基本信息
罗三中  男  博导  中国科学院化学研究所
电子邮件: luosz@iccas.ac.cn
通信地址: 北京海淀中关村北一街2号
邮政编码: 100190

研究领域

   

招生信息

   
招生专业
070303-有机化学
招生方向
仿生不对称催化,物理有机,超分子化学
有机光化学
有机电化学

教育背景

2004-03--2005-05   美国俄亥俄州立大学   访问学生
2002-09--2005-06   中国科学院化学研究所   理学博士
1999-09--2002-06   南开大学化学系   理学硕士
1995-09--1999-06   郑州大学化学系   理学学士
学历
   
学位
   

工作经历

   
工作简历
2011-06~现在, 中国科学院化学研究所, 研究员/课题组长
2007-10~2011-06,中国科学院化学研究所, 副研究员/课题组长
2005-07~2007-10,中国科学院化学研究所, 助理研究员
2004-03~2005-05,美国俄亥俄州立大学, 访问学生
2002-09~2005-06,中国科学院化学研究所, 理学博士
1999-09~2002-06,南开大学化学系, 理学硕士
1995-09~1999-06,郑州大学化学系, 理学学士
社会兼职
   

教授课程

有机化学II
有机化学I
现代有机合成艺术与挑战讲座

专利与奖励

   
奖励信息
(1) 物理有机青年奖, 其他, 2017
(2) Asian Core Program Lectureship, 其他, 2015
(3) 中国科学院青年创新促进会优秀会员, 院级, 2015
(4) 中国青年五四奖章, 国家级, 2014
(5) 启明星优秀人才, 院级, 2013
(6) 化学科学奖教金创新奖, 研究所(学校), 2013
(7) Thieme Journal Award, 其他, 2012
(8) 卢嘉锡青年人才奖, 院级, 2009
(9) 中国化学会青年化学奖, 国家级, 2008
专利成果
( 1 ) 一种手性α-氨基酸衍生物及其制备方法, 2017, 第 1 作者, 专利号: 201710579976.2
( 2 ) 一种手性β-氨基酸衍生物及其制备方法, 2017, 第 1 作者, 专利号: 201710579915.6
( 3 ) 合成手性二氢吡喃环类化合物的方法, 2017, 第 1 作者, 专利号: 201710361604.4

出版信息

   
发表论文
(1) Oxidative Synthesis of Benzimidazoles, Quinoxalines, and Benzoxazoles from Primary Amines by ortho-Quinone Catalysis, Org. Lett., 2017, 第 11 作者
(2) 催化不对称光诱导自由基反应, Acta Chim. Sinica., 2017, 第 11 作者
(3) Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis., J. Am. Chem. Soc., 2017, 第 11 作者
(4) Reagent-Controlled Enantioselectivity Switch in Asymmetric Fluorination of β-Ketocarbonyls by Chiral Primary Amine Catalysis., Chem. Sci., 2017, 第 11 作者
(5) Organocatalysis in Inert C–H Bond Functionalization, Chem. Rev., 2017, 第 11 作者
(6) Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Couplingof Tertiary Amines to Ketones by Synergistic Multiple Catalysis, Angew. Chem. Int. Ed., 2017, 第 11 作者
(7) Catalytic Asymmetric Electrochemical Oxidative Coupling of Tertiary Amines with Simple Ketones., Org. Lett., 2017, 第 11 作者
(8) Enantio- and Diastereoselective Cyclopropanation of β,γ-Unsaturated α-Ketoester by a Chiral Phosphate/Indium(III) Complex, Org. Lett., 2017, 第 11 作者
(9) Divergent Coupling of β,γ-Unsaturated α-Ketoesters with Simple Olefins: Vinylation and [2 + 2] Cycloaddition, Org. Lett., 2017, 第 11 作者
(10) Catalytic Regio- and Enantioselective [4+2] Annulation Reactions of Non-activated Allenes by a Chiral Cationic Indium Complex, Angew. Chem. Int. Ed., 2017, 第 11 作者
(11) Enantioselective Decarboxylative α-Alkynylation of β-Ketocarbonyls via a Catalytic α-Imino Radical Intermediate, Org. Lett., 2017, 第 11 作者
(12) Catalytic Asymmetric Mannich Reaction with N-Carbamoyl Imine Surrogates of Formaldehyde and Glyoxylate, Angew. Chem. Int. Ed., 2017, 第 11 作者
(13) Linear free-energy relationships in asymmetric catalysis, SCIENTIA SINICA Chimica, 2016, 第 11 作者
(14) Oxidative Radical Addition−Cyclization of Sulfonyl Hydrazones with Simple Olefins by Binary Acid Catalysis, Org. Lett, 2016, 第 11 作者
(15) Asymmetric Retro-Claisen Reaction by Chiral Primary Amine Catalysis, J. Am. Chem. Soc, 2016, 第 11 作者
(16) Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins, Org. Chem. Front., 2016, 第 11 作者
(17) Carbocation Lewis Acid Catalyzed Redox-Neutral α-C(sp3)H Arylation of Amines, Acta Chim. Sinica.,, 2016, 第 11 作者
(18) Asymmetric Latent Carbocation Catalysis with Chiral Trityl Phosphate, J. Am. Chem. Soc, 2015, 第 11 作者
(19) Chiral Primary Amine/Palladium Dual Catalysis for AsymmetricAllylic Alkylation of b-Ketocarbonyl Compounds with Allylic Alcohols, Angew. Chem. Int. Ed, 2015, 第 11 作者
(20) Catalytic Asymmetric Oxidative α-C−H N,O-Ketalization of Ketones by Chiral Primary Amine, Org. Lett, 2015, 第 11 作者
(21) Organic Photocatalytic Cyclization of Polyenes: A Visible-Light-Mediated Radical Cascade Approach, Chem. Eur. J., 2015, 第 11 作者
(22) Copper-Catalyzed Aerobic Autoxidation of N-Hydroxycarbamates Probed by Mass Spectrometry, Chem. Eur. J., 2015, 第 11 作者
(23) Chiral Primary Amine Catalyzed Asymmetric Tandem Reduction–Michael Addition–Protonation Reaction between Alkylidene Meldrum’s Acid and α-Substituted Vinyl Ketones, Synthesis, 2015, 第 11 作者
(24) Pushing the Limits of Aminocatalysis: Enantioselective Transformations of α-Branched β-Ketocarbonyls and Vinyl Ketones by Chiral Primary Amines, Acc. Chem. Res.,, 2015, 第 11 作者
(25) Redox Tuning of a Direct Asymmetric Aldol Reaction, Angew. Chem. Int. Ed, 2015, 第 11 作者
(26) [4 + 2] Cycloaddition of in Situ Generated 1,2-Diaza-1,3-dienes with Simple Olefins: Facile Approaches to Tetrahydropyridazines, Org. Lett, 2015, 第 11 作者
(27) Bioinspired Organocatalytic Aerobic C−H Oxidation of Amines with an ortho-Quinone Catalyst, Org. Lett, 2015, 第 11 作者
(28) Asymmetric α-Benzoyloxylation of β-Ketocarbonyls by a Chiral Primary Amine Catalyst, Org. Lett, 2015, 第 11 作者
(29) Chiral Primary Amine Catalyzed Asymmetric Michael Addition of Malononitrile to α-Substituted Vinyl Ketone, Org. Lett, 2015, 第 11 作者
(30) Primary-Tertiary Diamine/Brønsted Acid Catalyzed α-Allylation of Carbonyl Compounds with Allylic Alcohols, Chin. J. Chem., 2014, 第 11 作者
(31) Asymmetric Enamine Catalysis with β-Ketoesters by Chiral Primary Amine: Divergent Stereocontrol Modes, J. Org. Chem., 2014, 第 11 作者
(32) Visible-light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes, Chem. Eur. J., 2014, 第 11 作者
(33) Origins of the Enantio- and N/O Selectivity in the Primary-Amine-Catalyzed Hydroxyamination of 1,3-Dicarbonyl Compounds with In-Situ-Formed Nitrosocarbonyl Compounds: A Theoretical Study, Chem. Asian J.,, 2014, 第 11 作者
(34) Sc(OTf)3-Catalyzed Transfer Diazenylation of 1,3-Dicarbonyls with Triazenes via N−N Bond Cleavage), Org. Lett, 2014, 第 11 作者
(35) Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters, J. Am. Chem. Soc., 2014, 第 11 作者
(36) Direct Intramolecular Conjugate Addition of Simple Alkenes to α,β- Unsaturated Carbonyls Catalyzed by Cu(OTf)2, Org. Lett, 2014, 第 11 作者
(37) Asymmetric Sulfa-Michael Addition to α-Substituted Vinyl Ketones Catalyzed by Chiral Primary Amine, Org. Lett, 2014, 第 11 作者
(38) Counteranions of In(Ⅲ) Induced Reversal of Enantiocontrol in Friedel-Crafts Reaction of Indoles by Asymmetric Binary Acid Catalysis, Acta Chim. Sinica.,, 2014, 第 11 作者
(39) Synergistic Pd/Enamine Catalysis: A Strategy for the C−H/C−H Oxidative Coupling of Allylarenes with Unactivated Ketones, Org. Lett, 2014, 第 11 作者
(40) Chiral primary amine catalysed asymmetric conjugate addition of azoles to α-substituted vinyl ketones, Org. Chem. Front., 2014, 第 11 作者
(41) Merging Aerobic Oxidation and Enamine Catalysis in the Asymmetric α-Amination of β-Ketocarbonyls Using N-Hydroxycarbamates as Nitrogen Sources, Angew. Chem. Int. Ed, 2014, 第 11 作者
(42) Enantioselective Organocatalytic Conjugate Addition of Alkenes to α,β-Enones, Eur. J. Org. Chem.,, 2014, 第 11 作者
(43) Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to α,β-Enones, Chem. Eur. J., 2014, 第 11 作者
(44) Catalytic asymmetric α-C(sp3)–H functionalization of amines, Tetrahedron Lett., 2014, 第 11 作者
(45) Catalytic Intermolecular Haloamidation of Simple Alkenes with N-Halophthalimide as Both Nitrogen and Halogen Source, Org. Lett, 2013, 第 11 作者
(46) Chiral Primary-Amine-Catalyzed Conjugate Addition to α-Substituted Vinyl Ketones/Aldehydes: Divergent Stereocontrol Modes on Enamine Protonation, Chem. Eur. J., 2013, 第 11 作者
(47) In(III)/PhCO2H Binary Acid Catalyzed Tandem [2 + 2] Cycloaddition and Nazarov Reaction between Alkynes and Acetals, Org. Lett, 2013, 第 11 作者
(48) Switchable Diastereoselectivity in Enantioselective [4+2] Cycloadditions with Simple Olefins by Asymmetric Binary Acid Catalysis, Angew. Chem. Int. Ed, 2013, 第 11 作者
(49) A Practical Protocol for Asymmetric Synthesis of Wieland-Miescher and Hajos-Parrish Ketones Catalyzed by a Simple Chiral Primary Amine, Synthesis, 2013, 第 11 作者
(50) Primary–Tertiary Diamine/Brønsted Acid Catalyzed C–C Coupling between para-Vinylanilines and Aldehydes, Chem. Eur. J., 2013, 第 11 作者
(51) Catalytic Nazarov Reaction of Aryl Vinyl Ketones via Binary Acid Strategy, J. Org. Chem., 2013, 第 11 作者
(52) Asymmetric Binary Acid Catalysis: Chiral Phosphoric Acid as Dual Ligand and Acid, Chem. Commun., 2013, 第 11 作者
(53) Theoretical Studies of the Asymmetric Binary-Acid-Catalyzed tert-Aminocyclization Reaction: Origins of the Csp3-H Activation and Stereoselectivity, Chem. Asian J.,, 2012, 第 11 作者
(54) Asymmetric Binary-Acid Catalysis in the Inverse-Electron–Demanding Hetero-Diels-Alder Reaction of 3,4-Dihydro-2H -Pyran, Acta Chim. Sinica.,, 2012, 第 11 作者
(55) Bio-inspired Chiral Primary Amine Catalysis, Synlett, 2012, 第 11 作者
(56) Catalytic Enantioselective tert-Aminocyclization via Asymmetric Binary-acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer, Chem. Eur. J., 2012, 第 11 作者
(57) Asymmetric Synthesis of Wieland-Miescher and Hajos-Parrish Ketones Catalyzed by an Amino Acid Derived Chiral Primary Amine, J. Org. Chem., 2012, 第 11 作者
(58) Asymmetric Binary-acid Catalysis with InBr3 in Inverse-Electron-demanding Hetero Diels-Alder Reaction of Mono- and Bis-substituted Cyclopentadienes: Remote Fluoro Effect on Stereocontrol, Chem. Eur. J., 2012, 第 11 作者
发表著作
"Supported Asymmetric Organocatalysis." in Green Techniques for Organic Synthesis and Medicinal Chemistry, John Wiley & Sons, Ltd., 2012-08, 第 3 作者

科研活动

   
科研项目
( 1 ) 仿生有机小分子催化C-H键反应研究, 主持, 国家级, 2014-01--2018-12
( 2 ) 新型手性伯胺催化剂的设计优化及其在不对称alpha-支链酮催化转化中的应用, 主持, 国家级, 2017-01--2020-12
参与会议
   

合作情况

   
项目协作单位
   

指导学生