基本信息
罗三中  男  博导  中国科学院化学研究所
电子邮件: luosz@iccas.ac.cn
通信地址: 北京海淀中关村北一街2号
邮政编码: 100190

招生信息

   
招生专业
070303-有机化学
招生方向
仿生不对称催化,物理有机,超分子化学
有机光化学
有机电化学

教育背景

2004-03--2005-05   美国俄亥俄州立大学   访问学生
2002-09--2005-06   中国科学院化学研究所   理学博士
1999-09--2002-06   南开大学化学系   理学硕士
1995-09--1999-06   郑州大学化学系   理学学士

工作经历

   
工作简历
2011-06~现在, 中国科学院化学研究所, 研究员/课题组长
2007-10~2011-06,中国科学院化学研究所, 副研究员/课题组长
2005-07~2007-10,中国科学院化学研究所, 助理研究员
2004-03~2005-05,美国俄亥俄州立大学, 访问学生
2002-09~2005-06,中国科学院化学研究所, 理学博士
1999-09~2002-06,南开大学化学系, 理学硕士
1995-09~1999-06,郑州大学化学系, 理学学士

教授课程

有机化学II
有机化学I
现代有机合成艺术与挑战讲座

专利与奖励

   
奖励信息
(1) 物理有机青年奖, 其他, 2017
(2) Asian Core Program Lectureship, 其他, 2015
(3) 中国科学院青年创新促进会优秀会员, 院级, 2015
(4) 中国青年五四奖章, 国家级, 2014
(5) 启明星优秀人才, 院级, 2013
(6) 化学科学奖教金创新奖, 研究所(学校), 2013
(7) Thieme Journal Award, 其他, 2012
(8) 卢嘉锡青年人才奖, 院级, 2009
(9) 中国化学会青年化学奖, 国家级, 2008
专利成果
( 1 ) 一种手性α-氨基酸衍生物及其制备方法, 2017, 第 1 作者, 专利号: 201710579976.2
( 2 ) 一种手性β-氨基酸衍生物及其制备方法, 2017, 第 1 作者, 专利号: 201710579915.6
( 3 ) 合成手性二氢吡喃环类化合物的方法, 2017, 第 1 作者, 专利号: 201710361604.4

出版信息

   
发表论文
(1) Oxidative Synthesis of Benzimidazoles, Quinoxalines, and Benzoxazoles from Primary Amines by ortho-Quinone Catalysis, Org. Lett., 2017, 通讯作者
(2) 催化不对称光诱导自由基反应, Acta Chim. Sinica., 2017, 通讯作者
(3) Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis., J. Am. Chem. Soc., 2017, 通讯作者
(4) Reagent-Controlled Enantioselectivity Switch in Asymmetric Fluorination of β-Ketocarbonyls by Chiral Primary Amine Catalysis., Chem. Sci., 2017, 通讯作者
(5) Organocatalysis in Inert C–H Bond Functionalization, Chem. Rev., 2017, 通讯作者
(6) Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Couplingof Tertiary Amines to Ketones by Synergistic Multiple Catalysis, Angew. Chem. Int. Ed., 2017, 通讯作者
(7) Catalytic Asymmetric Electrochemical Oxidative Coupling of Tertiary Amines with Simple Ketones., Org. Lett., 2017, 通讯作者
(8) Enantio- and Diastereoselective Cyclopropanation of β,γ-Unsaturated α-Ketoester by a Chiral Phosphate/Indium(III) Complex, Org. Lett., 2017, 通讯作者
(9) Divergent Coupling of β,γ-Unsaturated α-Ketoesters with Simple Olefins: Vinylation and [2 + 2] Cycloaddition, Org. Lett., 2017, 通讯作者
(10) Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex, Angew. Chem. Int. Ed., 2017, 通讯作者
(11) Enantioselective Decarboxylative α-Alkynylation of β-Ketocarbonyls via a Catalytic α-Imino Radical Intermediate, Org. Lett., 2017, 通讯作者
(12) Catalytic Asymmetric Mannich Reaction with N-Carbamoyl Imine Surrogates of Formaldehyde and Glyoxylate, Angew. Chem. Int. Ed., 2017, 通讯作者
(13) Linear free-energy relationships in asymmetric catalysis, SCIENTIA SINICA Chimica, 2016, 通讯作者
(14) Oxidative Radical Addition−Cyclization of Sulfonyl Hydrazones with Simple Olefins by Binary Acid Catalysis, Org. Lett, 2016, 通讯作者
(15) Asymmetric Retro-Claisen Reaction by Chiral Primary Amine Catalysis, J. Am. Chem. Soc, 2016, 通讯作者
(16) Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins, Org. Chem. Front., 2016, 通讯作者
(17) Carbocation Lewis Acid Catalyzed Redox-Neutral α-C(sp3)H Arylation of Amines, Acta Chim. Sinica.,, 2016, 通讯作者
(18) Asymmetric Latent Carbocation Catalysis with Chiral Trityl Phosphate, J. Am. Chem. Soc, 2015, 通讯作者
(19) Chiral Primary Amine/Palladium Dual Catalysis for AsymmetricAllylic Alkylation of b-Ketocarbonyl Compounds with Allylic Alcohols, Angew. Chem. Int. Ed, 2015, 通讯作者
(20) Catalytic Asymmetric Oxidative α-C−H N,O-Ketalization of Ketones by Chiral Primary Amine, Org. Lett, 2015, 通讯作者
(21) Organic Photocatalytic Cyclization of Polyenes: A Visible-Light-Mediated Radical Cascade Approach, Chem. Eur. J., 2015, 通讯作者
(22) Copper-Catalyzed Aerobic Autoxidation of N-Hydroxycarbamates Probed by Mass Spectrometry, Chem. Eur. J., 2015, 通讯作者
(23) Chiral Primary Amine Catalyzed Asymmetric Tandem Reduction–Michael Addition–Protonation Reaction between Alkylidene Meldrum’s Acid and α-Substituted Vinyl Ketones, Synthesis, 2015, 通讯作者
(24) Pushing the Limits of Aminocatalysis: Enantioselective Transformations of α-Branched β-Ketocarbonyls and Vinyl Ketones by Chiral Primary Amines, Acc. Chem. Res.,, 2015, 通讯作者
(25) Redox Tuning of a Direct Asymmetric Aldol Reaction, Angew. Chem. Int. Ed, 2015, 通讯作者
(26) [4 + 2] Cycloaddition of in Situ Generated 1,2-Diaza-1,3-dienes with Simple Olefins: Facile Approaches to Tetrahydropyridazines, Org. Lett, 2015, 通讯作者
(27) Bioinspired Organocatalytic Aerobic C−H Oxidation of Amines with an ortho-Quinone Catalyst, Org. Lett, 2015, 通讯作者
(28) Asymmetric α-Benzoyloxylation of β-Ketocarbonyls by a Chiral Primary Amine Catalyst, Org. Lett, 2015, 通讯作者
(29) Chiral Primary Amine Catalyzed Asymmetric Michael Addition of Malononitrile to α-Substituted Vinyl Ketone, Org. Lett, 2015, 通讯作者
(30) Primary-Tertiary Diamine/Brønsted Acid Catalyzed α-Allylation of Carbonyl Compounds with Allylic Alcohols, Chin. J. Chem., 2014, 通讯作者
(31) Asymmetric Enamine Catalysis with β-Ketoesters by Chiral Primary Amine: Divergent Stereocontrol Modes, J. Org. Chem., 2014, 通讯作者
(32) Visible-light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes, Chem. Eur. J., 2014, 通讯作者
(33) Origins of the Enantio- and N/O Selectivity in the Primary-Amine-Catalyzed Hydroxyamination of 1,3-Dicarbonyl Compounds with In-Situ-Formed Nitrosocarbonyl Compounds: A Theoretical Study, Chem. Asian J.,, 2014, 通讯作者
(34) Sc(OTf)3-Catalyzed Transfer Diazenylation of 1,3-Dicarbonyls with Triazenes via N−N Bond Cleavage), Org. Lett, 2014, 通讯作者
(35) Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters, J. Am. Chem. Soc., 2014, 通讯作者
(36) Direct Intramolecular Conjugate Addition of Simple Alkenes to α,β- Unsaturated Carbonyls Catalyzed by Cu(OTf)2, Org. Lett, 2014, 通讯作者
(37) Asymmetric Sulfa-Michael Addition to α-Substituted Vinyl Ketones Catalyzed by Chiral Primary Amine, Org. Lett, 2014, 通讯作者
(38) Counteranions of In(Ⅲ) Induced Reversal of Enantiocontrol in Friedel-Crafts Reaction of Indoles by Asymmetric Binary Acid Catalysis, Acta Chim. Sinica.,, 2014, 通讯作者
(39) Synergistic Pd/Enamine Catalysis: A Strategy for the C−H/C−H Oxidative Coupling of Allylarenes with Unactivated Ketones, Org. Lett, 2014, 通讯作者
(40) Chiral primary amine catalysed asymmetric conjugate addition of azoles to α-substituted vinyl ketones, Org. Chem. Front., 2014, 通讯作者
(41) Merging Aerobic Oxidation and Enamine Catalysis in the Asymmetric α-Amination of β-Ketocarbonyls Using N-Hydroxycarbamates as Nitrogen Sources, Angew. Chem. Int. Ed, 2014, 通讯作者
(42) Enantioselective Organocatalytic Conjugate Addition of Alkenes to α,β-Enones, Eur. J. Org. Chem.,, 2014, 通讯作者
(43) Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to α,β-Enones, Chem. Eur. J., 2014, 通讯作者
(44) Catalytic asymmetric α-C(sp3)–H functionalization of amines, Tetrahedron Lett., 2014, 通讯作者
(45) Catalytic Intermolecular Haloamidation of Simple Alkenes with N-Halophthalimide as Both Nitrogen and Halogen Source, Org. Lett, 2013, 通讯作者
(46) Chiral Primary-Amine-Catalyzed Conjugate Addition to α-Substituted Vinyl Ketones/Aldehydes: Divergent Stereocontrol Modes on Enamine Protonation, Chem. Eur. J., 2013, 通讯作者
(47) In(III)/PhCO2H Binary Acid Catalyzed Tandem [2 + 2] Cycloaddition and Nazarov Reaction between Alkynes and Acetals, Org. Lett, 2013, 通讯作者
(48) Switchable Diastereoselectivity in Enantioselective [4+2] Cycloadditions with Simple Olefins by Asymmetric Binary Acid Catalysis, Angew. Chem. Int. Ed, 2013, 通讯作者
(49) A Practical Protocol for Asymmetric Synthesis of Wieland-Miescher and Hajos-Parrish Ketones Catalyzed by a Simple Chiral Primary Amine, Synthesis, 2013, 通讯作者
(50) Primary–Tertiary Diamine/Brønsted Acid Catalyzed C–C Coupling between para-Vinylanilines and Aldehydes, Chem. Eur. J., 2013, 通讯作者
(51) Catalytic Nazarov Reaction of Aryl Vinyl Ketones via Binary Acid Strategy, J. Org. Chem., 2013, 通讯作者
(52) Asymmetric Binary Acid Catalysis: Chiral Phosphoric Acid as Dual Ligand and Acid, Chem. Commun., 2013, 通讯作者
(53) Theoretical Studies of the Asymmetric Binary-Acid-Catalyzed tert-Aminocyclization Reaction: Origins of the Csp3-H Activation and Stereoselectivity, Chem. Asian J.,, 2012, 通讯作者
(54) Asymmetric Binary-Acid Catalysis in the Inverse-Electron–Demanding Hetero-Diels-Alder Reaction of 3,4-Dihydro-2H -Pyran, Acta Chim. Sinica.,, 2012, 通讯作者
(55) Bio-inspired Chiral Primary Amine Catalysis, Synlett, 2012, 通讯作者
(56) Catalytic Enantioselective tert-Aminocyclization via Asymmetric Binary-acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer, Chem. Eur. J., 2012, 通讯作者
(57) Asymmetric Synthesis of Wieland-Miescher and Hajos-Parrish Ketones Catalyzed by an Amino Acid Derived Chiral Primary Amine, J. Org. Chem., 2012, 通讯作者
(58) Asymmetric Binary-acid Catalysis with InBr3 in Inverse-Electron-demanding Hetero Diels-Alder Reaction of Mono- and Bis-substituted Cyclopentadienes: Remote Fluoro Effect on Stereocontrol, Chem. Eur. J., 2012, 通讯作者
发表著作
"Supported Asymmetric Organocatalysis." in Green Techniques for Organic Synthesis and Medicinal Chemistry, John Wiley & Sons, Ltd., 2012-08, 第 3 作者

科研活动

   
科研项目
( 1 ) 仿生有机小分子催化C-H键反应研究, 主持, 国家级, 2014-01--2018-12
( 2 ) 新型手性伯胺催化剂的设计优化及其在不对称alpha-支链酮催化转化中的应用, 主持, 国家级, 2017-01--2020-12