基本信息
高连勋  男  博导  中国科学院长春应用化学研究所
电子邮件: lxgao@ciac.ac.cn
通信地址: 长春市人民大街5625号
邮政编码: 130022

研究领域

聚酰亚胺合成与材料,手性超分子化学
有机合成化学,包括不对称催化,合成方法学与药物中间体合成

招生信息

   
招生专业
070303-有机化学
070305-高分子化学与物理
招生方向
有机方法学,不对称合成
聚酰亚胺材料
超分子化学

教育背景

   
学历

1979-1982  吉林大学化学系 本科
1987-1992  日本北海道大学理学研究科 研究生
 

学位
学士学位:1982年,吉林大学化学系
硕士学位:1989年,日本北海道大学理学部
博士学位:1992年,日本北海道大学理学部

工作经历

   
工作简历
   

专利与奖励

   
专利成果
(1) 聚酰亚胺基体树脂溶液的制备方法,发明,专利号:CN00128254.9
(2) 氯代苯酐及氯代邻苯二甲酸粗产物的精馏前处理方法 ,发明,专利号:CN01110204.7
(3) 聚酰亚胺水解回收方法,发明,专利号:CN01129547.3
(4) 4-苯乙炔苯酐的制备方法,发明,专利号:CN200310115829.8
(5) 由双氯酞酰亚胺与双酚制备聚醚酰亚胺的方法,发明,专利号:CN200410010703.9
(6) 双酚二盐的制备方法,发明,专利号:CN20041001900.0
(7) 磺化聚酰亚胺质子传输膜的合成方法,发明,专利号:CN200410011205.6
(8) 双氯酞酰亚胺与二氯二苯酮或二氯二苯砜共聚物的制备方法,发明,专利号:CN02104269.1
(9) 联苯型聚酰亚胺的制备方法,发明,专利号:CN02123897.9
(10) 电化学制备联苯四甲酸二酐及其衍生物,发明,专利号:CN02148860.6
(11) 2,3,3,4-联苯四酸二酐及其衍生物的制备方法,发明,专利号:CN03105026.3
(12) 聚酰亚胺纤维及制备方法,发明,2011,第3作者,专利号:201010572496.1
(13) 一种聚酰亚胺纤维及制备方法,发明,2010,第3作者,专利号:201010572240.0
(14) 一种聚酰亚胺纤维及制备方法,发明,2010,第3作者,专利号:201010572262.7

出版信息

(1) Hexagonla lyotropic liquid crystal from simple “abiotic” foldamers, ChemistryOpen, 2016, 第9作者
(2) Effect of multiple H-Bonding on the properties of polyimides containing the rigid rod groups, J.Polym. Sci. A Polym. Chem., 2016, 通迅作者
(3) Preparation and properties of nanocomposites based on polyimide and polyfluorinated surfactant-pillared layered double hydroxide, Chem. J. Chin. Univ., 2016, 通迅作者.
(4) Ni-catalyzed cross coupling of aryl Grignard reagents with aryl halides in a nonpolar solvent and an efficient synthesis of biaryls under neat conditions, Chem. Res. Chin. Univ., 2016, 通迅作者
(5) Cu-Catalyzed Aryl C-H Halogenation Using N-Halosuccinimides via Assistance of Benzoic Acid, Chem. Res. Chin. Univ., 2015, 第2作者
(6) In situ iodoalkane-reduction of graphene oxide in a polymer matrix: an easy and effective approach for the fabrication of conductive composites, J. Mater. Chem. C, 2015, 通迅作者
(7) A porous metal-organic framework formed by a V-shaped ligand and Zn(II) ion with highly selective sensing for nitroaromatic explosives, J. Mater. Chem. A, 2015, 第5作者
(8) A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4, Chem. Commun., 2015, 第7作者
(9) Synthesis and adhesion properties of polyimdies containing diphenylpyrimidine, Acta Polym. Sinica, 2015, 通迅作者
(10) Preparation and properties of imidazole-containing polyimide/silica hybrid films, Chem. Res. Chin. Univ., 2014, 通迅作者
(11) Supramolecular hydrogels derived from cyclic amino acids and their applications in the synthesis of Pt and Ir nanocrystals, Chem. Commun., 2014, 通迅作者
(12)The adsorption and simulated separation of light hydrocarbons in isoreticular metal-organic frameworks based on dendritic ligands with different aliphatic side chains, Chem. Eur. J., 2014, 第6作者
(13) Effect of draw ratio on the morphologies and properties of BPDA/PMDA/ODA polyimide fibers, C hem. Res. Chin. Univ., 2014,
(14) The crystallographic observation of mesitylene-mesitylene and mesitylene-CH2Cl2-mesitylene adducts trapped in an irregular cavity, CrystEngComm, 2014, 第10作者
(15) 含磷聚酰亚胺纤维的制备及其力学与阻燃性能, 应用化学, 通迅作者
(16) Dehydrogenation and dehalogenation of amines in MALDI-TOF MS investigated by isotopic labeling, J. Mass Spectro. , 2013, 通迅作者
(17) ZIF-8 crystal coatings on a polyimide substrate and their catalytic behaviours for the Knoevenagel reaction, Dalton Trans., 2013, 通迅作者
(18) Preparations and Properties of the Phosphorus-containing Polyimide Fibers, Chem. J. Chin. Univ., 2013, 通迅作者
(19) In Situ Gel-to-Crystal Transition and Synthesis of Metal Nanoparticles Obtained by Fluorination of a Cyclic beta-Aminoalcohol Gelator, Chem. Eur. J., 2012, 通迅作者
(20) Donor-Induced Helical Inversion of 1,1 '-Binaphthyl Connecting with Two Molybdenum Complexes, Chem. Eur. J., 2012, 通迅作者

(21)  Efficient synthesis of 2,5-disubstituted tetrazoles via the Cu2O-catalyzed aerobic oxidative direct cross-coupling of N-H free tetrazoles with boronic acids , Chem. Commun., 2012, 第 2 作者
(22)  Preparation and properties of ionic cross-linked sulfonated copolyimide membranes containing pyrimidine groups , Polym. Adv. Technol., 2012, 通讯作者
(23)  An organogel formed from a cyclic beta-aminoalcohol, Chem. Commun., 2011, 通讯作者
(24) Self-discriminating and hierarchical assembly of racemic binaphthyl-bisbipyridines and silver ions: from metallocycles to gel nanofibers, Chem. Commun., 2011, 通讯作者
(25)  PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions , Chem. Commun., 2011, 第 2 作者
(26) Nickel-Catalyzed Cross-Coupling of Phenols and Arylboronic Acids Through an In Situ Phenol Activation Mediated by PyBroP , Chem. Eur. J., 2011, 第 3 作者
(27) Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex , Chem. Res. Chin. Univ., 2011, 通讯作者
(28) Novel C3-symmetrical triphenylbenzene-based organogelators with different linkers between phenyl ring and alkyl chain, Tetrahedron, 2010, 通讯作者
(29) Chiral binaphthylbisbipyridine-based copper(I) coordination polymer gels as supramolecular catalysts, Chem. Commun., 2010, 通讯作者
(30) Stereoselective and hierarchical self-assembly from nanotubular homochiral helical coordination polymers to supramolecular gels, Chem. Commun., 2010, 通讯作者
(31) Crystal Structure and Solution Behavior of a Novel Enantiopure Helical Coordination Polymer Based on Binaphthyl-bisbipyridine Ligand , Chem. Res. Chin. Univ., 2010, 通讯作者
(32)  Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3, Chem. Eur. J., 2010, 第 2 作者
(33) Aryl Phosphoramides: Useful Electrophiles for Suzuki-Miyaura Coupling Catalyzed by a NiCl2/dppp System (dppp=1,3-Bis(diphenylphosphino)propane) , Chem. Eur. J., 2010, 第 4 作者
(34) Asymmetric Michael addition of aldehydes to nitroolefins catalyzed by L-prolinamide derivatives using phenols as co-catalysts, Tetrahedron: Asymmetry , 2009, 通讯作者
(35) Ultrasound-promoted chiral fluorescent organogel, New Journal of Chemistry, 2009, 通讯作者
(36) Enantioselective Iodolactonizations of 4-Pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex, Synlett , 2009, 通讯作者
(37) Novel Sulfonated Polyimide Ionomers by Incorporating Pyridine Functional Group in the Polymer Backbone , J. Appl. Polym. Sci., 2009, 通讯作者
(38) Highly efficient and recoverable dendritic organocatalyst from click chemistry for the asymmetric michael addition of ketones to nitroolefins without the use of organic solvent, Tetrahedron-Asymmetry, 2008, 通讯作者
(39) Palladium within ionic liquid functionalized mesoporous silica SBA-15 and its catalytic application in room-temperature Suzuki coupling reaction, J. Mol. Cata. A Chem., 2008, 通讯作者
(40) Immobilization of dipyridyl complex to magnetic nanoparticle via click chemistry as a recyclable catalyst for Suzuki cross-coupling reactions, Synlett, 2008, 通讯作者
(41) Chiral ligand 2-(2-piperidinyl)pyridine: synthesis, resolution and application, Tetrahedron: Asymmetry, 2008, 通讯作者
(42) Monooxychlorophosphine as a novel and efficient ligand for palladium-catalyzed suzuki-miyaura cross-coupling of aryl chlorides, Synlett, 2007, 通讯作者
(43) Studies on syntheses and properties of novel CeO2/Polyimide nanocomposite films from Ce(Phen)(3) complex, Polymer, 2007, 通讯作者
(44) One-step synthesis of palladium/SBA-15 nanocomposites and its catalytic application, J. Mol. Cata. A Chem.,  2007, 通讯作者
(45) Synthesis and properties of novel sulfonated polyimides containing binaphthyl groups as proton-exchange membranes for fuel cells , J.Polym. Sci. A Polym. Chem., 2007, 通讯作者
(46)  Synthesis and applications of 3-[6-(hydroxymethyl)pyridin-2-yl]-1,1 -bi-2-naphthols or 3,3 -bis[6-(hydroxymethyl)pyridin-2-yl]-1,1 -bi-2-naphthols, Synthesis Stuttgart, 2007, 通讯作者
(47) PEG-supported dipyridyl ligand for palladium-catalyzed Suzuki and Suzuki-type reactions in PEG and aqueous media, Synlett, 2006, 通讯作者
(48) Preparation and properties of ternary polyimide/SiO2/polydiphenyisiloxane composite films,Polym. Inter., 2006, 通讯作者
(49) Polyimides derived from 3,3 -bis(N-aminophthalimide), Macromolecules , 2006, 第 3 作者
(50) The natural alkaloid isoanabasine: synthesis from 2,3-bipyridine, efficient resolution with BINOL, and assignment of absolute configuration by Moshers method, Tetrahedron-Asymmetry, 2005, 通讯作者
(51) TEMPO-derived task-specific ionic liquids for oxidation of alcohols, Synlett, 2005, 通讯作者
(52) Synthesis of new bis-BINOLs linked by a 2,2 -bipyridine bridge, Synthesis-Stuttgart, 2005, 通讯作者
(53) Syntheses and properties of soluble biphenyl-based polyimides from asymmetric bis(chlorophthalimide)s , Macromolecules, 2004, 通讯作者
(54) Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1-binaphthyls, J.Polym. Sci. A Polym. Chem., 2004, 通讯作者
(55) Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine, J. Org. Chem., 2004, 通讯作者
(56) Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis(chlorophthalimide)s, Macromolecules , 2003, 第 3 作者
(57) Synthesis and properties of polyquinolines and polyanthrazolines containing pyrrole units in the main chain, Macromolecules, 2003, 通讯作者

(58) Aromatic poly(ester imide)s and poly(amide imide)s having 1,1-binaphthyl-2,2-diyls in the main chain, Macro. Chem. Phys., 2000, 通讯作者

 

合作情况

   
项目协作单位
   

指导学生

已指导学生

王芒  博士研究生  070303-有机化学  

夏爱香  博士研究生  070303-有机化学  

宋乃恒  博士研究生  070303-有机化学  

李继贞  博士研究生  070303-有机化学  

买文鹏  博士研究生  070303-有机化学  

刘芳  博士研究生  070303-有机化学  

侯士法  博士研究生  070303-有机化学  

尚振平  博士研究生  070303-有机化学  

金日哲  博士研究生  070303-有机化学  

马丽  博士研究生  070303-有机化学  

赵剑英   博士研究生  070303-有机化学  

卞证  博士研究生  070303-有机化学  

韩福社  博士研究生  070303-有机化学  

高照波  博士研究生  070303-有机化学  

姜劲越  博士研究生  070303-有机化学  

韩鹏  博士研究生  070303-有机化学  

袁修华   博士研究生  070303-有机化学  

吴雪娥   博士研究生  070303-有机化学  

王晓梅  博士研究生  070303-有机化学  

高昌录  博士研究生  070303-有机化学  

白晓莉  博士研究生  070303-有机化学  

刘旭东  博士研究生  070303-有机化学  

张敏杰  博士研究生  070303-有机化学  

吕光华  博士研究生  070303-有机化学  

宁兆伦  博士研究生  070303-有机化学  

王喜  硕士研究生  070303-有机化学  

李玉邯  博士研究生  070303-有机化学  

何亚兵  博士研究生  070303-有机化学  

成燕琴  博士研究生  070303-有机化学  

雷瑞  博士研究生  070303-有机化学  

现指导学生

康传清  博士研究生  070303-有机化学  

文金花  硕士研究生  070303-有机化学  

黄森彪  博士研究生  070303-有机化学  

丁祥  博士研究生  070303-有机化学  

李乐乐  硕士研究生  070303-有机化学  

李钰  博士研究生  070303-有机化学  

戚福玲  博士研究生  070303-有机化学  

王兰兰  硕士研究生  070303-有机化学  

陈宇  硕士研究生  070303-有机化学  

余海  博士研究生  070303-有机化学