基本信息
徐立  男  博导  中国科学院福建物质结构研究所
电子邮件: xli@fjirsm.ac.cn
通信地址: 福州市鼓楼区杨桥西路155号
邮政编码: 350002

招生信息

   
招生专业
070301-无机化学
070303-有机化学
070304-物理化学
招生方向
团簇的分子与晶体工程
新型有机化合物的设计及其金属功能材料的构筑
Zintl化学

教育背景

1990-01--1993-02   中科院福建物质结构研究所   博士学位

工作经历

   
工作简历
2003-06~现在, 中科院福建物质结构研究所, 研究员
2002-05~2003-06,加拿大ALBERTA大学, 博士后
2000-12~2002-05,美国RICE大学, 研究科学家
1998-12~2000-12,美国NOTRE DAME大学, 博士后
1997-07~1998-12,日本北海道大学理学院, 日本学术振兴会外国人特别研究员
1994-04~1997-07,福建物质结构研究所, 副研究员
1993-02~1994-04,中科院福建物质结构研究所, 助理研究员
1990-01~1993-02,中科院福建物质结构研究所, 博士学位

出版信息

   
发表论文
(1) MoIV3•••[O8Mo4]3 Lewis acid-base cluster pairs: Highly efficient and stable Lewis catalysis fields frustrated in crystalline nanoclusters, Nanoscale, 2020, 通讯作者
(2) Aggregation of polybismuthide anions in a single compound using +Rh-CO units: Heterometallic cluster ions [Rh@Bi10(RhCO)6]3- and [Rh@Bi9(RhCO)5]3-, Inorg. Chem., 2020, 通讯作者
(3) Highly efficient MoIV3•••SbIII cluster frustrated Lewis pair hydrogenation, Dalton Transaction, 2019, 通讯作者
(4) [(η3-Bi3)2(IrCO)6(μ4-Bi)3]3- : a new archetype of 15-vertex deltahedral hybrid from Bixx--coordination aggregation of cationic [IrCO]+ units, Dalton Transaction, 2019, 通讯作者
(5) [Bi7M3(CO)3]2- (M = Co, Rh): A New Architype of 10-vertex Deltahedral Hybrids From Unprecedented Polycyclic η5−coordination addition of Bi73- and trimetallic fragments, Chem. Commun., 2019, 通讯作者
(6) POM-FLPs: [MoIV3]n-Polyoxometalate Bifunctional Catalysis by [MoIV3]n-Om Lewis Pairs Frustrated by Triangular MoIV-MoIV bonds, Dalton Transaction, 2019, 通讯作者
(7) Mo3IV-Polyoxomolybdates with Frustrated Lewis Pairs For High-Performance Hydrogenation Catalysis, Catalysis Science & Technology, 2019, 通讯作者
(8) Unprecedented Nanocage-like and Heterometallic [Mo3O4]-Polyoxomolybdate Hybrid, Dalton Transaction, 2018, 通讯作者
(9) Sb102− and Sb22− found in [K(18-crown-6)]6[Sb10] [Sb4{Mo(CO)3}2]•2en: two missing family members, Dalton Transaction, 2017, 通讯作者
(10) [Ge9{M(CO)5}3]4−: electrophilic addition of M(CO)5 and [E9]4− Zintl anions (M = Cr, Mo, W), Dalton Transaction, 2017, 通讯作者
(11) Counterion-induced Crystallization of Intermetalloid Matryoshka Clusters [Sb@Pd12@Sb20]3-,4-, Dalton Transaction, 2017, 通讯作者
(12) [A3X][Ga3PS8] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds, Chemical Science, 2016, 通讯作者
(13) [A3X][Ga3PS8] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds, Chemical Science, 2016, 通讯作者
(14) An All-Metal Aromatic Sandwich Complex [Sb3Au3Sb3]3−, J. Am. Chem . Soc, 2015, 其他(合作组作者)
(15) Isolated [Cd2Sb5]11- Butterfly Zintl Anion Built of Unprecedented Planar [CdSb3] Triangle, Dalton Transaction, 2015, 通讯作者
(16)  [Ge8(Mo(CO)3)2]4?:Unprecedented 20?Electron Empty Ten?vertex Zintl Cluster, ChemCommun, 2014, 通讯作者
(17) Unprecedented [MoIV3O4]-incorporated Polyoxometalate Concomitant with MoO2, ChemCommun, 2013, 通讯作者
(18) Unprecedented 3-D SHG MOF Material of Silver (I) Induced by Chiral Triple R-helices, ChemCommun, 2013, 通讯作者
(19) Unprecedented Dawson Isomerism Induced by Central [WO5] and Four 45?-rotated Belt , ChemCommun, 2012, 通讯作者
(20) Countercation-directed chiral resolution of [Mo2O4(H2dtpa)]-, syntheses, crystal structures and CD spectra of (λ)-[NEt4][Mo2O4(H2dtpa)] and (δ)-Na[Mo2O4(H2dtpa)], CrystEngCommun, 2012, 通讯作者
(21) Solvothermal Treatment of Triangular Molybdenum (IV) Oxo Species, A Novel Approach for the Synthesis of New Molybdenum Oxo Clusters, Eur. J. Inorg. Chem, 2011, 通讯作者
(22) Synthesis and Crystal of [K(2,2,2-crypt)]3Sb11 , Chinese J. Struc. Chem., 2011, 通讯作者
(23) Synthesis and Crystal Structure of a New mixed-ligands Iron Complex with Cylic Water Hexamers [Fe(HCDTA).H2O].Fe(1,10-phen)3.10H2O.2OH-, Chinese J. Struc. Chem., 2011, 通讯作者
(24) Bis[(1,10-diaza-4,7,13,16,21,24-hexaoxabicyclo[8.8.8] hexacosane)potassium(+)], Acta. Cryst. Sect C. , 2011, 通讯作者
(25) Construction of a series of 1D and 2D inorganic-organic hybrid coordination polymers based on 1, 1’-di(propionic acid)-2, 2’-biimidazole, Eur. J. Inorg. Chem , 2010, 通讯作者
(26) Helix-based Supramolecular Isomerism of Metal-organic Framework, CrystEngComm, 2010, 通讯作者
(27) Reversible formation of Regular Pentagonal Dodecahedral (H2O)20 in a 2D Metal-Organic Framework, CrystEngComm , 2010, 通讯作者
(28) Lanthanide (III) addition of [Mo2O3S(HNTA)2]2- (Ln = Eu, Dy), J. Solid State Chem., 2009, 通讯作者
(29) Supramolecular architectures built of triangular molybdenum(IV) heterometallic clusters encapsulating novel water clusters, Inorg. Chim. Acta, 2009, 通讯作者
(30)  pH-Dependent Displacement of [Bi(citrate)]- with Cysteine: Synthesis, Spectroscopic and X-ray Crystallographic Characterization of Bi(cysteine)3., J. Inorg. Biochem., 2008, 通讯作者
(31) Syntheses and optical property of two novel chlorobithmuthate(III) complexes:[8-hydroxyquinnolinium]4-K2[BiCl6]2 and [8-hydroxyquinnolinium]6-[Bi2Cl10][Bi(H2O)Cl5], J. Mol. Struc., 2008, 通讯作者
(32) Unprecedented 2-D Hydrated Proton Encapsulated in Supramolecular Framework Built of [Mo3O4(C2O4)(H2O)3]2-, Inorg. Chem. Comm., 2008, 通讯作者
(33) Two Novel Luminescent Silver(I) Coordination Polymers Containing Octanuclear Silver Cluster Units or Ligand unsupported Ag???Ag Interactions Constructed from 5-sulfoisophic acid (H3SIP) and Organic Amine, CrystEngComm. , 2008, 通讯作者
(34) Unprecedented Helix-based Microporous Metal-Organic Frameworks Constructed from Single Ligand, Chem. Commun., 2008, 通讯作者
(35) Syntheses, Structures and Photoluminescence of Two 3D- pillared Metal-organic Framework with unique (411?64)(410?65) topology based on two kinds of topologically nonequivalent nodes, Inorg. Chem. Comm., 2008, 通讯作者
(36) Remarkable Structural Transformation of [Zn(tza)2] During recrystallization, Syntheses and Crystal Structures of [M(tza)2] (M = Zn, Cd, Mn, Co; Htza = Tetrazole-1-acetic Acid ), Crystal Growth and Design, 2008, 通讯作者
(37) Syntheses, crystal structure and properties of two novel coordinationpolymers with the flexible tetrazole-1-acetic acid (Htza), J. Solid. Chem. Chem., 2008, 通讯作者
(38) Protonated N-Heterocycle-templated Supramolecular Frameworks Built of Triangular Molybdenum(IV) Clusters., Inorg. Chim. Acta, 2008, 通讯作者
(39) Syntheses,Crystal Structures, and Magnetic Properties of Copper(II) and Manganese(II) Compounds Constructed from 5-Sulfoisophthalic Acid (H3SIP) and 2,2’-Bipydine(bpy) Ligands., Eur. J. Inorg. Chem., 2008, 通讯作者
(40) Diversity of Coordination Architecture of Copper(II)-5-Sulfoisophthalic Acid: Synthesis, Crystal Structures and Characterizations., Cryst Growth and Design, 2007, 通讯作者
(41) Layered Lanthanide Molybdate Pillared by Chiral [l-Mo2O4EDTA]2-, Inorg. Chem., 2006, 通讯作者
(42)  Syntheses, crystal structures and properties of [K(2,2,2-crypt)]3K(HP7)2.en, [K(18-crown-6)]2HP7 and [K(db18-crown-6)]2HP7.toluene, Inorg. Chim. Acta , 2006, 通讯作者
(43) Counter-anion Induced Formation of cis and trans Singly and Doubly H2biim-bridged Di-, Hexa- and Polymeric Ag-H2biim Complexes., Eur. J. Inorg. Chem., 2006, 通讯作者
(44) Syntheses, Crystal Structrues and Photophysical Properties of Two Novel Lead(II)-SIP (NaH2SIP = 5-Sulfoisophthalic Acid Monosodium Salt) Coordination Polymers Containing Tetranuclear Lead(II) Units, Eur. J. Inorg. Chem., 2006, 通讯作者
(45) Synthesis, Crystal Structures and Photoluminescent Properties of Three Novel Cadmium(II) Compounds Constructed from 5-Sulfoisophthalic Acid (H3SIP), Eur. J. Inorg. Chem., 2006, 通讯作者
(46) Supramolecular Architecture Built of Biimidazole Complexes and Sulfate or Nitrate Anions, Polyhedron, 2006, 通讯作者
(47) The First Lanthanide(III)-Iminodiacetate Coordination Polymer, Inorg. Chem. Comm., 2006, 通讯作者
(48) Supramolecular Architectures of Cadmium(II) Built of 2,2-Bimmidazole and Bifunctional Carboxylates: Syntheses, Crystal Structure and Properties, Inorg. Chim. Acta, 2006, 通讯作者
(49) Unprecedented Quadruple-Me2biim Bridged Di- and Tetra-nuclear Complexes, Syntheses, Crystal Structures and Magnetic Properties, Inorg. Chim. Acta, 2006, 通讯作者
(50) Novel Structure Evolution From 1D Chain to 3D Network of Lanthanide-SIP Coordination Polymers as a Consequence of Lanthanide Contraction Effect, Euro. J. Inorg. Chem., 2005, 通讯作者
(51) A Series of Single, Double, and Triple Me2biim-Bridged Dinuclear, Trinuclear, and Polymeric Complexes: Syntheses, Crystal Structures, and Luminescent Properties, Inorg. Chem.,, 2005, 通讯作者
(52) Synthesis, Crystal Structures and Photophysical Properties of Two Supramolecular Complexes of Cd(II), Inorg. Chem. Comm., 2005, 通讯作者
(53) (H2O)12-Containing Infinite Chains Encapsulated in Supramolecular Open Framework Structures ,  CrystEngComm, 2005, 通讯作者
(54) Hybrid Metal Carbonyl-Oxo Clusters, Synthesis and Characterization of, organometallics, 2002, 第 1 作者
(55)  Stablization of Ozone-like [Bi3]3- in the Heteroatomic closo-Clusters [Bi3Cr2(CO)6]3- and , J. Am. Chem. Soc., 2001, 第 1 作者
(56) Heteroatomic Deltahedral Clusters of Main Group Elements, Syntheses and Structures of , Inorg. Chem, 2000, 第 1 作者
(57) A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a Short Bi-Bi Bond: Synthesis and , J. Am. Chem. Soc., 2000, 第 1 作者
(58) Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions, J. Am. Chem. Soc., 1999, 第 1 作者

科研活动

   
科研项目
( 1 ) ZINTL团簇的合成,结构与反应性, 主持, 国家级, 2011-01--2013-12
( 2 ) 新型半导体团簇的制备及结构性质研究, 主持, 国家级, 2011-01--2014-12
( 3 ) 功能导向多孔配合物晶体工程, 参与, 国家级, 2010-01--2013-12
( 4 ) Zintl团簇化学:合成,结构与反应性, 主持, 国家级, 2015-01--2018-12
( 5 ) Zintl杂化团簇-合成、结构与反应性, 主持, 国家级, 2019-01--2022-12