(1)Fluorine Chemistry;  (2)Phosphorus Chemistry

-- Ph.D

Aug. 2005−present: Professor (Organic Chemistry)

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Aug. 2003−Jul. 2005: Postdoctoral research (Organic Chemistry)

Department of Chemistry, University of Idaho (Professor Jean’ne M. Shreeve’s group)

Aug. 2000−Jul. 2003: Ph. D. (Organic Chemistry)

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China.

Aug. 1997−Aug. 2000: M.E., Chemical Engineering

Shanghai Research Institute of Chemical Industry, Shanghai, China

Jul. 1992−Aug. 1997: Lecturer (Organic Chemistry)

                  Department of Chemistry, Shaoyang Teachers College, Hunan Province, China

Aug. 2005−present: Professor (Organic Chemistry)

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Jul. 1992−Aug. 1997: Lecturer (Organic Chemistry)

                  Department of Chemistry, Shaoyang Teachers College, Hunan Province, China

Jul. 1992−Aug. 1997: Lecturer (Organic Chemistry)

                  Department of Chemistry, Shaoyang Teachers College, Hunan Province, China

1. Xiao, Ji-Chang; Duan, Jian-Xin; Li, An-Rong; Guo, Yong; Chen, Qing-Yun. “A simple method for preparing difluorodiiodomethane from difluoro(fluorosulfonyl)acetyl fluoride” Collect. Czech. Chem. Commun. 2002, 67, 1320-1324.

2. Xiao, Ji-Chang; Chen, Qing-Yun. “The chemistry of tetrafluoroallene: one-pot synthesis of (trifluoromethyl)indolizines from 1,3-diiodo-1,1,3,3-tetrafluoropropane by 1,3-dipolar cycloaddition” Chin. J. Chem. 2003, 21, 898-903.

3. Xiao, Ji-Chang; Chen, Qing-Yun. “The chemistry of tetrafluoroallene: nucleophilic addition reactions with phenols and amines” J. Fluorine Chem. 2003, 123, 189-195.

4. Xiao, Ji-Chang; Chen, Qing-Yun. “Reaction of imidazole anions with difluorodiiodo- methane and their products conversion in sulfinatodehalogenation system” Chin. J. Chem. 2003, 21, 1349-1355.

5. Xiao, Ji-Chang; Twamley, Brendan; Shreeve, Jean'ne M. “An Ionic Liquid-Coordinated Palladium Complex: A Highly Efficient and Recyclable Catalyst for the Heck Reaction” Org. Lett. 2004, 6, 3845-3847.

6. Xiao, Ji-Chang; Shreeve, Jean'ne M. “Microwave-assisted rapid electrophilic fluorination of 1, 3-dicarbonyl derivatives with Selectfluor^®” J. Fluorine Chem. 2005, 126, 475-478.

7. Xiao, Ji-Chang; Shreeve, Jean'ne M. “Synthesis of 2,2’-Biimidazolium-based Ionic Liquid: Its Use as a New Reaction Medium and Ligand for Palladium-catalyzed Suzuki Cross-coupling Reaction” J. Org. Chem. 2005, 70, 3072-3078.

8. Ye, Chengfeng; Xiao, Ji-Chang; Twamley, Brendan; Shreeve, Jean'ne M. “Energetic salts of azotetrazolate, iminobis(5-tetrazolate) and 5,5’-bis(tetrazolate)” Chem. Commun. 2005, 2750-2752.

9. Xiao, Ji-Chang; Ye, Chengfeng; Shreeve, Jean’ne M. “Bipyridinium ionic liquid promoted cross-coupling reactions between perfuoroalkyl or pentafluorophenyl halides and aryl iodides” Org. Lett. 2005, 7, 1963-1965.

10. Cao, Hai-Ping; Xiao, Ji-Chang; Chen, Qing-Yun. “Fluoroalkylation of aromatics: An intramolecular radical cyclization of 4-chloro-1,1,2,2,3,3,4,4-octafluorobutylbenzenes” J. Fluorine Chem. 2006, 127, 1079-1086.

11. Jin, Li-Mei; Yi, Juan-Juan; Chen, Liang; Xiao, Ji-Chang; Guo, Can-Cheng; Chen, Qing-Yun. “Unusual fluoroalkenylation of porphyrins: a highly stereoselective synthesis of 10,20-diaryl-5-[(E)-fluoroalkenyl]-15-(fluoroalkyl)porphyrins” Eur. J. Org. Chem. 2006, 3405-3411.

12. Jin, Li-Mei; Yin, Juan-Juan; Chen, Liang; Zhou, Jin-Ming; Xiao, Ji-Chang; Guo, Can-Cheng; Chen, Qing-Yun. “Self-assembly and liquid-crystalline properties of 5-fluoroalkylporphyrins” Chem. Eur. J. 2006, 12, 7935-7941.

13. Cheng, Zhan-Ling; Xiao, Ji-Chang; Liu, Chao; Chen, Qing-Yun. “Chemistry of difluorocarbene: synthesis and conversion of difluoro(methylene)cyclopropanes” Eur. J. Org. Chem. 2006, 24, 5581-5587.

14. Chen, Liang; Jin, Li-Mei; Xiao, Ji-Chang; Guo, Can-Cheng; Chen, Qing-Yun. “Fluoroalkylation of porphyrins: synthesis of porphyrins bearing double meso,β-fused fluoroalkyl rings via radical cyclization” Synlett 2007, 2096-2100.

15. Ye, Chengfeng; Xiao, Ji-Chang; Twamley, Brendan; Lalonde, Aaron D.; Norton, M. Grant; Shreeve, Jean’ne M. “Basic Ionic Liquids: Facile Solvents for Carbon-Carbon Bond Formation Reactions and Ready Access to Palladium Nanoparticles” Eur. J. Org. Chem. 2007, 5095-5100.

16. Wang, Ruihu; Xiao, Ji-Chang; Twamley, Brendan; Shreeve, Jean’ne M. “Efficient Heck reactions catalyzed by a highly recyclable palladium(II) complex of a pyridyl-functionalized imidazolium-based ionic liquid” Org. Biomol. Chem. 2007, 5, 671-678.

17. Gao, Haixiang; Ye, Chengfeng; Gupta, Om D.; Xiao, Ji-Chang; Hiskey, Michael A.; Twamley, Brendan; Shreeve, Jean'ne M. “2,4,5-trinitroimidazole-based energetic salts” Chem. Eur. J. 2007, 13, 3853-3860.

18. Zeng, Zhuo; Phillips, Benjamin S.; Xiao, Ji-Chang; Shreeve, Jean'ne M. “Polyfluoroalkyl, Polyethylene Glycol, 1,4-Bismethylenebenzene, or 1,4-Bismethylene-2,3,5,6-Tetrafluorobenzene Bridged Functionalized Dicationic Ionic Liquids: Synthesis and Properties as High Temperature Lubricants.” Chem. Mater. 2008, 20, 2719-2726.

19. Hang, Xiao-Chun; Chen, Qing-Yun; Xiao, Ji-Chang. “Highly regio- and stereoselective Diels-Alder cycloaddition of difluoro(methylene)cyclopropanes” Eur. J. Org. Chem. 2008, 1101-1106.

20. Zhang, Cheng-Pan; Chen, Qing-Yun; Xiao, Ji-Chang. “Reactions of HMPA with hexafluorobenzene, pentafluorochlorobenzene and pentafluorophenol” J. Fluorine Chem. 2008, 129, 424-428.

21. Hang, Xiao-Chun; Chen, Qing-Yun; Xiao, Ji-Chang. “1,3-Dipolar Cycloaddition of Difluoro(methylene)cyclopropanes with Nitrones: Efficient synthesis of 3,3-Difluorinated Tetrahydropyridinols” Synlett 2008, 1989-1992.

22. Zhu, Zhi-Qiang; Xiang, Shaoji; Chen, Qing-Yun; Chen, Chaosen; Zeng, Zhuo; Cui, Yi-Ping; Xiao, Ji-Chang “Novel low-melting salts with donor-acceptor substituents as targets for second-order nonlinear optical applications” Chem. Commun. 2008, 5016-5018.

23. Hang, Xiao-Chun; Chen, Qing-Yun; Xiao, Ji-Chang. “Ring-Opening Reactions of Difluoro(methylene)cyclopropanes with Halogens and Amines” J. Org. Chem. 2008, 73, 8598-8600.

24. Jiang, Hua-Wei; Chen, Qing-Yun; Xiao, Ji-Chang; Gu, Yu-Cheng. “Synthesis and Reactions of the First Fluoroalkylated Ni(II) N-Confused Porphyrins” Chem. Commun. 2008, 5435-5437.

25. Zhang, Chengpan; Lin, Jinhong; Qiang, Zhenwei; Xiao, Jichang. “An efficient method for the preparation of pentafluoroiodoethane from chloropentafluoroethane” Chin. J. Chem. 2009, 27, 202-204.

26. Lin, Jin-Hong; Zhang, Cheng-Pan; Zhu, Zhi-Qiang; Chen, Qing-Yun; Xiao, Ji-Chang “A novel pyrrolidinium ionic liquid with 1,1,2,2-tetrafluoro-2-(1,1,2,2- tetrafluoroethoxy)ethanesulfonate anion as a recyclable reaction medium and efficient catalyst for Friedel-Crafts alkylations of indoles with nitroalkenes” J. Fluorine Chem. 2009, 130, 394-398.

27. Jiang, Hua-Wei; Chen, Qing-Yun; Xiao, Ji-Chang; Gu, Yu-Cheng. “The Oxidation of Ni(II) N-Confused Porphyrins (NCPs) with Azo Radical Initiators and an Unexpected Intramolecular Nucleophilic Substitution Reaction via a Proposed Ni(III) NCP Intermediate” Chem. Commun. 2009, 3732-3734.

28. Zhang, Cheng-Pan; Chen, Qing-Yun; Xiao, Ji-Chang; Gu, Yu-Cheng. “A mild hydrodehalogenation of fluoroalkyl halides” J. Fluorine Chem. 2009, 130, 671-673.

29. Hang, Xiao-Chun; Gu, Wei-Peng; Chen, Qing-Yun; Xiao, Ji-Chang. “Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones” Tetrahedron 2009, 65, 6320-6324.

30. Zhu, Zhi-Qiang; Jiang, Ming-Yue; Lin, Jin-Hong; Zhang, Cheng-Pan; Hang, Xiao-Chun; Zheng, Chang-Ge; Chen, Qing-Yun; Xiao, Ji-Chang “Unexpected Reactions of Push-Pull N-Heterocyclic Carbene Derived from N-(4-methoxyphenyl)-N-(4-nitrophenyl)-imidazolium Chloride” Synlett 2009, 2305-2308.

31. Lin, Jin-Hong; Zhang, Cheng-Pan; Xiao, Ji-Chang “Enantioselective aldol reaction of cyclic ketones with aryl aldehydes catalyzed by a cyclohexanediamine derived salt in the presence of water” Green Chem. 2009, 11, 1750-1753.

32. Jiang, Huawei; Xiao, Jichang^*. “Recent Progress in Subporphyrins” Chin. J. Org. Chem. 2009, 29, 1750-1755.

33. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Xiao, Ji-Chang “One-pot synthesis of arylfluoroalkylsulfoxides and study of their anomalous ¹⁹F NMR behavior” J. Fluorine Chem. 2010, 131, 433-438.

34. Zhang, Cheng-Pan; Cao, Hai-Ping; Wang, Zong-Ling; Zhang, Chun-Tao; Chen, Qing-Yun; Xiao, Ji-Chang “New Electrophilic Bromodifluoromethylation and Pentafluoroethylation Reagents” Synlett 2010, 1089-1092.

35. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang “Determination of pK_a Values of Fluoroalkanesulfonamides and Investigation of Their Nucleophilicity” J. Fluorine Chem. 2010, 131, 761-766.

36. Jiang, Hua-Wei; Hao, Fei; Chen, Qing-Yun; Xiao, Ji-Chang; Liu, Shu-Bin; Gu, Yu-Cheng “Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols” J. Org. Chem. 2010, 75, 3511-3514.

37. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang “Synthesis and Physicochemical Properties of Bis(fluoroalkanesulfonyl)imide-based Ionic Liquids” Eur. J. Inorg. Chem. 2010, 3419-3422.

38. Zhu, Zhi-Qiang; Xiao, Ji-Chang “N-Heterocyclic Carbene Catalyzed Reaction of Alkynyl Aldehydes with 1,3-Ketoesters or 1,3-Diketones” Adv. Synth. Catal. 2010, 352, 2455-2458.

39. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang “Ionic liquids with high densities and wide temperature range of liquid state” Glob. J. Inorg. Chem. 2010, 1, 115-118.

40. Hang, Xiao-Chun; Gu, Wei-Peng; Chen, Qing-Yun; Xiao, Ji-Chang; Xu, Wei-Guo; Liu, Shubin “Thermal rearrangement of substituted difluoro(methylene)cyclopropane” J. Fluorine Chem. 2011, 132, 63-67.

41. Zhang, He; Zhou, Chang-Bing; Chen, Qing-Yun; Xiao, Ji-Chang; Hong, Ran “Monofluorovinyl Tosylate: A Useful Building Block for the Synthesis of Terminal Vinyl Monofluorides via Suzuki-Miyaura Coupling” Org. Lett., 2011, 13, 560–563.

42. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang “Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts” Angew. Chem. Int. Ed. 2011, 50, 1896-1900.

43. Zhang, Cheng-Pan; Wang, Zong-Ling; Chen, Qing-Yun; Zhang, Chun-Tao; Gu, Yu-Cheng; Xiao, Ji-Chang “Generation of the CF₃ Radical from Trifluoromethylsulfonium Triflate and its Trifluoromethylation of Styrenes” Chem. Commun. 2011, 47, 6632-6634.

44. Zhu, Zhi-Qiang; Zheng, Xing-Liang; Jiang, Ning-Fei; Wan, Xiaolong; Xiao, Ji-Chang “Chiral N-Heterocyclic Carbene Catalyzed Annulation of α,β-Unsaturated Aldehydes with 1,3-Dicarbonyls” Chem. Commun. 2011, 47, 8670-8672.

45. Zhang, Cheng-Pan; Cai, Ji; Zhou, Chang-Bing; Wang, Xiao-Ping; Zheng, Xing; Gu, Yu-Cheng; Xiao, Ji-Chang “Copper-Mediated Trifluoromethylation of Arylboronic Acids by Trifluoromethyl Sulfonium Salts” Chem. Commun. 2011, 47, 9516-9518.

46. Lin, Jin-Hong; Xiao, Ji-Chang “The Asymmetric Friedel-Crafts Reaction of Indoles with Fluoroalkylated Nitroalkenes Catalyzed by Chiral Phosphoric Acid” Eur. J. Org. Chem. 2011, 4536-4539.

47. Wang, Zongling; Zhang, Chengpan; Zhang, Chuntao; Xiao, Jichang “Solvent- and Catalyst-Free Direct Aldol Reactions” Chin. J. Chem. 2011, 29, 2689-2694.

48. Zhu, Zhi–Qiang; Jiang, Ming–Yue; Zheng, Chang–Ge; Xiao, Ji–Chang “Efficient Synthesis of 1-Alkyl-3-methylimidazolium Fluorides and Possibility of the Existence of Hydrogen Bonding Between Fluoride Anion and C(sp³)–H” J. Fluorine Chem. 2012, 133, 160-162.

49. Hao, Fei; Jiang, Hua–Wei; Zong, Guoqiang; Zhou, Zhiguo; Du, Ruo–Bing; Chen, Qing–Yun; Xiao, Ji–Chang “Electrophilic Fluoroalkylation of Ni(II) N-Confused Porphyrins with Fluoroalkylarylsulfonium Salts” J. Org. Chem. 2012, 77, 3604-3608.

50. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong; Xiao, Ji-Chang; Gu, Yu-Cheng “Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system” Chem. Soc. Rev. 2012, 41, 4536-4559.

51. Lin, Jin-Hong; Zong, Guoqiang; Du, Ruo-Bing; Xiao, Ji-Chang; Liu, Shubin “The asymmetric synthesis of CF₃- or -CF₂-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst” Chem. Commun. 2012, 48, 7738-7740.

52. Du, Shangchao; Hu, Chunhua; Xiao, Ji-Chang; Tan, Huaqiao; Liao, Wuping “A giant coordination cage based on sulfonylcalix[4]arenes” Chem. Commun. 2012, 48, 9177-9179.

53. Lv, Huichao; Zhang, Chengpan; Huang, Jin; Zhao, Qiaoling; Ma, Zhi; Xiao, Jichang “Polystyrene-co-poly(2,3,4,5,6-pentafluorostyrene) Copolymers: Synthesis and Fabrication of Their Porous Films” Acta Chim. Sinica 2012, 70, 1125-1130.

54. Wang, Xiaoping; Lin, Jinhong; Zhang, Chengpan; Xiao, Jichang; Zheng, Xing “Copper-mediated trifluoromethylation of terminal alkynes by S-(trifluoromethyl)diarylsulfonium salt” Chin. J. Chem. 2013, 31, 915-920.

55. Zheng, Jian; Cai, Ji; Lin, Jin-Hong; Guo, Yong; Xiao, Ji-Chang “Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine” Chem. Comm. 2013, 49, 7513-7515.

56. Yang, Tang-Po; Lin, Jin-Hong; Chen, Qing-Yun; Xiao, Ji-Chang “A novel reaction of gem-difluorocyclopropyl ketones with nitriles leading to 2-fluoropyrroles” Chem. Comm. 2013, 49, 9833-9835.

57. Zheng, Jian; Lin, Jin-Hong; Cai, Ji; Xiao, Ji-Chang “Conversion between Difluorocarbene and Difluoromethylene Ylide” Chem. Eur. J. 2013, 19, 15261-15266.

58. Zhang, Yanhui; Du, Ruobing; Wang, Zhenxing; Lu, Renjie; Mao, Tingting; Xiao, Jichang “Research on buffer solution of chloroacetic acid in rare earth detection” J. Chin. Soc. Rare Earth (in Chinese) 2013, 31, 636-640. 

59. Wang, Xiao-Ping; Lin, Jin-Hong; Zhang, Cheng-Pan; Xiao, Ji-Chang; Zheng Xing “Copper-catalyzed Trifluoromethylation of Alkenes with Electrophilic Trifluoromethylating Reagent” Beilstein J. Org. Chem. 2013, 9, 2635-2640.

60. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong; Xiao, Ji-Chang “Bi-Functional Fluoroalkylation Reagents: An introduction to Halo-substituted 3-Oxa-Perfluoroalkanesulfonyl Fluorides” Tetrahedron 2013, 69, 10955-10989.

61. Wang, Qi; Huan, Feng; Shen, Haiming; Xiao, Ji-Chang; Gao, Min; Yang, Xianjin^*; Murahashi, Shun-Ichi^*; Chen, Qing-Yun^*; Guo, Yong^* “Organocatalytic Reactions of α-Trifluoromethylated Esters with Terminal Alkenes at Room Temperature” J. Org. Chem. 2013, 78, 12525-12531.

62. Gu, Wei-Peng; Lin, Jin-Hong; Xiao, Ji-Chang^*. “Direct N-gem-difluorocyclopropylation of nitro-heterocycles by utilizing gem-difluorocyclopropyl Tosylate” Chin. Chem. Lett. 2014, 25, 24-28.

63. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong; Xiao, Ji-Chang^*; Gu, Yu-Cheng. “Difluoromethylation and Trifluoromethylation Reagents Derived from Tetrafluoroethane β-Sultone: Synthesis, Reactivity and Applications” Coord. Chem. Rev. 2014, 261, 28-72.

64. Zhang, He; Lin, Jin-Hong; Xiao, Ji-Chang^*; Gu, Yu-Cheng. “Rh-Catalyzed Allylic C-F Bond Activation: The Stereosynthesis of Trisubstituted Monofluoroalkenes and A Mechanism Study” Org. Biomol. Chem. 2014, 12, 581-588.

65. Yang, Tang-Po; Li, Qiang; Lin, Jin-Hong; Xiao, Ji-Chang^*. “Boron-trihalide-promoted Regioselective Ring-opening Reactions of gem-Difluorocyclopropyl Ketones” Chem. Commun. 2014, 50, 1077-1079.

66. Wang, Xiao-Ping; Lin, Jin-Hong; Xiao, Ji-Chang^*; Zheng, Xing. “Decarboxylative Julia–Kocienski gem-difluoroolefination of 2-Pyridinyl sulfonyl-difluoroacetate” Eur. J. Org. Chem. 2014, 928-932.

67. Ji, Yun-Long; Kong Jun-Jie; Lin, Jin-Hong^*; Xiao, Ji-Chang^*; Gu, Yu-Cheng. “Copper-mediated Trifluoromethylation of Propargyl Acetates Leading to Trifluoromethyl-allenes” Org. Biomol. Chem. 2014, 12, 2903–2906.

68. Zong, Guoqiang; Chen, Bo; Zhang, Long; Sun, Jiahong; Dong, Qun’an; Chen, Wei; Xiao, Jichang^*. “Preparation of FLiNaK molten salt” Nucl. Tech. 2014, 37, 050604-1-5.

69. Li, Qiang; Lin, Jin-Hong; Deng, Zu-Yong; Zheng, Jian; Cai, Ji; Xiao, Ji-Chang^*. “Wittig gem-Difluoroolefination of Aldehydes with Difluoromethyltriphenylphosphonium Bromide” J. Fluorine Chem. 2014, 163, 38-41.

70. Jiang, Dong-Fang; Liu, Chao^*; Guo, Yong; Xiao, Ji-Chang; Chen, Qing-Yun^* “A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arene-diazonium Salts with R_FCu(CH₃CN) Complexes” Eur. J. Org. Chem. 2014, 6303-6309.

71. Zhao, Shuai; Liu, Chao; Guo, Yong; Xiao, Ji-Chang; Chen, Qing-Yun^* “Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) β-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin” J. Org. Chem. 2014, 79, 8926-8931.

72. Zhao, Shuai; Liu, Chao; Guo, Yong; Xiao, Ji-Chang; Chen, Qing-Yun^* “β-perfluoroalkylated meso-aryl-substituted subporphyrins: synthesis and properties” Synthesis 2014, 46, 1674-1688.

73. Du, Ruobing; Zhang, Yanhui; Lu, Renjie; Zhang, Ting; Ma, Hengli; Xiao, Jichang^*. “Accurate Measurement of Rare Earth in the Presence of Salting-Out Agent—NaCl” J. Chin. Soc. Rare Earth (in Chinese) 2014, 32, 370-376. 

74. Deng, Xiaoyun; Lin, Jinhong; Zheng, Jian; Xiao, Jichang^*. “Cu-promoted Oxidative Trifluoromethylation of Terminal Alkynes with Difluoromethylene Phosphobetaine” Chin. J. Chem. 2014, 32, 689-693.

75. Lin, Jin-Hong; Xiao, Ji-Chang^*. “Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis” Tetrahedron Lett. 2014, 55, 6147-6155.

76. Ji, Yun-Long; Lin, Jin-Hong^*; Xiao, Ji-Chang^*; Gu, Yu-Cheng. “Copper-catalyzed Tandem Trifluoromethylation/ Cyclization of Internal Alkynes” Org. Chem. Front. 2014, 1, 1280-1284.

77. Ji, Yun-Long; Lin, Jin-Hong^*; Xiao, Ji-Chang^*; Gu, Yu-Cheng. “Stereoselective Synthesis of α-Trifluoromethyl Enones by Au(I)/Cu(I)-Cocatalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation of Propargyl Acetates” Eur. J. Org. Chem. 2014, 7948-7954.

78. 78. Li, Zhong; Wang, Qing-liang^*; Li, Qian; Hu, E-ming; Xiong, Xiao; Xiao, Ji-chang; Cheng, Quan-hui. “Experimental study on removal of sulfate radical(ion) from beryllium hydroxide” Min. Metall. Eng. (China) 2014, 34, 83-86, 91. 

79. Zong, Guoqiang; Chen, Bo; Gao, Min; Xiao, Jichang^* “Determination of trace oxygen in FLiNaK molten salt” Chinese J. Inorg. Anal. Chem. 2015, 5, 45-48. 

80. Zheng, Jian; Lin, Jin-Hong; Deng, Xiao-Yun; Xiao, Ji-Chang^* “1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation” Org. Lett. 2015, 17, 532-535.

81. Wu, Hao; Xiao, Zhiwei; Wu, Junhui; Guo, Yong; Xiao, Ji-Chang; Liu, Chao^*; Chen, Qing-Yun^* “Direct Trifluoromethylthiolation of Unactivated C(sp3)[n.63743]H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate” Angew. Chem. Int. Ed. 2015, 54, 4070-4074.

82. Deng, Xiao-Yun; Lin, Jin-Hong; Zheng, Jian; Xiao, Ji-Chang^* “Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation” Chem. Commun. 2015, 51, 8805-8808.

83. Wang, Shi-Meng; Han, Jia-Bin; Zhang, Cheng-Pan^*; Qin, Hua-Li^*; Xiao, Ji-Chang^* “An overview of reductive trifluoromethylation reactions using electrophilic '⁺CF₃' reagents” Tetrahedron 2015, 71, 7949-7976.

84. Liu, Hao; Yu, Jing; Li, Xinyu; Yan, Rui; Xiao, Ji-Chang; Hong, Ran^* “Stereoselectivity in N-Iminium Ion Cyclization: Development of an Efficient Synthesis of (±)-Cephalotaxine” Org. Lett. 2015, 17, 4444-4447.

85. Duan, Yaya; Zhou, Bin; Lin, Jin-Hong; Xiao, Ji-Chang^* “Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation” Chem. Commun. 2015, 51, 13127-13130.

86. Li, Lun; Huang, Meiwei; Liu, Chao; Xiao, Ji-Chang; Chen, Qing-Yun^*; Guo, Yong^*; Zhao, Zhi-Gang “2,2,2-Trifluoroethylation of Styrenes with Concomitant Introduction of a Hydroxyl Group from Molecular Oxygen by Photoredox Catalysis Activated by Visible Light” Org. Lett. 2015, 17, 4714-4717.

87. Lin, Jin-Hong^*; Ji, Yun-Long; Xiao, Ji-Chang^* “Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions” Curr. Org. Chem. 2015, 19, 1541-1553.

88. Deng, Xiao-Yun; Lin, Jin-Hong; Xiao, Ji-Chang^* “One-pot synthesis of gem-difluorostyrenes from benzyl bromide via olefination of phosphonium ylide with difluorocarbene” J. Fluorine Chem. 2015, 179, 116-120.

89. Shen, Qian; Huang, Yan-Gen^*; Liu, Chao; Xiao, Ji-Chang; Chen, Qing-Yun^*; Guo, Yong^* “Review of recent advances in C-F bond activation of aliphatic fluorides” J. Fluorine Chem. 2015, 179, 14-22.

90. Zheng, Jian; Wang, Lu; Lin, Jin-Hong; Xiao, Ji-Chang^*; Liang, Steven H.^* “Difluorocarbene-Derived Trifluoromethylthiolation and [¹⁸F]Trifluoromethylthiolation of Aliphatic Electrophiles” Angew. Chem. Int. Ed. 2015, 54, 13236-13240.

91. Zheng, Jian; Lin, Jin-Hong; Yu, Liu-Ying; Wei, Yun; Zheng, Xing; Xiao, Ji-Chang^* “Cross-Coupling between difluorocarbene and carbene-derived in-termediates generated from diazocompounds for the synthesis of gem-difluoroolefins” Org. Lett. 2015, 17, 6150-6153.

92. Du, Ruo-Bing; An, Huaying; Zhang, Suhui; Yu, Donghai; Xiao, Ji-Chang^* “Microwave-assisted synthesis of dialkylphosphinic acids and a structure–reactivity study in Rare Earth metal extraction” RSC Adv. 2015, 5, 104258-104262.

93. Zong, Guoqiang; Cui, Zhen-Hua; Sun, Xiao-Gang; Xiao, Ji-Chang^* “One-Step Synthesis of High-purity Li₂BeF₄ Molten Salt” J. Fluorine Chem. 2016, 181, 30-35.

94. Yue, Chun-Bo; Lin, Jin-Hong; Cai, Ji; Zhang, Cheng-Pan; Zhao, Gang; Xiao, Ji-Chang; Li, HengFeng ^* “O-difluoromethylation of 1,3-diones with S-difluoromethyl sulfonium salt” RSC Adv. 2016, 6, 35705-35708.

95. Deng, Zuyong; Lin, Jin-Hong; Xiao, Ji-Chang^* “Nucleophilic arylation with tetraarylphosphonium salts” Nat. Commun. 2016, 7: 10337 doi: 10.1038/ncomms10337.

96. Ji, Yun-Long; Luo, Jia-Jia; Lin, Jin-Hong; Xiao, Ji-Chang^*; Gu, Yu-Cheng “Cu-catalyzed C-H trifluoromethylation of 3-arylprop-1-ynes for the selective construction of allenic Csp²-CF₃ and propargyl Csp³-CF₃ bonds” Org. Lett. 2016, 18, 1000-1003.

97. Wei, Yun; Yu, Liuying; Lin, Jin-Hong^*; Zheng, Xing Zheng^*; Xiao, Ji-Chang^* “DBU-Promoted Trifluoromethylation of Aryl Iodides with Difluoromethyltriphenylphosphonium Bromide” Chin. J. Chem. 2016, 34, 481-484.

98. Yu, Donghai; Du, Ruobing; Zhang, Suhui; Lu, Renjie; An, Huaying; Xiao, Ji-Chang^* “Prediction of solubility properties from transfer energies for acidic phosphorus-containing Rare-Earth extractants using Implicit Solvation Model” Solvent Extr. Ion Exch. 2016, 34, 347-354.

99. Yu, Donghai; Du, Ruobing; Xiao, Ji-Chang^* “pK_a Prediction for Acidic Phosphorus-Containing Compounds Using Multiple Linear Regression with Computational Descriptors” J. Comput. Chem. 2016, 37, 1668-1671.

100. Duan, Yaya; Lin, Jin-Hong^*; Xiao, Ji-Chang^*; Yu-Cheng Gu “A Trifluoromethylcarbene Source” Org. Lett. 2016, 18, 2471-2474.

101. Du, Ruobing; Yu, Donghai; An, Huaying; Zhang, Suhui; Lu, Renjie; Zhao, Gang; Xiao, Ji-Chang^* “α,β-Substituent effect of dialkylphosphinic acids on lanthanide extraction” RSC Adv. 2016, 6, 56004-56008.

102. Deng, Zuyong; Lin, Jin-Hong; Cai, Ji; Xiao, Ji-Chang^* “Direct Nucleophilic Difluoromethylation of Carbonyl Compounds” Org. Lett. 2016, 18, 3206-3209.

103. Zhou, Sheng-Hua; Lin, Jin-Hong; Zhao, Gang; Xiao, Ji-Chang^*; Cao, Weiguo^* “Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by Zinc / viologen” RSC Adv. 2016, 6, 60080-60083.

104. Deng, Xiao-Yun; Lin, Jin-Hong; Xiao, Ji-Chang^* “Pd-Catalyzed Transfer of Difluorocarbene” Org. Lett. 2016, 18, 4384-4387.

105. Zheng, Qu-Tong; Wei, Yun; Zheng, Jian; Duan, Ya-ya; Zhao, Gang; Wang, Zong-Bao; Lin, Jin-Hong^*; Zheng, Xing^*; Xiao, Ji-Chang^* “Difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones” RSC Adv. 2016, 6, 82298-82300.

106. Liu, Can; Deng, Xiao-Yun; Zeng, Xian-Liang; Zhao, Gang; Lin, Jin-Hong^*; Wang, Hongqing^*​; Xiao, Ji-Chang^* “Base-free O-difluoromethylation of 1,3-diones with difluorocarbene” J. Fluorine Chem. 2016, 192, 27-30.

(1) Xiao, Jichang; Duan, Yaya; Zhou, Bin; Lin, Jinhong. “Fluorine- containing three-membered ring compound and its preparation method, and method for preparing fluoroalkyl sulfonium salt” Faming Zhuanli Shenqing (2016), CN 105523873 A 20160427.

(2) Xiao, Jichang; Du, Ruobing; An, Huaying; Lu, Renjie; Zhang, Ting; Yin, Wutao; Zhang, Suhui. “A method for removing iron by solvent extraction” Faming Zhuanli Shenqing (2016), CN 105349781 A 20160224.

(3) Xiao, Jichang; Du, Ruobing; An, Huaying; Lu, Renjie; Zhang, Ting; Yin, Wutao; Zhang, Suhui. “An extractant, extraction system and application in extraction or stripping of rare earth elements” Faming Zhuanli Shenqing (2015), CN 105177322 A 20151223.

(4) Xiao, Jichang; Zheng, Jian; Cai, Ji. “Synthesis and application of difluoro methylene phosphorus inner salt” PCT Int. Appl. (2014), WO 2014117452 A1 20140807.

(5) Xiao, Jichang; Du, Ruobing; Zhang, Yanhui; Lu, Renjie “Extraction system, extraction method and back extraction method” Faming Zhuanli Shenqing (2014), CN 103725880 A 20140416.

(6) Xiao, Jichang; Du, Ruobing; Wang, Zhenxing; Zhang, Yanhui; Zhang, Ting “Preparation method of dialkyl phosphinic acid compound or its salt with high conversion rate and short reaction time and application thereof in separation of rare earth ion-containing mixture” Faming Zhuanli Shenqing (2014), CN 103694273 A 20140402.

(7) Xiao, Jichang; Zong, Guoqiang; Sun, Xiaogang; Wang, Rongrong; Sun, Jiahong; Ye, Xinyan “High-purity lithium beryllium fluoride molten salt and its preparation method [Machine Translation]” Faming Zhuanli Shenqing (2014), CN 103606385 A 20140226.

(8) Xiao, Jichang; Zong, Guoqiang; Chen, Wei; Li, Xiaodong; Chen, Bo; Zhang, Long; Wang, Zhengneng “Method for preparing high-purity ammonium fluoberyllate and application of the prepared ammonium fluoberyllate” Faming Zhuanli Shenqing (2014), CN 103601222 A 20140226.

(9) Xiao, Jichang; Zong, Guoqiang; Sun, Jiahong; Sun, Xiaogang; Li, Xiaodong; Ye, Xinyan “Melting apparatus for producing molten salt” Shiyong Xinxing Zhuanli Shuomingshu (2014), CN 203440069 U 20140219.

(10) Xiao, Jichang; Zong, Guoqiang; Wang, Rongrong; Dong, Qunan; Chen, Bo; Zhang, Long; Chen, Wei “A high-purity fluoride molten salt and preparation method thereof” Faming Zhuanli Shenqing (2013), CN 103219052 A 20130724.

(11) Xiao, Jichang; Ma, Hengli; Mao, Tingting; Zhang, Yanhui; Zhang, Ting; Yin, Wutao; Li, Changfeng; Ouyang, Ming “Method for synthesis of hydroxyphosphonic acid monoalkyl ester” Faming Zhuanli Shenqing (2013), CN 103073582 A 20130501.

(12) Xiao, Jichang; Zhang, Chengpan. “Process for preparation of trifluoromethyl substituted heterocyclic compounds” Faming Zhuanli Shenqing Gongkai Shuomingshu (2011), 15pp. CODEN: CNXXEV CN 101973829 A 20110216

(13) Xiao, Jichang; Zhang, Chengpan; Zhang, Zhong; Shao, Wei; Yan, Chong; Qiang, Zhenwei. “Process for preparation of imidazolium salts as high density ionic liquids by anionic exchange” Faming Zhuanli Shenqing Gongkai Shuomingshu (2009), 11pp. CODEN: CNXXEV CN 101591296 A 20091202

(14) Xiao, Jichang; Zhang, Chengpan; Yan, Chong; Qiang, Zhenwei. “Process for preparation of fluoroalkyl sulfimides and salts” Faming Zhuanli Shenqing Gongkai Shuomingshu (2009), 17pp. CODEN: CNXXEV CN 101503382 A 20090812

(16) Xiao, Jichang; Zhang, Zhong; Chen, Qingyun; Tian, Weisheng. “Preparation of fluorine-containing benzothiazolylsulfonyl compounds as herbicides, pesticides, and bactericides” Faming Zhuanli Shenqing Gongkai Shuomingshu (2008), 17pp. CODEN: CNXXEV CN 101215270 A 20080709

(17) Xiao, Jichang; Jiang, Mingyue; Chen, Chaosen. “Process for preparation of imidazolium ionic salts with electron donor-acceptor groups as nonlinear optical materials” Faming Zhuanli Shenqing Gongkai Shuomingshu (2008), 13pp. CODEN: CNXXEV CN 101143848 A 20080319

(1) New organofluorination reagents and Reactions; (2) Extractants; (3) Fluorine-containing functional molecules

(1) 2007. 7. 15-20., The 15^th European Symposium on Fluorine Chemistry, Prague, Czech   Republic

(2) 2007.9. 9-11., The 7^th China-Japan Symposium on Fluorochemical Industry, Chengdu, China

(3) 2009. 8. 23-28., The 19^th International Symposium on Fluorine Chemistry, Jackson Hole, Wyoming,  USA

(4) 2012. 7. 22-27., The 20^th International Symposium on Fluorine Chemistry, Kyoto, Japan

(5) 2012.8. 12-17., Engineering Conferences International — “Rare Earth Minerals/Metals - Sustainable Technologies for the Future”  San Diego, California, USA

(6) 2012. 11. 14-16., 2012 Dasan Conference: Fluorine Chemistry to Enviroment and Health Aspects, Changwon,  South Korea

(7) 2013. 7. 21-25., The 17^th European Symposium on Fluorine Chemistry, Paris, France

(8) 2014. 7. 6-10., The Bordeaux Fluorine Days symposium, Bordeaux, France

(9) 2015. 6. 10-14., The 10^th International Conference on Molten Salt Chemistry and Technology, Shenyang,  China

(10) 2015. 8. 23-28., The 21^st International Symposium on Fluorine Chemistry, Como, Italy

(11) 2016. 7. 3-7., The 5^th International Symposium on Organofluorine Compounds in Biomedical, Materials and Agricultural Sciences, FluorineDays, Bremen, Germany

(1) Dr. Steven H. Liang, Massachusetts General Hospital & Department of Radiology, Harvard Medical School, 55 Fruit St., White 427, Boston, MA (USA)

(2) Dr. Shubin Liu, Research Computing Center, University of North Carolina, Chapel Hill, NC 27599-3420, USA

已指导学生

辜伟鹏  02  19132  

杭晓春  01  19132  

蔡吉  01  19132  

蒋华卫  01  19132  

郝菲  02  19132  

林锦鸿  01  19132  

张成潘  01  19132  

朱志强  01  19132  

李强  02  19132  

张禾  01  19132  

于静  02  63220  

季云龙  01  19132  

姜延华  02  63220  

郑剑  01  19132  

邓祖勇  01  19132  

现指导学生

于蛟  02  19132  

罗佳佳  02  19132  

邓晓云  01  19132  

段亚亚  01  19132  

张维  02  19132  

张敏  02  19132  

陈佳  01  19132  

张唯  01  19132