基本信息
杨维慎  男  博导  中国科学院大连化学物理研究所
电子邮件: yangws@dicp.ac.cn
通信地址: 大连市中山路457号
邮政编码: 116023

研究领域

主要研究方向:催化新材料及催化新反应;膜分离材料及膜催化反应 

        反应和分离是化学工业的两大基本过程,将这两个过程集成一体是一项极具挑战的课题。膜催化是将膜材料的分离过程和催化材料的催化反应过程耦合在膜反应器中,即在反应的同时将反应物或产物进行分离,提高催化反应选择性或转化率,从而实现反应/分离一体化。研究涉及材料化学、催化化学以及化学化工等学科的交叉,其关键是高性能无机膜材料的优化设计与合成。研究包括,

      催化新材料及催化新反应: 催化材料主要包括亚纳米孔和纳米孔催化材料,复合氧化物材料以及负载型金属催化材料等;催化反应重点研究低碳烷烃催化转化反应,如烷烃催化脱氢以及催化选择氧化。无机膜材料:分子筛膜材料;氧分离膜材料;氢分离膜材料。主要探讨无机膜宏观分离性能与其微观结构的内在关联;研究无机膜制备过程中体系的物理化学变化规律对其微观结构的影响;发展具有自我知识产权的无机膜催化材料合成策略和制备方法。无机膜催化过程:揭示催化反应与膜分离耦合的新过程中膜分离材料和催化剂材料间相互作用以及膜分离过程和催化反应过程间相互作用的科学认知,为今后新的膜催化过程的研究和开拓提供科学基础。在提供重要新科学认知的基础上,进一步优化产生具有自主知识产权的技术创新成果,为化石能源洁净高效优化利用,解决能源短缺和环境恶化提供技术基础。

      在应用研究方面,开发了具有自主知识产权的微波放大合成分子筛膜技术以及分子筛膜有机物/水分离设备集成等相关技术,相关授权专利20余件。该系列技术可以广泛用于能源、化工、制药以及电子工业中有机物脱水(如乙醇、醇类、酮类、醚类、脂类等)。

招生信息

   
招生专业
070304-物理化学(含:化学物理)
080501-材料物理与化学
招生方向
催化;膜分离
材料科学
电化学

教育背景

1989-03--1989-12   英国Birmingham大学化学学院   访问学者
1983-09--1990-03   中国科学院大连化学物理研究所   理学博士学位
1979-09--1983-07   哈尔滨师范大学化学系   理学学士学位
出国学习工作
先后在英国Birmingham大学(1989)、德国Inst. Interfacial Eng. Biotech. (1999)、美国Univ. Southern California(2001)等作访问学者。

专利与奖励

   
奖励信息
(1) 分子尺度分离无机膜材料设计合成及其分离与催化性能研究, 二等奖, 国家级, 2015
(2) 中国科学院优秀导师奖, 院级, 2015
(3) 大连市劳动模范, , 市地级, 2008
(4) 无机膜与膜催化, 一等奖, 省级, 2006
(5) 中国化学会青年化学奖, , 专项, 1998
专利成果
(1) 一种微波加热法合成T型分子筛膜的方法,发明,2010,第1作者,专利号:200710010507.5
(2) 一种耐CO2 、SO2复合透氧陶瓷膜及其制备以及应用,发明,2010,第1作者,专利号:201010548682.1
(3) 纳米级复合金属氧化物八面体的制备方法,发明,2010,第1作者,专利号:201010547016.6
(4) 一种中、低温固体氧化物燃料电池三元复合阴极材料,发明,2011,第1作者,专利号:200710011081.5
(5) 用于丙烷氧化制丙烯酸反应的钼钒碲铌催化剂的制备方法,发明,2010,第1作者,专利号:201010558871.7
(6) 烷烃选择氧化反应催化剂Mo-V-M-O的制备方法,发明,2010,第1作者,专利号:201010555415.7
(7) 微米级花状复合金属氧化物的制备方法,发明,2010,第1作者,专利号:201010547019.X
(8) 一种制备金属复合膜的方法,发明,2010,第1作者,专利号:200610112703.9
(9) 一种固体氧化物燃料电池阴极材料及其制备方法,发明,2010,第1作者,专利号:201010233408.5
(10) Membrane for i-butanol recovery,发明,2010,第1作者,专利号:PCT/CN2010/000947

出版信息

近年来50篇代表性论文(共发表论文300余篇/他人引用11000余次/H-index 52):

  1. Peng Y, Li YS, Ban YJ, Jin H, Jiao WM, Liu XL, Yang WS, Metal-organic framework nanosheets as building blocks for molecular sieving membranes, Science, 346(6215)(2014)1356-1359

  2. Peng Y, Li YS, Ban YJ, Yang WS, Two-Dimensional Metal-Organic Framework Nanosheets for Membrane-Based Gas Separation, Angew. Chem. Int. Ed., 56(2017)9757-9761

  3. Li WP, Zhu XF, Chen SG, Yang WS, Integration of Nine Steps into One Membrane Reactor to Produce SynthesisGases for Ammonia and Liquid Fuel, Angew. Chem. Int. Ed., 55(30)(2016)8566-8570

  4. Ban YJ, Li ZJ, Li YS, Peng Y, Jin H, Jiao WM, Guo A, Wang P, Yang QY, Zhong CL, Yang WS, Confinement of Ionic Liquids in Nanocages: Tailoring the Molecular Sieving Properties of ZIF-8 for Membrane-Based CO2 Capture, Angew. Chem. Int. Ed., 54(51)(2015)15483

  5. Yu TW, Chu WL, Cai R, Liu YC, Yang WS, InSitu Electrochemical Synthesis of Oriented and Defect-Free AEL Molecular-Sieve Films Using Ionic Liquids, Angew. Chem. Int. Ed., 54(44)(2015)13032-13035

  6. Liu Y, Zhu XF, Li MR, Liu HY, Cong Y, Yang WS, Stabilization of Low-Temperature Degradation in Mixed Ionic and Electronic Conducting Perovskite Oxygen Permeation Membranes, Angew. Chem. Int. Ed., 52(11)(2013)3232-3236

  7. Liu XL, Li YS, Zhu, GQ, Ban YJ, Xu LY, Yang WS, An Organophilic Pervaporation Membrane Derived from Metal-Organic Framework Nanoparticles for Efficient Recovery of Bio-Alcohols, Angew. Chem. Int. Ed., 50(45)(2011)10636-10639

  8. Liu Y, Li YS, Yang WS, Fabrication of Highly b-Oriented MFI Film with Molecular Sieving Properties by Controlled In-Plane Secondary Growth, J. Am. Chem. Soc., 132(6)(2010)1768

  9. Liu Y, Ban YJ, Yang WS, Microstructural Engineering and Architectural Design of Metal-Organic Framework Membranes, Adv. Mater., 29(2017)1606949

  10. Xu XC, Yang WS, Liu J, Lin LW, Synthesis of a High-permeance NaA Zeolite Membrane by Microwave Heating, Adv. Mater., 12(3)(2000)195-198

  11. Liu Y, Zhu XF, Li MR, O'Hayre RP, Yang WS, Nanoparticles at Grain Boundaries Inhibit the Phase Transformation of Perovskite Membrane, Nano Lett., 15(11)(2015)7678-7683

  12. Li WP, Cao ZW, Cai LL, Zhang LX, Zhu XF, Yang WS, H2S-tolerant oxygen-permeable ceramic membrane for hydrogen separation with performance comparable to palladium-based membranes, Energy Environ. Sci., 10(1)(2017)101-106

  13. Zhu Y, Li WP, Liu Y, Zhu XF, Yang WS, Selection of Oxygen Permeation Models for Different Mixed Ionic-Electronic Conducting Membranes, AIChE J., 63(9)(2017)4043-4053

  14. Li WP, Cao ZW, Zhu XF, Yang WS, High-rate hydrogen separation using an MIEC oxygen permeable membrane reactor, AIChE J., 63(4)(2017)1278-1286

  15. Liu Y, Zhu Y, Li MR, Zhu XF, Yang WS, Oxygen Transport Kinetics of MIEC Membranes Coated with Different Catalysts, AIChE J., 62(8)(2016)2803-2812

  16. Liu Y, Zhu XF, Yang WS, Degradation Mechanism Analysis of Ba0.5Sr0.5Co0.8Fe0.2O3-d Membranes at Intermediate-Low Temperatures, AIChE J., 61(11)(2015) 3879-3888

  17. Zhu XF, Liu HY, Cong Y, Yang WS, Permeation model and experimental investigation of mixed conducting membranes, AIChE J., 58(6)(2012)1744-1754

  18. He YF, Zhu XF, Yang WS, The Role of A-Site Ion Nonstoichiometry in the Oxygen Absorption Properties of Sr1+xCo0.8Fe0.2O3 Oxides, AIChE J., 57(1)(2011) 87-95

  19. He YF, Zhu XF, Li QM, Yang WS, Perovskite Oxide Absorbents for Oxygen Separation, AIChE J., (55)(12)(2009) 3125-3133

  20. Zhu XF, Yang WS, Composite membrane based on ionic conductor and mixed conductor for oxygen permeation, AIChE J., 54(3)(2008)665-672

  21. Jin H, Liu XL, Ban YJ, Peng Y, Jiao WM, Wang P, Guo A, Li YS, Yang WS, Conversion of xylose into furfural in a MOF-based mixed matrix membrane reactor, Chem. Eng. J., 305(2016)12-18

  22. Jin H, Li YS, Liu XL, Ban YJ, Peng Y, Jiao WM, Yang WS, Recovery of HMF from aqueous solution by zeolitic imidazolate frameworks, Chem. Eng. Sci., 124(2015)170-178

  23. Jiao WM, Ban YJ, Shi ZX, Jiang XS, Li YS, Yang WS, High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices, Chem. Commun., 52(95)(2016)13779-13782

  24. Zhu KY, Li MR, Li XN, Zhu XF, Wang JH, Yang WS, Enhancement of oxygen evolution performance through synergetic action between NiFe metal core and NiFeOx shell, Chem. Commun., 52(79)(2016)11803-11806

  25. Liu XL, Li YS, Ban YJ, Peng Y, Jin H, Bux H, Xu LY, Caro J, Yang WS, Improvement of hydrothermal stability of zeolitic imidazolate frameworks, Chem. Commun., 49(80)(2013)9140-9142

  26. Liu Y, Li YS, Cai R, Yang WS, Suppression of twins in b-oriented MFI molecular sieve films under microwave irradiation, Chem. Commun., 48(54)(2012)6782-6784

  27. Zhu XF, Liu HY, Cong Y, Yang WS, Novel dual-phase membranes for CO2 capture via an oxyfuel route, Chem. Commun., 48(2)(2012) 251-253

  28. Liu HY, Zhu XF, Cheng MJ, Cong Y, Yang WS, Novel Mn1.5Co1.5O4 spinel cathodes for intermediate temperature solid oxide fuel cells, Chem. Commun., 47(8)(2011)2378-2380

  29. Ji BF, Wang JB, Chu WL, Yang WS, Lin LW, Acrylic acid and electric power cogeneration in an SOFC reactor, Chem. Commun., 15(2009)2038-2040

  30. Zhang HZ, Yang WS, Highly efficient electrocatalysts for oxygen reduction reaction, Chem. Commun., 41(2007)4215-4217

  31. Zhu XF, Wang HH, Yang WS, Novel cobalt-free oxygen permeable membrane, Chem. Commun.,, 9(2004)1130-1131

  32. Wang HH, Cong Y, Yang WS, High selectivity of oxidative dehydrogenation of ethane to ethylene in an oxygen permeable membrane reactor, Chem. Commun., 14(2002)1468-1469

  33. Jiao WM, Ban YJ, Shi ZX, Jiang XS, Li YS, Yang WS, Gas separation performance of supported carbon molecular sieve membranes based on soluble polybenzimidazole, J. Membr. Sci., 533(2017)1-10

  34. Cai LL, Li WP, Cao ZW, Zhu XF, Yang WS, Improving oxygen permeation of MIEC membrane reactor by enhancing the electronic conductivity under intermediate-low oxygen partial pressures, J. Membr. Sci., 520(2016)607-615

  35. Jin H, Wollbrink A, Yao R, Li YS, Caro J, Yang WS, A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions, J. Membr. Sci., 513(2016)40-46

  36. Liu Y, Zhu XF, Yang WS, Stability of sulfate doped SrCoO3-delta MIEC membrane, J. Membr. Sci., 501(2016)53-59

  37. Liu Y, Zhu XF, Li MR, Li WP, Yang WS, Degradation and stabilization of perovskite membranes containing silicon impurity at low temperature, J. Membr. Sci., 492(2015)173

  38. Li HB, Zhu XF, Liu Y, Wang WP, Yang WS, Comparative investigation of dual-phase membranes containing cobalt and iron-based mixed conducting perovskite for oxygen permeation, J. Membr. Sci., 462(2014)170-177

  39. Liu XL, Jin H, Li YS, Bux H, Hu ZY, Ban YJ, Yang WS, Metal-organic framework ZIF-8 nanocomposite membrane for efficient recovery of furfural via pervaporation and vapor permeation, J. Membr. Sci., 428(2013)498-506

  40. Zhu XF, Li MR, Liu HY, Zhang TY, Cong Y, Yang WS, Design and experimental investigation of oxide ceramic dual-phase membranes, J. Membr. Sci., 394(2012)120-130

  41. Liu XL, Li YS, Liu Y, Zhu GQ, Liu J, Yang WS, Capillary supported ultrathin homogeneous silicalite-poly(dimethylsiloxane) nanocomposite membrane for bio-butanol recovery, J. Membr. Sci., 369(2011)228-232

  42. Li QM, Zhu XF, He YF, Cong Y, Yang WS, Effects of sintering temperature on properties of dual-phase oxygen permeable membranes, J. Membr. Sci., 367(1-2)(2011) 134-140

  43. Zhu XF, Li QM, He YF, Cong Y, Yang WS, Oxygen permeation and partial oxidation of methane in dual-phase membrane reactors, J. Membr. Sci., 360(2010)454-460

  44. Zhan SJ, Zhu XF, Ji BF, Wang WP, Zhang XL, Wang JB, Yang WS, Lin LW, Preparation and hydrogen permeation of SrCe0.95Y0.05O3-delta asymmetrical membranes, J. Membr. Sci., 340(1-2)(2009)241-248

  45. Zhu XF, Sun SM, Cong Y, Yang WS, Operation of perovskite membrane under vacuum and elevated pressures for high-purity oxygen production, J. Membr. Sci., 345(2009)47-52

  46. Zhu GQ, Li YS, Zhou H, Liu J, Yang WS, Microwave synthesis of high performance FAU-type zeolite membranes: Optimization, characterization and pervaporation dehydration of alcohols, J. Membr. Sci., 337(1-2)(2009) 47-54

  47. Li QM, Zhu XF, Yang WS, Single-step fabrication of asymmetric dual-phase composite membranes for oxygen separation, J. Membr. Sci., 325(2008)11-15

  48. Zhu XF, Sun SM, He YF, Cong Y, Yang WS, New concept on air separation, J. Membr. Sci., 323(2008)221-224

  49. Li YS, Yang WS, Microwave synthesis of zeolite membranes: A review, J. Membr. Sci., 316(2008)3-17

  50. Zhu XF, Wang HH, Yang WS, Relationship between homogeneity and oxygen permeability of composite membranes, J. Membr. Sci., 309(1-2)(2008)120-127