenation of Heteroaromatic Compounds, Quinolines and Isoquinolines, 2010, 第 1 作者
（60） Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines, JOURNAL OF ORGANIC CHEMISTRY, 2009, 第 4 作者
（61） Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines; 2-Functionalized and 2;3-Disubstituted Quinolines, JOURNAL OF ORGANIC CHEMISTRY, 2009, 第 4 作者
（62） A simple and highly effective method for hydrogenation of arenes by Rh(COD)Cl(2), TETRAHEDRON LETTERS, 2009, 第 2 作者
（63） Highly enantioselective Ir-catalyzed hydrogenation of exocyclic enamines, TETRAHEDRON-ASYMMETRY, 2009, 第 3 作者
（64） A Simple and Highly Efficient Method for Hydrogenation of Arenes by Rh(COD)Cl2, TETRAHEDRON LETTERS, 2009, 第 2 作者
（65） An efficient catalytic system for the hydrogenation of quinolines, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 第 1 作者
（66） Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines, JOURNAL OF ORGANIC CHEMISTRY, 2007, 第 2 作者
（67） An Efficient Catalyst System for the Hydrogenation of Quinolines, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 第 1 作者
（68） Highly Enantioselectivie Palladium-Catalyzed Asymmetric Hydrogenation of Activated Imines, JOURNAL OF ORGANIC CHEMISTRY, 2007, 第 2 作者
（69） 1－取代异喹啉合成新方法的研究, 有机化学, 2006, 第 2 作者
（70） Asymmetric Hydrogenation of Quinolines and Isoquinolines Activated by Chlorformates, ANGEWANDTE CHEMIE INTERNATIONAL EDITION, 2006, 第 1 作者
（71） A new synthetic method of 1-substituted isoquinolines, CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2006, 第 2 作者
（72） 均相体系中铱催化2-取代-1；2－二氢喹啉类化合物的脱氢芳构化, 催化学报, 2005, 第 1 作者
（73） 芳香杂环化合物不对称催化氢化反应的研究进展, 有机化学, 2005, 第 1 作者
（74） 对映选择性铱催化氢化取代芳香吡啶环和吡嗪环的方法, 科技开发动态, 2004, 第 2 作者

   

（ 1 ） 羧酸及其衍生物的催化氢化, 负责人, 其他任务, 2020-01--2023-12